scholarly journals Chlorine as a Discriminant Element to Establish the Provenance of Central Mediterranean Obsidians

2020 ◽  
Vol 6 (1) ◽  
pp. 454-476
Author(s):  
Franco Foresta Martin ◽  
Silvio G. Rotolo ◽  
Manuela Nazzari ◽  
Maria Luisa Carapezza
Keyword(s):  
Electron Microprobe ◽  
Minor Element ◽  
Igneous Rocks ◽  
Chlorine Concentration ◽  
Silicate Melts ◽  
Alkali Content ◽  
Central Mediterranean ◽  
A Minor

Abstract Chlorine is a minor element present in obsidians in quantities greater than in average igneous rocks. The chlorine concentration in obsidians is generally low, of the order of tenths of wt %, but it exhibits an appreciable differentiation among geological sources. Despite these characteristics, chlorine has rarely been taken into consideration as a possible indicator of obsidian provenance and it does not appear in the chemical analytical tables accompanying the geochemical characterisation of obsidian samples. In this work, after an overview of chlorine geochemistry and cycle, we present thirty-one new electron microprobe (EPMA) analyses, including Cl, of geologic obsidians sampled from the four sources of the Central Mediterranean, exploited in prehistoric times (Monte Arci, Palmarola, Lipari and Pantelleria). The results are compared with 175 new EPMA analyses, including Cl, of archaeological obsidians already characterised in previous work and of known provenance. As such it was possible to ascertain that each source has a characteristic chlorine concentration, showing the utility of its use in the studies of obsidian provenance. Furthermore, given that the solubility of chlorine in silicate melts is correlated to its alkali content, in particular sodium, we assessed the efficacy of simple binary graphs Cl vs Na2O to better constrain the provenance of the obsidian samples.

Igneous Rocks, Meteorites, and Fluid-Rock Interactions

1999 ◽  
Author(s):  
Robert E. Criss
Keyword(s):  
Oxygen Isotope ◽  
Isotope Geochemistry ◽  
Minor Element ◽  
Limited Range ◽  
Igneous Rocks ◽  
Iron Core ◽  
The Moon ◽  
Mafic Lavas ◽  
A Minor ◽  
Ocean Ridge

Oxygen is the most important element in common, rock-forming minerals. Earth’s crust and mantle contain about 44 wt. % oxygen, and even with its dense iron core, the bulk Earth is estimated to be approximately 30% oxygen. Considering the low mass and large size of the oxygen atom, the oxygen content is even higher if expressed in terms of vol. % or mol. %. For the above reason, a central problem of stable isotope geochemistry is to explain the distribution of oxygen isotope ratios in rocks. As shown in this chapter, much of the diversity in the abundance ratios is related to interactions of rocks with Earth’s extensive hydrosphere, which is nearly 89 wt. % oxygen. Even though hydrogen is only a minor element in rocks, some discussion of hydrogen isotopes is included here because they provide powerful complementary relationships to evaluate fluid-rock interactions. It has been suspected for centuries, and has now been proven by oxygen isotope data (see later), that Earth and the Moon have very similar origins. In particular, the δ18O values of large rock reservoirs on the Moon and Earth are practically identical. Diverse lunar lithologies have remarkably uniform values ranging only from +5.4 to +6.8 relative to SMOW, with the subset of lunar igneous rocks showing even less variation at +5.7 ± 0.2 (Epstein and Taylor, 1971; Taylor and Epstein, 1973). The same limited range of values is found for the largest lithologic reservoirs on Earth. For example, mid-ocean ridge (MOR) basalts are the most abundant igneous rock type on Earth, and cover practically the entire ocean floor. The δ18O values of these basalts are practically uniform at +5.7 ± 0.5 (Kyser, 1986). Similarly, other mafic lavas, as well as peridotites, pyroxenites, and practically all other mantle materials with the exception of the ophiolites and eclogites, have δ18O values in the restricted range of +5.0 to +8.0. Moreover, no apparent secular trend over geologic time has been found in the bulk δ18O values of these reservoirs. For these reasons, it is likely that the bulk δ18O values of Earth and the Moon are identical and very close to +5.7 ± 0.2.

SATOUMI APPROACH FOR REALIZING SUSTAINABLE COASTAL USE IN A RIASTYPE BAY: A CASE OF SHIZUGAWA BAY IN SANRIKU COAST HIT BY THE HUGE TSUNAMI ON 11 MARCH 2011

2017 ◽  
Author(s):  
Teruhisa Komatsu ◽  
Teruhisa Komatsu ◽  
Shuji Sasa ◽  
Shuji Sasa ◽  
Shigeru Montani ◽  
...  
Keyword(s):  
Local Governments ◽  
Minor Element ◽  
Coupling Model ◽  
Sanriku Coast ◽  
High Productivity ◽  
Biological Coupling ◽  
Miyagi Prefecture ◽  
Human Use ◽  
A Minor ◽  
Aquaculture Facilities

Rias-type bays are one of the most common coasts in Japan where aquacultures have been active due to sheltered geological shape with a deep bottom. The huge tsunami hit Sanriku Coast consisting of open rias-type bays near the epicenter facing Pacific Ocean on 11 March 2011. For recovering Sanriku Coast, it is important to include sustainability in its program. Satoumi is defined as the human use and management of coastal seas for high productivity while maintaining high biodiversity. Therefore, we proposed Satoumi approach to an open rias-type bay, Shizugawa Bay, in southern Sanriku Coast. We conducted scientific researches on mapping of coastal habitats and aquaculture facilities, hydrography, and material flows of nutrients, a minor element (Fe) and organic matters in the bay including those from the rivers and from the offshore waters. At the same time, Committee for Shizugawa Bay Management of Fishermen’s Cooperative of Miyagi Prefecture decided to decrease in aquaculture facilities for sustainable development of aquaculture. Based on these data, a physical-biological coupling model was used for calculating the number of aquaculture facilities that are suitable not only for yields but also for environments. These researches were established on strong collaborations among a fishermen’s’ cooperative, local governments and scientists. Results of this practice may help to realize sustainable coastal use of a rias-type bay.

Diffusivity, Solubility and Speciation of Sulphur in Silicate Melts

2006 ◽  
Vol 46 ◽  
pp. 93-97 ◽  
Author(s):  
J. Stelling ◽  
Harald Behrens ◽  
Joachim Deubener ◽  
Stefan Mangold ◽  
Joerg Goettlicher
Keyword(s):  
High Temperature ◽  
Electron Microprobe ◽  
Industrial Production ◽  
Silicate Melts ◽  
Viscosity Data ◽  
Decomposition Products ◽  
X Ray ◽  
Diffusion Couple Technique ◽  
X Ray Absorption ◽  
Diffusion Profiles

Diffusion and solubility of sulphur have important effects on the degassing of silicate melts. Both properties are closely related to the structural incorporation of sulphur in the melt. Depending on the oxygen fugacity, sulphur can be present as sulphide (S2-), sulphite (S4+) or sulphate (S6+). Sulphates play an important role in the industrial production of glasses especially in the fining process. The decomposition products of sulphate amass in bubbles which ascend and homogenize the melt. Structural incorporation of sulphur in glasses is studied by XANES (X-ray Absorption Near Edge Spectroscopy). Diffusion of sulphur is investigated in simple silicate systems using the diffusion couple technique. First diffusion profiles were measured in sodium trisilicate glasses by electron microprobe. The results indicate that sulphur diffusivity in high temperature melts is close to the Eyring diffusivity calculated from viscosity data.

scholarly journals Rinkite–nacareniobsite-(Ce) solid solution series and hainite from the Ilímaussaq alkaline complex: occurrence and compositional variation

2014 ◽  
Vol 62 ◽  
pp. 1-15
Author(s):  
Jørn G. Rønsbo ◽  
Henning Sørensen ◽  
Encarnacion Roda-Robles ◽  
François Fontan ◽  
Pierre Monchoux
Keyword(s):  
Solid Solution ◽  
Electron Microprobe ◽  
Compositional Variation ◽  
Solid Solution Series ◽  
Alkaline Complex ◽  
Full Extension ◽  
X Ray ◽  
Solution Series ◽  
Compositional Variations ◽  
A Minor

In the Ilímaussaq alkaline complex, minerals from the rinkite–nacareniobsite-(Ce) solid solution series have been found in pulaskite pegmatite, sodalite foyaite, naujaite and naujaite pegmatite from the roof sequence, and in marginal pegmatite, kakortokite and lujavrite from the floor sequence. The electron microprobe analyses embrace almost the full extension of the solid solution series and confirm its continuity. The solid solution series shows similar compositional variations in the roof and floor sequences: Rinkite members of the series are found in the less evolved rocks in the two sequences, whereas nacareniobsite-Ce members occur in the most evolved rocks and pegmatites in the two sequences. The REE (+Y) content varies from 0.83 atoms per formula unit (apfu) in rinkite from pulaskite pegmatite to 1.31 apfu in nacareniobsite-(Ce) from naujaite pegmatite. The main substitution mechanisms in the solid solution series investigated in this work are 2Ca2+ = Na+ + REE3+ and Ti4+ + Ca2+ = Nb5+ + Na+. The increased contents of Nb5+ and REE3+ are only to a minor degree compensated through the F1– = O2– substitution. The chondrite normalised REE patterns of the minerals develop in a similar way in the two sequences, showing relative La-enrichment and Y-depletion from the less to the most evolved rocks. Hainite has not previously been found in the Ilímaussaq complex. It was here identified in a pulaskite pegmatite sample by a combination of X-ray diffraction giving the unit cell dimensions a = 9.5923(7) Å, b = 7.3505(5) Å, c = 5.7023(4) Å, α = 89.958(2)°, β = 100.260(1)°, γ = 101.100(2)°, and X-ray powder pattern and electron microprobe data giving the empirical formula (Ca1.62 Zr0.16Y 0.22) (Na0.87Ca1.11) (Ca 1.65 REE0.35)Na(Ti0.81Nb0.09Fe0.08 Zr0.02)(Si2O7)2O0.99F2.96. Based on published and the present data it is documented that minerals from the hainite-götzenite solid solution series show a compositional variation between the ideal end members (Y,REE,Zr)Na2Ca4Ti(Si2O7)2OF3 and NaCa6Ti(Si2O7)2OF3.

scholarly journals The Motive Of Crime In Foreign Law: A Comparative Legal Analysis

2019 ◽  
pp. 145-154
Author(s):  
Yu.V. Leka
Keyword(s):  
Legal Status ◽  
State Level ◽  
Minor Element ◽  
Legal Analysis ◽  
Foreign Countries ◽  
European Standards ◽  
Basic Approaches ◽  
A Minor ◽  
Criminal Legislation ◽  
Subjective Side

The article substantiates the need to carry out a comparative legal analysis of Ukrainian and foreign legislation on fixing the motive of the crime and its criminal- legal significance. Comparative analysis of the laws of foreign countries is made taking into account the membership of countries in the legal systems. The research of the legal status of the motive of crime in the legislation of foreign countries was carried out on the basis of consideration of basic acts of criminal legislation approved at the state level by the higher legislative bodies of a state. The analysis of various approaches to determining the motive of the crime based on the works of foreign and domestic scientists. On the basis of consideration of normative legal acts of criminal nature of foreign countries, the main terms, which indicate the motive of the crime are defined. The basic approaches of fixing the motive of crime in the legislation of foreign countries are defined and the ways of improvement of the Ukrainian legislation in this matter are proposed. It has been established that the legislation of some countries clearly traces the role of motive as a circumstance aggravating punishment and as a sign that must be taken into account directly in sentencing. In spite of this, most countries still hold a position of indifference to the motive of the crime, recognizing it as a minor element of the subjective side of the crime. It is established that the position of the Ukrainian legislator on the optionality of the sign of motive among other constituents of the subjective side of the crime and the obligatory sign among the elements of evidence in the criminal process is quite logical and justified. But many aspects related to the motive for the crime must be refined. Ukrainian legislation, including criminal law, become more progressive every year and meets European standards.

Silurian acastacean trilobites of the Americas

1993 ◽  
Vol 67 (4) ◽  
pp. 535-548 ◽  
Author(s):  
Gregory D. Edgecombe
Keyword(s):  
Minor Element ◽  
South American ◽  
A Minor ◽  
North And South

Species of the superfamily Acastacea constitute a minor element of North and South American Silurian trilobite faunas. Phacopidina? obsoleta (Ulrich and Delo) (Llandovery, Tennessee) provides the sole Silurian record of the “kloucekiine” grade (Acastacea s.l.); a lectotype is designated for this species. Acaste birminghamensis Norford (mid Llandovery, Alabama) lacks synapomorphies of post-Llandovery Acastidae s.s. (=Acastinae + “Acastavinae” + Asteropyginae), and is the basis for Llandovacaste n. gen. (Acastidae s.l.). A well-preserved sample of Andinacaste cf. A. ledgrandi Eldredge and Braniša from the Catavi Formation (Ludlow–Přídolí), Bolivia, displays apomorphic characters of the genal spines and hypostome shared with Devonian calmoniids. Coaptative structures, including vincular furrow/pits and “bifurcated” thoracic pleural tips, are documented for Andinacaste; similar enrollment morphologies arose in other acastomorph calmoniids. Poorly known Llandovery acastaceans from Paraguay and Venezuela may represent Andinacaste. Acaste zerinae n. sp. from the Pembroke Formation (Přídolí) of Maine is closely comparable to British late Wenlock A. downingiae (Murchison). The Australian Gedinnian acastine placed in Phacopinae indet. longisulcata (Shergold) is designated Acaste lokii n. sp.

How can a minor element added to a binary amorphous alloy simultaneously improve the plasticity and glass-forming ability?

2013 ◽  
Vol 61 (17) ◽  
pp. 6597-6608 ◽  
Author(s):  
Hong-Kyu Kim ◽  
Mirim Lee ◽  
Kwang-Ryeol Lee ◽  
Jae-Chul Lee
Keyword(s):  
Amorphous Alloy ◽  
Minor Element ◽  
Glass Forming Ability ◽  
Glass Forming ◽  
A Minor

First-Principles Study of Atomic Hydrogen and Oxygen Adsorption on Doped-Iron Nanoclusters

2016 ◽  
Author(s):  
Nishith K. Das ◽  
T. Shoji
Keyword(s):  
Density Functional ◽  
Hydrogen Adsorption ◽  
Density Functional Theory Calculations ◽  
Minor Element ◽  
Oxygen Adsorption ◽  
Ground State Structure ◽  
Small Contribution ◽  
Functional Theory ◽  
Strong Hybridization ◽  
A Minor

Density functional theory calculations have been used to calculate the ground state structure and oxygen and hydrogen adsorption properties of the pure and doped-iron nanoclusters. Small atomic clusters containing two to six atoms have been considered and a single Fe atom has replaced by a minor element i.e. Zr, Ti, and Sc. Doping of a minor element increases the cluster stability and octahedron Fe5Zr is the most stable structure within this study. Zr- and Sc-doped clusters have the highest oxygen and hydrogen adsorption energy. The electronic structure shows a strong hybridization between the metal 3d and oxygen 2p orbitals with a small contribution from metal 4s and 3p orbitals. Additionally, H s and metal 4s states form a new peak below the Fermi energy and a small modification is observed for 3d orbitals near the Fermi level. A small amount of Zr- and Sc-doping into the Fe-based alloys might improve the oxide film adherence.

Chlorite crystallinity as an indicator of metamorphic grade of low-temperature meta-igneous rocks: a case study from the Bükk Mountains, Northeast Hungary

Clay Minerals ◽  
1997 ◽  
Vol 32 (2) ◽  
pp. 205-222 ◽  
Author(s):  
P. Árkai ◽  
D. Sadek Ghabrial
Keyword(s):  
Low Temperature ◽  
Electron Microprobe ◽  
Metamorphic Grade ◽  
Igneous Rocks ◽  
Chemical Compositions ◽  
X Ray Diffraction ◽  
Facies Classification ◽  
Increasing Temperature ◽  
Relative Differences

AbstractX-ray diffraction chlorite crystallinity (ChC) indices and major element chemical compositions of chlorites and bulk rocks were determined and correlated in meta-igneous rocks from different Mesozoic formations in various tectonic units of the Bükk Mountains, NE Hungary. The rocks, of basic to acidic compositions, range from ocean-floor metamorphic prehnite-pumpellyite facies (diagenetic zone) through regional metamorphic prehnite-pumpellyite facies (anchizone) up to the regional metamorphic pumpellyite-actinolite and greenschist facies (epizone). As in the case of meta-sedimentary rocks, chlorite crystallinity can be applied as an empirical, complementary petrogenetic tool to determine relative differences in grades of low-temperature meta-igneous rocks. Electron microprobe and XRD data show that ChC is controlled mainly by the decreasing amounts of contaminants (mixed-layered components or discrete, intergrown phases of mostly smectitic composition) in chlorite with advancing metamorphic grade, up to the epizone. The apparent increase in calculated Aliv content of chlorite with increasing temperature is related to the decrease of these contaminants, as stated earlier by Jiang et al. (1994). On the basis of the significant correlations found between ChC and temperatures, derived by the chlorite-Aliv geothermometer of Cathelineau (1988), both methods may be used for estimating the approximate temperatures of metamorphism, in spite of the contrasting interpretation of chemical data from chlorites obtained by electron microprobe analyses. After determining the effects of changing bulk chemistry on chlorite composition and ChC, the chlorite crystallinity method may complement the correlation of the illite crystallinity-based zonal classification of meta-sediments and the mineral facies classification of meta-igneous rocks.

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