Foaming and rheological properties of aqueous solutions: an interfacial study

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Badri Vishal
Keyword(s):  
Rheological Properties ◽  
Industrial Applications ◽  
Bubble Surface ◽  
Point Of View ◽  
Interfacial Rheology ◽  
Foaming Agents ◽  
Aqueous Foam ◽  
Air Water Interface ◽  
Foam Rheology ◽  
Low Shear

Abstract Although aqueous foam is composed of simple fluids, air and water, it shows a complex rheological behavior. It exhibits solid-like behavior at low shear and fluid-like behavior at high shear rate. Therefore, understanding such behavior is important for many industrial applications in foods, pharmaceuticals, and cosmetics. Additionally, air–water interface of bubble surface plays an important role in the stabilizing mechanism of foams. Therefore, the rheological properties associated with the aqueous foam highly depend on its interfacial properties. In this review, a systematic study of aqueous foam are presented primarily from rheology point of view. Firstly, foaming agents, surfactants and particles are described; then foam structure was explained, followed by change in structure under applied shear. Finally, foam rheology was linked to interfacial rheology for the interface containing particles whose surface properties were altered by surfactants.

scholarly journals Structure and rheology of macromolecular systems at interfaces

2015 ◽  
Author(s):  
Αντιγόνη Θεοδωράτου
Keyword(s):  
Rheological Properties ◽  
Light Stimulus ◽  
Interfacial Rheology ◽  
Water Interface ◽  
Molecular Architecture ◽  
Molecular Weights ◽  
Air Water Interface ◽  
2D Polymers ◽  
Pressure Area ◽  
Double Wall

This thesis focuses on the structural and rheological properties of viscoelastic filmsat the air-water interface. Our aim is to tailor the rheological properties of fluid interfacesand link them with their structure at the molecular scale. Langmuir quasimonolayerswere built by employing three different types of molecular systems, a seriesof semifluorinated alkanes that consist of two hydrophobic segments, a homopolymer,Poly(methyl methacrylate) (PMMA), and block copolymers of PEO-PDMS with differentmolecular architectures. The techniques employed in this thesis include LangmuirPockelstrough, to measure surface pressure/ area isotherms, and the magnetic rod interfacialstress rheometer, double wall ring fixture and bi-conical device in commercialrheometers for interfacial rheology studies. For structural studies of the films at theair-water interface we performed neutron reflectivity measurements and scanning forcemicroscopy.We observed great tunability of the structural and rheological properties of thesemifluorinated alkanes moving from simple linear molecules to more complex andbranched architectures, showing that molecular modification can change dramaticallythe viscoelastic response of the layers. Regardless of the molecular architecture effect,the external light stimulus effect was investigated for photo-sensitive semifluorinatedalkanes that could change their conformation reversibly from trans to cis. One of themain findings of this study was the transition from ordered to mixed (disordered) structureswhose onset is signaled by the drop of the interfacial storage modulus of aboutone order of magnitude.The predominantly elastic layers of PMMA were used to investigate the presence ofeven harmonics among different rheometry techniques. By analysing the strain signalin the Fourier space, it was found that the bi-conical and the double wall ring fixture do not generate even harmonics while the magnetic rod showed the presence of 2ndharmonics that are connected with asymmetry in the stress-strain profile, apparentlystemming from ununiformity in flow and the subphase contribution.Finally, the diblock and triblock copolymers of PEO-PDMS exhibit perfectly reversiblelayers at the air-water interface showing a reproducible PDMS phase transitionfor all the different molecular weights. Moreover, the average Flory radius of the polymersscale as RF∼N ν , with ν=0.56±0.01. Such result are in agreement with predictedscaling for 2D-polymers in bad solvent conditions.

Enzyme Promiscuous Activity: How to Define it and its Evolutionary Aspects

2020 ◽  
Vol 27 (5) ◽  
pp. 400-410
Author(s):  
Valentina De Luca ◽  
Luigi Mandrich
Keyword(s):  
Gene Evolution ◽  
Sequence Divergence ◽  
High Specificity ◽  
Industrial Applications ◽  
Point Of View ◽  
Enzyme Promiscuity ◽  
Primary Activity ◽  
Starting Point ◽  
Main Activity

: Enzymes are among the most studied biological molecules because better understanding enzymes structure and activity will shed more light on their biological processes and regulation; from a biotechnological point of view there are many examples of enzymes used with the aim to obtain new products and/or to make industrial processes less invasive towards the environment. Enzymes are known for their high specificity in the recognition of a substrate but considering the particular features of an increasing number of enzymes this is not completely true, in fact, many enzymes are active on different substrates: this ability is called enzyme promiscuity. Usually, promiscuous activities have significantly lower kinetic parameters than to that of primary activity, but they have a crucial role in gene evolution. It is accepted that gene duplication followed by sequence divergence is considered a key evolutionary mechanism to generate new enzyme functions. In this way, promiscuous activities are the starting point to increase a secondary activity in the main activity and then get a new enzyme. The primary activity can be lost or reduced to a promiscuous activity. In this review we describe the differences between substrate and enzyme promiscuity, and its rule in gene evolution. From a practical point of view the knowledge of promiscuity can facilitate the in vitro progress of proteins engineering, both for biomedical and industrial applications. In particular, we report cases regarding esterases, phosphotriesterases and cytochrome P450.

scholarly journals Suboptimal Disturbance Observer Design Using All Stabilizing Q Filter for Precise Tracking Control

Mathematics ◽  
2020 ◽  
Vol 8 (9) ◽  
pp. 1434 ◽  
Author(s):  
Wonhee Kim ◽  
Sangmin Suh
Keyword(s):  
Design Method ◽  
Industrial Applications ◽  
Point Of View ◽  
Observer Design ◽  
Linear Matrix ◽  
External Disturbances ◽  
Closed Loop Systems ◽  
Control Target ◽  
The Stability ◽  
Unified Index

For several decades, disturbance observers (DOs) have been widely utilized to enhance tracking performance by reducing external disturbances in different industrial applications. However, although a DO is a verified control structure, a conventional DO does not guarantee stability. This paper proposes a stability-guaranteed design method, while maintaining the DO structure. The proposed design method uses a linear matrix inequality (LMI)-based H∞ control because the LMI-based control guarantees the stability of closed loop systems. However, applying the DO design to the LMI framework is not trivial because there are two control targets, whereas the standard LMI stabilizes a single control target. In this study, the problem is first resolved by building a single fictitious model because the two models are serial and can be considered as a single model from the Q-filter point of view. Using the proposed design framework, all-stabilizing Q filters are calculated. In addition, for the stability and robustness of the DO, two metrics are proposed to quantify the stability and robustness and combined into a single unified index to satisfy both metrics. Based on an application example, it is verified that the proposed method is effective, with a performance improvement of 10.8%.

Educational Model for the Kinematic Study of Non-Circular Gears

2013 ◽  
Vol 332 ◽  
pp. 297-304
Author(s):  
Liviu Ciupitu
Keyword(s):  
Numerical Methods ◽  
Industrial Applications ◽  
Point Of View ◽  
Spur Gears ◽  
Test Rig ◽  
Educational Model ◽  
Educational Test ◽  
Kinematic Study ◽  
Variation Curve ◽  
Noncircular Gears

The noncircular gears are used more and more in industrial applications. The paper presents an educational test rig for the kinematic study of non-circular gears. Two gears are studied from kinematic theoretically point of view: a gear with identically oval spur gears and another gear with identically elliptical spur gears, and simulation diagrams are presented. As for the testing rig, a gear with identically oval spur gears has been used. The researchers are able to draw with high precision the variation curve of output angle with respect to input angle. By using numerical methods for integration and differentiation other diagrams could be drawn and a comparation with simulation diagrams could be made.

Characterisation of supersonic gas jets for different nozzle geometries for laser-plasma acceleration experiments at SPARC_LAB

2022 ◽  
Vol 17 (01) ◽  
pp. C01049
Author(s):  
G. Costa ◽  
M.P. Anania ◽  
A. Biagioni ◽  
F.G. Bisesto ◽  
M. Del Franco ◽  
...  
Keyword(s):  
High Power ◽  
Plasma Channel ◽  
Laser Pulses ◽  
Industrial Applications ◽  
Point Of View ◽  
Theoretical Point ◽  
High Power Laser ◽  
Power Laser ◽  
Neutral Gas ◽  
Nozzle Geometries

Abstract Plasma-based technology promises a tremendous reduction in size of accelerators used for research, medical, and industrial applications, making it possible to develop tabletop machines accessible for a broader scientific community. The use of high-power laser pulses on gaseous targets is a promising method for the generation of accelerated electron beams at energies on the GeV scale, in extremely small sizes, typically millimetres. The gaseous target in question can be a collimated supersonic gasjet from a nozzle. In this work, a technique for optimising the so generated plasma channel is presented. In detail, a study on the influence of the nozzle throat shape in relation to the uniformity and density of the generated plasma profile is reported. These considerations are discussed first of all from a theoretical point of view, by means of a stationary one-dimensional mathematical model of the neutral gas, thus exploiting the possibility of comparing the properties of the output flow for different nozzle geometries. This is combined with an experimental approach using interferometric longitudinal density measurements of the plasma channel. The latter is generated by a high-power laser pulse focused on a helium gasjet, in the SPARC_LAB laboratories.

scholarly journals Bioaccessibility of Marine Carotenoids

Marine Drugs ◽  
2018 ◽  
Vol 16 (10) ◽  
pp. 397 ◽  
Author(s):  
Isabel Viera ◽  
Antonio Pérez-Gálvez ◽  
María Roca
Keyword(s):  
Pharmaceutical Industry ◽  
Human Health ◽  
Industrial Production ◽  
Food Industry ◽  
Industrial Applications ◽  
Point Of View ◽  
Market Area ◽  
Biological Functions ◽  
Determination Methods ◽  
Nutraceutical Properties

The benefit of carotenoids to human health is undeniable and consequently, their use for this purpose is growing rapidly. Additionally, the nutraceutical properties of carotenoids have attracted attention of the food industry, especially in a new market area, the ‘cosmeceuticals.’ Marine organisms (microalgae, seaweeds, animals, etc.) are a rich source of carotenoids, with optimal properties for industrial production and biotechnological manipulation. Consequently, several papers have reviewed the analysis, characterization, extraction and determination methods, biological functions and industrial applications. But, now, the bioaccessibility and bioactivity of marine carotenoids has not been focused of any review, although important achievements have been published. The specific and diverse characteristic of the marine matrix determines the bioavailability of carotenoids, some of them unique in the nature. Considering the importance of the bioavailability not just from the health and nutritional point of view but also to the food and pharmaceutical industry, we consider that the present review responds to an actual demand.

scholarly journals ANNEALING OF UNFERMENTED (POLVILHO DOCE) AND FERMENTED (POLVILHO AZEDO) CASSAVA STARCHES

2010 ◽  
Vol 28 (2) ◽  
Author(s):  
ANIDA MARIA MORAES GOMES ◽  
CLÁUDIO ERNANI MENDES DA SILVA ◽  
PALOMA LIMA DA SILVA ◽  
NÁGILA MARIA PONTES SILVA RICARDO ◽  
MARIA ISABEL GALLÃO
Keyword(s):  
Rheological Properties ◽  
Food Industry ◽  
Annealing Treatment ◽  
Point Of View ◽  
Swelling Power ◽  
Double Helices ◽  
Power Peak ◽  
Waxy Starch ◽  
Pasting Temperature

The effects of annealing on the properties of unfermented (polvilho doce-PD) and fermented (polvilho azedo-PAD) cassava starches were studied. The samples were submitted to annealing treatment for 24, 72, 96, 144, 192 and 240 hours. The annealing treatment changed the main physicochemical (gelatinization, enthalpy and temperature) and rheological properties (swelling power, peak viscosity and pasting temperature) of the both samples. The increase in the gelatinization temperatures and the narrowing of the gelatinization range was attributed to an reinforcement in the packing of the double helices of the amylopectin. The PAD samples seemed to be more affected by this treatment than PD ones. The PAD samples presented some characteristics of a waxy starch, such as increased crystallinity and increased stability of the pastes, which from a technological point of view is very important to diversify further its use in the food industry.

scholarly journals Application of Depletion Attraction in Mineral Flotation: II. Effects of Depletant Concentration

Minerals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 450 ◽  
Author(s):  
Gahee Kim ◽  
Junhyun Choi ◽  
Sowon Choi ◽  
KyuHan Kim ◽  
Yosep Han ◽  
...  
Keyword(s):  
Surface Tension ◽  
Polymer Brush ◽  
Bubble Surface ◽  
Mass Ratio ◽  
Attraction Force ◽  
Surface Acting ◽  
Pure Silica ◽  
Mineral Flotation ◽  
Air Water Interface ◽  
High Concentrations

Along with the accompanying theory article, we experimentally investigate the effect of the depletion attraction force on the flotation of malachite. While varying the concentration of the depletion agent (polyethylene glycol), three different systems are studied: pure malachite, pure silica and a 1:1 mass ratio of malachite and silica binary system. We find that the recovery increases significantly as the concentration of the depletion reagents increases for all three systems. However, the recovery suddenly decreases in a certain concentration range, which corresponds to the onset of the decreased surface tension when high concentrations of the depletion agent are used. The decreased surface tension of the air/water interface suggests that the recovery rate is lowered due to the adsorption of the depletion agent to the bubble surface, acting as a polymer brush. We also perform experiments in the presence of a small amount of a collector, sodium oleate. An extremely small amount of the collector (10−10–10−5 M) leads to the increase in the overall recovery, which eventually reaches nearly 100 percent. Nevertheless, the grade worsens as the depletant provides the force to silica particles as well as target malachite particles.

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