An Alternate Electrochemical Procedure for Testing Anodized Aluminum

2009 ◽  
pp. 49-49-10
Author(s):  
PR Roberge ◽  
E Halliop
Keyword(s):  
Anodized Aluminum

Time response of anodized aluminum pressure-sensitive paint

AIAA Journal ◽  
2001 ◽  
Vol 39 ◽  
pp. 1944-1949
Author(s):  
Hirotaka Sakaue ◽  
John P. Sullivan
Keyword(s):  
Time Response ◽  
Pressure Sensitive Paint ◽  
Anodized Aluminum ◽  
Pressure Sensitive

Investigation of Polyoxometalate-(Poly)pyrrole Heterogeneous Nanostructures as Cathodes for Rechargeable Magnesium-Ion Batteries

2018 ◽  
Author(s):  
Hakeem K. Henry ◽  
Sang Bok Lee
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Photoelectron Spectroscopy ◽  
Active Material ◽  
Conductive Polymer ◽  
Current Collector ◽  
Constant Current ◽  
Anodized Aluminum ◽  
Transmission Electron ◽  
Pyrrole Monomer

The PMo<sub>12</sub>-PPy heterogeneous cathode was synthesized electrochemically. In doing so, the PMo<sub>12</sub> redox-active material was impregnated throughout the conductive polymer matrix of the poly(pyrrole) nanowires. All chemicals and reagents used were purchased from Sigma-Aldrich. Anodized aluminum oxide (AAO) purchased from Whatman served as the porous hard template for nanowire deposition. A thin layer of gold of approximately 200nm was sputtered onto the disordered side of the AAO membrane to serve as the current collector. Copper tape was connected to the sputtered gold for contact and the device was sealed in parafilm with heat with an exposed area of 0.32 cm<sup>2</sup> to serve as the electroactive area for deposition. All electrochemical synthesis and experiments were conducted using a Bio-Logic MPG2 potentiostat. The deposition was carried out using a 3-electrode beaker cell setup with a solution of acetonitrile containing 5mM and 14mM of the phosphomolybdic acid and pyrrole monomer, respectively. The synthesis was achieved using chronoamperometry to apply a constant voltage of 0.8V vs. Ag/AgCl (BASi) to oxidatively polymerize the pyrrole monomer to poly(pyrrole). To prevent the POM from chemically polymerizing the pyrrole, an injection method was used in which the pyrrole monomer was added to the POM solution only after the deposition voltage had already been applied. The deposition was well controlled by limiting the amount of charge transferred to 300mC. Following deposition, the AAO template was removed by soaking in 3M sodium hydroxide (NaOH) for 20 minutes and rinsed several times with water. After synthesis, all cathodes underwent electrochemical testing to determine their performance using cyclic voltammetry and constant current charge-discharge cycling in 0.1 M Mg(ClO<sub>4</sub>)<sub>2</sub>/PC electrolyte. The cathodes were further characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), scanning transmission electron microscopy (STEM), and x-ray photoelectron spectroscopy (XPS).

The Ti3.6Nb1.0Ta0.2Zr0.2 coating of anodized aluminum by PVD: A potential candidate for short-time biomedical applications

Vacuum ◽  
2021 ◽  
pp. 110450
Author(s):  
M. Zarka ◽  
B. Dikici ◽  
M. Niinomi ◽  
K.V. Ezirmik ◽  
M. Nakai ◽  
...  
Keyword(s):  
Biomedical Applications ◽  
Potential Candidate ◽  
Anodized Aluminum ◽  
Short Time

scholarly journals Synergistic Effects of Fe2O3 Nanotube/Polyaniline Composites for an Electrochemical Supercapacitor with Enhanced Capacitance

Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1557
Author(s):  
Farkhod Azimov ◽  
Jihee Kim ◽  
Seong Min Choi ◽  
Hyun Min Jung
Keyword(s):  
Electrode Materials ◽  
High Efficiency ◽  
Electrochemical Impedance ◽  
Synergistic Effects ◽  
Structural Development ◽  
Anodized Aluminum ◽  
Anodized Aluminum Oxide ◽  
Inner Diameter ◽  
Polyaniline Composites ◽  
Fe2o3 Nanotubes

α-Fe2O3, which is an attractive material for supercapacitor electrodes, has been studied to address the issue of low capacitance through structural development and complexation to maximize the use of surface pseudocapacitance. In this study, the limited performance of α-Fe2O3 was greatly improved by optimizing the nanotube structure of α-Fe2O3 and its combination with polyaniline (PANI). α-Fe2O3 nanotubes (α-NT) were fabricated in a form in which the thickness and inner diameter of the tube were controlled by Fe(CO)5 vapor deposition using anodized aluminum oxide as a template. PANI was combined with the prepared α-NT in two forms: PANI@α-NT-a enclosed inside and outside with PANI and PANI@α-NT-b containing PANI only on the inside. In contrast to α-NT, which showed a very low specific capacitance, these two composites showed significantly improved capacitances of 185 Fg−1 for PANI@α-NT-a and 62 Fg−1 for PANI@α-NT-b. In the electrochemical impedance spectroscopy analysis, it was observed that the resistance of charge transfer was minimized in PANI@α-NT-a, and the pseudocapacitance on the entire surface of the α-Fe2O3 nanotubes was utilized with high efficiency through binding and conductivity improvements by PANI. PANI@α-NT-a exhibited a capacitance retention of 36% even when the current density was increased 10-fold, and showed excellent stability of 90.1% over 3000 charge–discharge cycles. This approach of incorporating conducting polymers through well-controlled nanostructures suggests a solution to overcome the limitations of α-Fe2O3 electrode materials and improve performance.

scholarly journals Surface Enhanced Raman Spectroscopy With Electrodeposited Copper Ultramicro-Wires With/Without Silver Nanostars Decoration

Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 518
Author(s):  
Margherita Longoni ◽  
Maria Sole Zalaffi ◽  
Lavinia de Ferri ◽  
Angela Maria Stortini ◽  
Giulio Pojana ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Surface Enhanced Raman Spectroscopy ◽  
Anodized Aluminum ◽  
Anodized Aluminum Oxide ◽  
Electrochemical Preparation ◽  
Deposition Parameters ◽  
Raman Enhancement ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Materials Used

The electrochemical preparation of arrays of copper ultramicrowires (CuUWs) by using porous membranes as templates is critically revisited, with the goal of obtaining cheap but efficient substrates for surface enhanced Raman spectroscopy (SERS). The role of the materials used for the electrodeposition is examined, comparing membranes of anodized aluminum oxide (AAO) vs. track-etched polycarbonate (PC) as well as copper vs. glassy carbon (GC) as electrode material. A voltammetric study performed on bare electrodes and potentiostatic tests on membrane coated electrodes allowed the optimization of the deposition parameters. The final arrays of CuUWs were obtained by chemical etching of the template, with NaOH for AAO and CH2Cl2 for PC. After total etching of the template, SERS spectra were recorded on CuUWs using benzenethiol as SERS probe with known spectral features. The CuUW substrates displayed good SERS properties, providing enhancement factor in the 103–104 range. Finally, it was demonstrated that higher Raman enhancement can be achieved when CuUWs are decorated with silver nanostars, supporting the formation of SERS active hot-spots at the bimetallic interface.

scholarly journals Vacuum Venting Enhances the Replication of Nano/Microfeatures in Micro-Injection Molding Process

2016 ◽  
Vol 4 (2) ◽  
Author(s):  
Seong Ying Choi ◽  
Nan Zhang ◽  
J. P. Toner ◽  
G. Dunne ◽  
Michael D. Gilchrist
Keyword(s):  
Injection Molding ◽  
Quantitative Study ◽  
Vacuum Pressure ◽  
Injection Molding Process ◽  
Anodized Aluminum ◽  
Molding Process ◽  
Micro Injection Molding ◽  
Sample Shape ◽  
Final Sample ◽  
Qualitative And Quantitative Study

Vacuum venting is a method proposed to improve feature replication in microparts that are fabricated using micro-injection molding (MIM). A qualitative and quantitative study has been carried out to investigate the effect of vacuum venting on the nano/microfeature replication in MIM. Anodized aluminum oxide (AAO) containing nanofeatures and a bulk metallic glass (BMG) tool mold containing microfeatures were used as mold inserts. The effect of vacuum pressure at constant vacuum time, and of vacuum time at constant vacuum pressure on the replication of these features is investigated. It is found that vacuum venting qualitatively enhances the nanoscale feature definition as well as increases the area of feature replication. In the quantitative study, higher aspect ratio (AR) features can be replicated more effectively using vacuum venting. Increasing both vacuum pressure and vacuum time are found to improve the depth of replication, with the vacuum pressure having more influence. Feature orientation and final sample shape could affect the absolute depth of replication of a particular feature within the sample.

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