A model to predict the kinetics of mass loss in wood during thermo-vacuum modification

Holzforschung ◽  
2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Ottaviano Allegretti ◽  
Ignazia Cuccui ◽  
Nasko Terziev ◽  
Laerte Sorini

AbstractMass loss (ML) of wood caused by thermal degradation is one of the most important features of the thermal treatments and referred to as an indicator of intensity and quality of the process. The ML is proportional to the quantity of the effective heat power exchanged during the treatment process, represented by the area of the temperature profile versus time during the process. In this paper a model for the ML prediction based on the relative area was discussed. The model proposed an analytical solution to take into account the non-linear trend of ML when plotted versus temperature and time as observed in isothermal experiments. The model was validated comparing calculated and measured final ML of samples treated during thermal modification tests with different temperature profiles. The results showed that the relative area calculated in a transformed time-temperature space improves the correlation with the measured ML.

Author(s):  
M.A. Egyan ◽  

The article shows studies characterizing the quality of the squeeze: the mechanical composition of the squeeze is determined, the structural moisture of each component is determined, the sugar content in the formed process of sedimentation of the juice and its acidity are determined refractometrically. The kinetics of anthocyanins extraction was determined in two ways, the solids content in the extract was calculated, and the reaction rate constants of the extraction process and the efficiency coefficient of ultrasonic amplification of the extraction process speed were calculated.


2007 ◽  
Vol 2 (1) ◽  
Author(s):  
A. Meda ◽  
C. Schaum ◽  
M. Wagner ◽  
P. Cornel ◽  
A. Durth

TIn 2004, the German Association for Wastewater, Water and Waste (DWA) carried out a survey about the current status of sewage sludge treatment and disposal in Germany. The study covered about one third of the wastewater treatment plants and about two thirds of the entire treatment capacity (expressed in population equivalents) in Germany. This provides an up-to-date and representative database. The paper presents the most important results regarding sludge treatment, process engineering, current disposal paths and sewage sludge quality.


1995 ◽  
Vol 31 (5-6) ◽  
pp. 85-89 ◽  
Author(s):  
S. J. Turner ◽  
G. D. Lewis

Over a 12 month period F-specific bacteriophages, faecal coliforms and enterococci were compared as microbial indicator organisms for the quality of a wastewater treatment (oxidation pond) system. Results suggest that enterococci may be the most useful indicator for oxidation pond systems.


1982 ◽  
Vol 47 (8) ◽  
pp. 2087-2096 ◽  
Author(s):  
Bohumil Bernauer ◽  
Antonín Šimeček ◽  
Jan Vosolsobě

A two dimensional model of a tabular reactor with the catalytically active wall has been proposed in which several exothermic catalytic reactions take place. The derived dimensionless equations enable evaluation of concentration and temperature profiles on the surface of the active component. The resulting nonlinear parabolic equations have been solved by the method of orthogonal collocations.


2007 ◽  
Vol 12 (1) ◽  
pp. 37-62 ◽  
Author(s):  
Paul Lambert ◽  
Kenneth Prandy ◽  
Wendy Bottero

This paper discusses long term trends in patterns of intergenerational social mobility in Britain. We argue that there is convincing empirical evidence of a small but steady linear trend towards increasing social mobility throughout the period 1800-2004. Our conclusions are based upon the construction and analysis of an extended micro-social dataset, which combines records from an historical genealogical study, with responses from 31 sample surveys conducted over the period 1963-2004. There has been much previous study of trends in social mobility, and little consensus on their nature. We argue that this dissension partly results from the very slow pace of change in mobility rates, which makes the time-frame of any comparison crucial, and raises important methodological questions about how long-term change in mobility is best measured. We highlight three methodological difficulties which arise when trying to draw conclusions over mobility trends - concerning the extent of controls for life course effects; the quality of data resources; and the measurement of stratification positions. After constructing a longitudinal dataset which attempts to confront these difficulties, our analyses provide robust evidence which challenges hitherto more popular, politicised claims of declining or unchanging mobility. By contrast, our findings suggest that Britain has moved, and continues to move, steadily towards increasing equality in the relationship between occupational attainment and parental background.


2017 ◽  
Vol 114 (31) ◽  
pp. 8265-8270 ◽  
Author(s):  
Simon Olsson ◽  
Hao Wu ◽  
Fabian Paul ◽  
Cecilia Clementi ◽  
Frank Noé

Accurate mechanistic description of structural changes in biomolecules is an increasingly important topic in structural and chemical biology. Markov models have emerged as a powerful way to approximate the molecular kinetics of large biomolecules while keeping full structural resolution in a divide-and-conquer fashion. However, the accuracy of these models is limited by that of the force fields used to generate the underlying molecular dynamics (MD) simulation data. Whereas the quality of classical MD force fields has improved significantly in recent years, remaining errors in the Boltzmann weights are still on the order of a few kT, which may lead to significant discrepancies when comparing to experimentally measured rates or state populations. Here we take the view that simulations using a sufficiently good force-field sample conformations that are valid but have inaccurate weights, yet these weights may be made accurate by incorporating experimental data a posteriori. To do so, we propose augmented Markov models (AMMs), an approach that combines concepts from probability theory and information theory to consistently treat systematic force-field error and statistical errors in simulation and experiment. Our results demonstrate that AMMs can reconcile conflicting results for protein mechanisms obtained by different force fields and correct for a wide range of stationary and dynamical observables even when only equilibrium measurements are incorporated into the estimation process. This approach constitutes a unique avenue to combine experiment and computation into integrative models of biomolecular structure and dynamics.


2004 ◽  
Vol 39 (3) ◽  
pp. 311-317 ◽  
Author(s):  
Luis Rejano ◽  
Antonio de Castro ◽  
Antonio H. Sanchez ◽  
Francisco J. Casado ◽  
Alfredo Montano
Keyword(s):  

Author(s):  
O. L. Moskalenko ◽  
O. V. Smirnova ◽  
E. V. Kasparov ◽  
I. E. Kasparova

The article is devoted to the study of the psychological characteristics of the behavior of patients with non-alcoholic fatty liver disease (NAFLD). The manifestations of NAFLD are a powerful frustrating factor for patients, negatively affect the quality of life, hinder psychosocial adaptation and serve as the basis for the formation of chronic stress from the disease, which blocks the actual needs of the individual. Psychological factors are an important component in the clinical assessment of patients in connection with the individualization of the treatment process and secondary psychoprophylaxis, including methods of somato-centered and personality-centered psychotherapy.


1992 ◽  
Vol 271 ◽  
Author(s):  
Charles D. Gagliardi ◽  
Dilum Dunuwila ◽  
Beatrice A. Van Vlierberge-Torgerson ◽  
Kris A. Berglund

ABSTRACTTitanium alkoxides modified by carboxylic acids have been widely studied as the molecular precursors to ceramic materials. These alkoxide complexes have also been very useful in the formation of stable, porous, optically clear films having many novel applications such as chemical sensors, catalytic supports, and ion-exchange media. To improve the processing of these materials, it is essential to better understand the kinetics of the chemical transformations which occur.The kinetics of the hydrolysis reaction are studied for selected carboxylic acids using Raman spectroscopy to probe the chemistry of the process. The study has a special emphasis on the titanium isopropoxide-valeric acid system due to the superior quality of these films over other carboxylates. Greater knowledge of the hydrolysis kinetics allows increased control over the quality of the film materials and should be of general interest to those working with modified metal alkoxides.


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