Effects of nano-silicon dioxide surface modification on the morphology and mechanical properties of ABS/PMMA blends

2018 ◽  
Vol 38 (7) ◽  
pp. 617-623
Author(s):  
Jin Ding ◽  
Zhenming Yue ◽  
Jiao Sun ◽  
Jun Gao

Abstract This work analyzed the effects of nano-silicon dioxide (nano-SiO2) fillers on the morphology and mechanical properties of acrylonitrile-butadiene-styrene (ABS)/poly(methyl methacrylate) (PMMA) blends. Nano-SiO2 particles were selectively dispersed in the PMMA phase, and the toughness of the ternary blends was significantly improved when the contents of the nano-SiO2 fillers were below 2 wt%. The stearic acid treatment of nano-SiO2 particles prevented the adhesion between constituents and markedly diminished the toughness of the blends. Nano-SiO2 particles were alternatively treated with a silane coupling agent to promote adhesion. The toughness was better in blends for filler contents below 2 wt% than in pure nano-SiO2 particles. However, the presence of nano-SiO2 fillers decreased the surface glossiness of the blends. This work provides new insights into the processes by which nanomaterials toughen ABS/PMMA blends.

2021 ◽  
Vol 1034 ◽  
pp. 101-108
Author(s):  
B. Ramanjaneyulu ◽  
N. Venkatachalapathi ◽  
G. Prasanthi

Binary and ternary blends of poly lactic acid (PLA), acrylonitrile-butadiene-styrene (ABS) and tapioca cassava starch (TCS) were prepared by the help of melt blend method. Rheological and mechanical properties of the prepared blends were studied. Rheological properties were studied using capillary Rheometer, shear rate, shear stress, the non-Newtonian index, were determined .Mechanical properties were studied in terms of tensile properties, stress at break, strain at break and Young's modulus have been determined by help of Universal Test Machine (UTM-3969).The results shows the ternary blends reveals shear-thinning behavior, over the range of the studied shear rates where the true shear rate of the blend decreases while increasing the shear rate. It also found that the true viscosity of the blend decreases with increased ABS content.


2015 ◽  
Vol 659 ◽  
pp. 463-467
Author(s):  
Sirirat Wacharawichanant ◽  
Parida Amorncharoen ◽  
Ratiwan Wannasirichoke

The effects of polypropylene-graft-maleic anhydride (PP-g-MA) compatibilizers on the morphology and mechanical properties of polyoxymethylene (POM)/acrylonitrile-butadiene-styrene (ABS) blends were investigated. Two types of compatibilizers, PP-g-MA with maleic anhydride 0.50 wt% (PP-g-MA1) and PP-g-MA with maleic anhydride 1.31 wt% (PP-g-MA2) were used to study the interfacial adhesion of POM and ABS. POM/ABS blends with and without PP-g-MA compatibilizer were prepared by an internal mixer and molded by compression molding. Scanning electron microscope (SEM) was used to investigate the morphology of ABS phase in POM matrix. The results found that POM/ABS blends clearly demonstrated a two phase separation of dispersed ABS phase and the POM matrix phase, and ABS phase dispersed as spherical domains in POM matrix in a range of ABS 10-30 wt% and the blends containing ABS more than 30 wt% showed the elongated structure of ABS phase. The addition of PP-g-MA could improve the interfacial adhesion of POM/ABS blends due to the domain size of ABS phase decreased after adding PP-g-MA. The mechanical properties showed that the impact strength of POM/ABS blends decreased in a range of 10-20 wt% and did not change after 20 wt%. The addition of PP-g-MA did not change the impact strength of POM/ABS blends. The Young’s modulus of POM/ABS blends increased up to 30 wt% of ABS and then decreased. While the blends showed the decrease of tensile strength and percent strain at break with increasing ABS content. The addition of PP-g-MA increased the tensile strength of POM/ABS blends in a range of 30-40 wt% of ABS. The above results indicated that the morphology had an effect on the mechanical properties of polymer blends.


e-Polymers ◽  
2012 ◽  
Vol 12 (1) ◽  
Author(s):  
Wei Yan ◽  
Shuhao Qin ◽  
Jianbing Guo, ◽  
Min He ◽  
Minmin Zhang ◽  
...  

AbstractIn this article, polyamide 6(PA6)/organoclay masterbatch were prepared by melt mixing, and then acrylonitrile-butadiene-styrene(ABS)/polyamide 6(PA6)(70/30,w/w) nanocomposites were prepared by the melt mixing of PA6, ABS and organoclay. The effect of organoclay platelets on morphology and mechanical properties of ABS/PA6/organoclay ternary nanocomposites had been investigated by wide angle X-ray diffraction (WAXD) and transmission electron microscopy (TEM), scanning electron microscopy (SEM) and mechanical properties testing. Morphology analysis revealed that organoclay platelets were selectively dispersed and exfoliated in PA6 phase, but some were located in interface of PA6 and ABS phase. The droplet size of PA6 dispersed phase were gradually reduced less than 4 phr organoclay, then the dispersed domain size became unchanged with the addition of various organoclay. It suggested the organoclay can compatibilize the ABS/PA6 blend nanocomposite. Moreover, the flexural strength and modulus increase with increasing organoclay content, but the tensile strength became maximal at 3 phr organoclay. The organoclay has no effect on impact strength of ABS/PA6 blend nanocomposite.


2014 ◽  
Vol 496-500 ◽  
pp. 327-330
Author(s):  
Shou Hai Wang ◽  
Jun Gao ◽  
Shu Xia Lin ◽  
Ping Zhang ◽  
Jun Huang ◽  
...  

Ethylene methacrylate (EMA) copolymer toughened acrylonitrile-butadiene-styrene (ABS)/polymethyl methacrylate (PMMA) were prepared in a co-rotating twin-screw extruder. The effect of EMA on mechanical properties and surface gloss of ABS/PMMA blends was investigated. Experiment results show that the toughness of ABS/PMMA is improved effectively with the incorporation of EMA, while the tensile strength and glossiness decrease slightly. ABS/PMMA/EMA blends present optimum mechanical and luster properties when the content of EMA is 6wt%.


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