A tetranuclear copper (II) complex with pyrazole-3,5-dicarboxylate ligands: synthesis, characterization and electrochemical properties
2016 ◽
Vol 71
(4)
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pp. 305-310
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Keyword(s):
X Ray
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AbstractA tetranuclear copper (II) complex with pyrazole-3,5-dicarboxylate ligands (pdc3−), [Me2NH2]4[Cu4(pdc)4], was synthesized using solvothermal and metal oxidation routes and characterized by elemental analysis, infrared, thermogravimetry/differential thermal analysis, and room-temperature magnetic measurements. The structure of the complex was determined by single-crystal X-ray diffraction. It comprises dimethylammonium cations and complex anions containing four Cu2+ cations. The crystal structure is stabilized by N–H···O hydrogen bonds. In addition, the electrochemical behavior was studied.
1996 ◽
Vol 52
(4)
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pp. 697-706
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2021 ◽