Crystal Structure and Magnetic Properties of the Novel Hollandite Ba1.3Co1.3Ti6.7O16

Single crystals of the new barium hollandite Ba1.3Co1.3Ti6.7O16 were obtained from a BaCl2 flux (I2/m, Z = 1, a = 9.9470(4), b = 2.9714(2), c = 10.2260(5) Å , β = 90.906(2)◦). In the crystal structure piles of Ba atoms are situated within a framework of edge- and vertex-sharing octahedra (Co,Ti)O6. The composition was deduced from microprobe analyses, structure refinements and charge balance arguments in agreement with the observed magnetic properties. The temperature dependence of the magnetic susceptibility χ(T) of Ba1.3Co1.3Ti6.7O16 single crystals reveals paramagnetism down to 2 K. The value of the Co magnetic moment deduced from the Curie-Weiss law agrees well with the theoretical value of the high-spin state spin-only moment of μeff = 3.87 μB for Co2+ (S = 3/2)

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Crystal Structure and Magnetic Properties of (2,2'-Dipyridyl)-(2-acetylphenolato)copper(II) Perchlorate

Zeitschrift für Naturforschung B ◽

10.1515/znb-2002-1009 ◽

2002 ◽

Vol 57 (10) ◽

pp. 1129-1132 ◽

Cited By ~ 3

Author(s):

A. Elmali ◽

Y. Elerman ◽

I. Svoboda

Keyword(s):

Crystal Structure ◽

Magnetic Properties ◽

Magnetic Susceptibility ◽

Magnetic Moment ◽

Basal Plane ◽

Effective Magnetic Moment ◽

Mixed Ligand ◽

Magnetic Susceptibility Data ◽

Susceptibility Data ◽

Dimeric Unit

The mixed-ligand dinuclear complex (2,2'-dipyridyl)-(2-acetylphenolato)copper(II) perchlorate was synthesized and its crystal structures determined. The structure consists of a dimeric unit involving a planar Cu2O2 group. The coordination sphere of the Cu atom can be described as an alongated octahedron where the basal plane is formed by the two N atoms of the 2,2'-dipyridyl molecule and the two O atoms of the acetophenon anion. Two apical Cu - O contacts complete the 4+2 coordination of the Cu atoms. They correspond to one of the O atoms of the perchlorate anion and to the O atom of the second unit. Magnetic susceptibility data obey the Curie-Weiss law with θ = -8.1(2) K. The decreasing of the effective magnetic moment from 1.94(8) μB at 300 K to 1.86(8) μB at 70 K and the negative Weiss constant indicate weak antiferromagnetic interactions between the two copper atoms in the dimeric units.

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Structure and Magnetic Properties of a Dinuclear Complex with Iron(III) in Octahedral and Pyramidal Coordination

Zeitschrift für Naturforschung B ◽

10.1515/znb-1994-0912 ◽

1994 ◽

Vol 49 (9) ◽

pp. 1239-1242 ◽

Cited By ~ 3

Author(s):

Ayhan Elmali ◽

Yalcin Elerman ◽

Ingrid Svoboda ◽

Hartmut Fuess ◽

Klaus Griesar ◽

...

Keyword(s):

Crystal Structure ◽

Magnetic Properties ◽

Magnetic Susceptibility ◽

Magnetic Moment ◽

Effective Magnetic Moment ◽

Dinuclear Complex ◽

Monoclinic Space Group ◽

Temperature Dependent ◽

Space Group ◽

Binuclear Unit

[FeL(MeOH)Cl]2 (L = N-(2-hydroxyphenyl)salicylaldimine) was synthesized and its crystal structure determined, [C27H20N 2O5Cl2Fe2], monoclinic, space group P21/c, a = 9.528(1), b = 7.684(1), c = 18.365(2) Å, β = 109.83(1)°, V = 1264.8 Å3, Z = 2. Two identical [FeL(MeOH)Cl] fragments, related by an inversion centre, are combined by the two bridging O atoms, to form a binuclear unit. The iron(III) centers are separated by 3.163(2) Å and weakly antiferromagnetically coupled (J = -8 .0 (1 ) cm-1), which follows from temperature - dependent magnetic susceptibility measurements in the range 4.2 to 288 K. The effective magnetic moment per iron(III) is μeff = 7.4 μB at 288 K

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Magnetic Properties and Crystal Structure of a 3,5-Dimethylpyrazolate-Bridged Binuclear Copper(II) Complex

Zeitschrift für Naturforschung B ◽

10.1515/znb-2001-1002 ◽

2001 ◽

Vol 56 (10) ◽

pp. 970-974 ◽

Cited By ~ 4

Author(s):

Y. Elerman ◽

A. Elmali

Keyword(s):

Crystal Structure ◽

Magnetic Properties ◽

Magnetic Susceptibility ◽

Dihedral Angle ◽

Coordination Sphere ◽

Magnetic Moment ◽

Binuclear Copper ◽

Temperature Dependent ◽

Orthorhombic Space Group ◽

Square Planar

[Cu2L(prz)] (prz = 3,5-dimethylpyrazole and L = 1,3-bis(5-bromo-2-hydroxybenzylidene)- propan-2-ol) was synthesized and its crystal structure determined. It crystallizes in the orthorhombic space group Pbca with a = 14.160(9), b = 15.109(4), c = 21.298(5) Å, V = 4557(1) A3, Z = 8 . Two copper(II) ions are in a square-planar coordination. The metal coordination sphere is four-coordinate, with a planar N2O2 donor set. The dihedral angle between the two coordination planes is 12.14(7)°. The copper(II) centers are separated by 3.365(1) Å and antiferromagnetically coupled (J = -214.3 cm-1), which follows from temperature-dependent magnetic susceptibility measurements in the temperature range 4.6 to 310 K. The Cu-O-Cu angle is 125.9(1)° in the super-exchange pathway. The magnetic moment at 310 K is ca. 1.76 B.M. and 0.13 B.M. at 4.6 K.

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Magnetic Properties and Crystal Structure of a Dinuclear Iron(III) Complex

Zeitschrift für Naturforschung B ◽

10.1515/znb-2001-0906 ◽

2001 ◽

Vol 56 (9) ◽

pp. 897-900 ◽

Cited By ~ 11

Author(s):

A. Elmali ◽

Y. Elerman ◽

I. Svoboda

Keyword(s):

Crystal Structure ◽

Magnetic Properties ◽

Magnetic Susceptibility ◽

Liquid Helium ◽

Magnetic Moment ◽

Helium Temperature ◽

Temperature Dependent ◽

Triclinic Space Group ◽

Dinuclear Iron ◽

Binuclear Unit

Abstract [FeL(MeOH)Cl]2 (L = N-(5-methylphenyl)-3-methoxysalicylaldimine) was synthesized and its crystal structure determined, [C30H26Cl2Fe2N2O6], triclinic, space group P1̄, a = 7.481(2), b = 9.436(2), c = 10.961(2) Å, α= 69.790(10), β= 82.440(10), γ= 83.690(10)°, V=718.1(3) Å3 , Z = 1. Two identical [FeLCl] fragments, related by an inversion centre, are connected by two bridging O atoms to form a binuclear unit. The iron(III) centers are separated by 3.196(2) Å and weakly antiferromagnetically coupled (J = -10.4(1) cm-1), which follows from temperature-dependent magnetic susceptibility measurements in the range 5.1 to 275.6 K. The magnetic moment at 275.6 K is ca. 7.02 B. M., but 0.99 B. M. at 5.1 K. The magnetic susceptibility is at a maximum near 80 K and decreases rapidly as the temperature is lowered to liquid helium temperature.

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Some Novel Cobalt Diphenylphosphine Complexes: Synthesis, Characterization, and Behavior in the Polymerization of 1,3-Butadiene

Molecules ◽

10.3390/molecules26134067 ◽

2021 ◽

Vol 26 (13) ◽

pp. 4067

Author(s):

Giovanni Ricci ◽

Giuseppe Leone ◽

Giorgia Zanchin ◽

Benedetta Palucci ◽

Alessandra Forni ◽

...

Keyword(s):

Crystal Structure ◽

Single Crystals ◽

The Novel ◽

X Ray Diffraction ◽

X Ray ◽

And Behavior

Some novel cobalt diphenylphosphine complexes were synthesized by reacting cobalt(II) chloride with (2-methoxyethyl)diphenylphosphine, (2-methoxyphenyl)diphenylphosphine, and 2-(1,1-dimethylpropyl)-6-(diphenylphosphino)pyridine. Single crystals suitable for X-ray diffraction studies were obtained for the first two complexes, and their crystal structure was determined. The novel compounds were then used in association with methylaluminoxane (MAO) for the polymerization of 1,3-butadiene, and their behavior was compared with that exhibited in the polymerization of the same monomer by the systems CoCl2(PnPrPh2)2/MAO and CoCl2(PPh3)2/MAO. Some significant differences were observed depending on the MAO/Co ratio used, and a plausible interpretation for such a different behavior is proposed.

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Single Crystal Growth and Physical Properties of Pyroxene CoGeO3

Crystals ◽

10.3390/cryst11040378 ◽

2021 ◽

Vol 11 (4) ◽

pp. 378

Author(s):

Li Zhao ◽

Zhiwei Hu ◽

Hanjie Guo ◽

Christoph Geibel ◽

Hong-Ji Lin ◽

...

Keyword(s):

High Pressure ◽

Magnetic Properties ◽

Magnetic Susceptibility ◽

Crystal Growth ◽

Physical Properties ◽

Single Crystal ◽

Single Crystals ◽

Magnetic Moments ◽

Single Crystal Growth ◽

The Impact

We report on the synthesis and physical properties of cm-sized CoGeO3 single crystals grown in a high pressure mirror furnace at pressures of 80 bar. Direction dependent magnetic susceptibility measurements on our single crystals reveal highly anisotropic magnetic properties that we attribute to the impact of strong single ion anisotropy appearing in this system with TN∼33.5 K. Furthermore, we observe effective magnetic moments that are exceeding the spin only values of the Co ions, which reveals the presence of sizable orbital moments in CoGeO3.

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Suppression of Ferromagnetism in EuxCa1-xB6

Solid State Phenomena ◽

10.4028/www.scientific.net/ssp.190.97 ◽

2012 ◽

Vol 190 ◽

pp. 97-100 ◽

Cited By ~ 1

Author(s):

V.V. Glushkov ◽

A.V. Kuznetsov ◽

I. Sannikov ◽

A.V. Bogach ◽

S.V. Demishev ◽

...

Keyword(s):

Magnetic Properties ◽

Magnetic Susceptibility ◽

Curie Temperature ◽

Single Crystals ◽

Effective Magnetic Moment ◽

Paramagnetic State ◽

Low Field ◽

Wide Range ◽

Free Ion ◽

The Eu

We report the magnetic properties of EuxCa1-xB6 single crystals (0.756x1) studied in the wide range of temperatures (1.8-300 K) and magnetic fields (up to 50 kOe). It was found that low field magnetic susceptibility χ (T) follows the Curie-Weiss law χ~(T-Θp)-1 at high temperatures for all the concentrations studied. The effective magnetic moment of the Eu2+ ion estimated from the data diminishes from the free ion value μeff7.93μB (μB - Bohr magneton) for x=1 to μeff7.3μB for x=0.756. A universal behavior of magnetic susceptibility χ~(T-Θ)-α (α=1.5) is detected close to the Curie temperature TC in the paramagnetic state at both metallic (x>xC~0.8) and dielectric (xC.

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Magnetic properties of undoped and Co-doped n-type β–FeSi2.5 single crystals

Journal of Materials Research ◽

10.1557/jmr.2002.0429 ◽

2002 ◽

Vol 17 (11) ◽

pp. 2960-2965 ◽

Cited By ~ 4

Author(s):

E. Arushanov ◽

L. Ivanenko ◽

D. Eckert ◽

G. Behr ◽

U. K. Rößler ◽

...

Keyword(s):

Activation Energy ◽

Magnetic Properties ◽

Magnetic Susceptibility ◽

External Field ◽

Single Crystals ◽

Spin Glasses ◽

Paramagnetic Centers ◽

Temperature Dependent ◽

Paramagnetic Curie Temperature ◽

Co Doped

Results of magnetization and magnetic susceptibility measurements on undoped and Co-doped FeSi2.5 single crystals are presented. The temperature dependence of the magnetic susceptibility of the Co-doped sample in the range of 5–300 K can be explained by temperature-dependent contributions due to paramagnetic centers and the carriers excited thermally in the extrinsic conductivity region. The values of the paramagnetic Curie temperature and activation energy of the donor levels were estimated. It is also shown that the magnetic susceptibility of Co-doped samples cooled in zero external field and in a field are different. This resembles the properties of spin-glasses and indicates the presence of coupling between magnetic centers.

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