BEHAVIOR OF NOBLE METALS DURING FRACTIONAL CRYSTALLIZATION OF Cu–Fe–Ni–(Pt, Pd, Rh, Ir, Ru, Ag, Au, Te) SULFIDE MELTS

2019 ◽  
Keyword(s):  
Fractional Crystallization ◽  
Noble Metals

Behavior of noble metals upon fractional crystallization of copper-rich sulfide melts

2016 ◽  
Vol 469 (2) ◽  
pp. 811-814 ◽  
Author(s):  
V. V. Distler ◽  
E. F. Sinyakova ◽  
V. I. Kosyakov
Keyword(s):  
Fractional Crystallization ◽  
Noble Metals

Arsenic influence on noble metals behavior during fractional crystallization of the Cu-Fe-Ni-S melts

2011 ◽  
Vol 3 (Special Issue) ◽  
pp. 1-7
Author(s):  
E. F. Sinyakova ◽  
V. I. Kosyakov ◽  
K. A. Kokh ◽  
N. S. Karmanov
Keyword(s):  
Fractional Crystallization ◽  
Noble Metals

Growth of near noble metal Pd and Pt thin film silicides morphology and structure

1984 ◽  
Vol 42 ◽  
pp. 498-499
Author(s):  
E. I. Alessandrini ◽  
M. O. Aboelfotoh
Keyword(s):  
Noble Metals ◽  
Annealing Temperature ◽  
Chemical Compounds ◽  
Barrier Properties ◽  
Solid State Reactions ◽  
Transmission Electron ◽  
Stable Chemical ◽  
Metal Thickness ◽  
Amorphous Si ◽  
Si Films

Considerable interest has been generated in solid state reactions between thin films of near noble metals and silicon. These metals deposited on Si form numerous stable chemical compounds at low temperatures and have found applications as Schottky barrier contacts to silicon in VLSI devices. Since the very first phase that nucleates in contact with Si determines the barrier properties, the purpose of our study was to investigate the silicide formation of the near noble metals, Pd and Pt, at very thin thickness of the metal films on amorphous silicon.Films of Pd and Pt in the thickness range of 0.5nm to 20nm were made by room temperature evaporation on 40nm thick amorphous Si films, which were first deposited on 30nm thick amorphous Si3N4 membranes in a window configuration. The deposition rate was 0.1 to 0.5nm/sec and the pressure during deposition was 3 x 10 -7 Torr. The samples were annealed at temperatures in the range from 200° to 650°C in a furnace with helium purified by hot (950°C) Ti particles. Transmission electron microscopy and diffraction techniques were used to evaluate changes in structure and morphology of the phases formed as a function of metal thickness and annealing temperature.

Microstructure and reactivity of small metal particles: The role of Ce additives

1992 ◽  
Vol 50 (1) ◽  
pp. 318-319
Author(s):  
L.D. Schmidt ◽  
K. R. Krause ◽  
J. M. Schwartz ◽  
X. Chu
Keyword(s):  
Atmospheric Pressure ◽  
Noble Metals ◽  
Mixed Oxides ◽  
Catalytic Properties ◽  
Chemical Shifts ◽  
Catalytic Converter ◽  
Structural Evolution ◽  
Single Particles ◽  
Small Metal Particles

The evolution of microstructures of 10- to 100-Å diameter particles of Rh and Pt on SiO2 and Al2O3 following treatment in reducing, oxidizing, and reacting conditions have been characterized by TEM. We are able to transfer particles repeatedly between microscope and a reactor furnace so that the structural evolution of single particles can be examined following treatments in gases at atmospheric pressure. We are especially interested in the role of Ce additives on noble metals such as Pt and Rh. These systems are crucial in the automotive catalytic converter, and rare earths can significantly modify catalytic properties in many reactions. In particular, we are concerned with the oxidation state of Ce and its role in formation of mixed oxides with metals or with the support. For this we employ EELS in TEM, a technique uniquely suited to detect chemical shifts with ∼30Å resolution.

Evolution of the electronic structure of metallic multilayers from two to threedimensionality. A Full Potential Linearized Augmented Plane Wave calculation.

2002 ◽  
Vol 727 ◽  
Author(s):  
A. M. Mazzone
Keyword(s):  
Plane Wave ◽  
Density Of States ◽  
Noble Metals ◽  
Full Potential ◽  
Metallic Multilayers ◽  
Augmented Plane Wave ◽  
Narrow Bandwidth ◽  
Epitaxial Multilayers ◽  
Linearized Augmented Plane Wave ◽  
Wave Calculation

AbstractFull Potential Linearized Augmented Plane Wave calculations have been performed for epitaxial multilayers formed by the noble metals Ag and Cu with a thickness n up to 10 layers. The multilayers have a fcc lattice and are pure or compositionally modulated with a structure of the type Agn Cun or (AgCu)n. For n in the range 2,3 the density of states, evaluated at paramagnetic level, exhibits a sharp reduction of the bandwidth which is consistent with the reduced coordination of these structures. For n ≤ 5 the density of states in the central layers converges to the bulk value while the outer layers retain the narrow bandwidth found at n=2. Due to the absence of charge intermixing and hybridization, these features are shared by multilayers of all composition.

TEMPERATURE DEPENDENCE BEHAVIOR OF ELECTRICAL RESISTIVITY IN NOBLE METALS AT LOW TEMPERATURES

2014 ◽  
Vol 5 (3) ◽  
pp. 982-992 ◽  
Author(s):  
M AL-Jalali
Keyword(s):  
Experimental Data ◽  
Electrical Resistivity ◽  
Temperature Dependence ◽  
Concentration Dependence ◽  
Low Temperatures ◽  
Noble Metals ◽  
Phonon Scattering ◽  
Theoretical Models ◽  
Residual Resistivity ◽  
Electron Phonon Scattering

Resistivity temperature – dependence and residual resistivity concentration-dependence in pure noble metals(Cu, Ag, Au) have been studied at low temperatures. Dominations of electron – dislocation and impurity, electron-electron, and electron-phonon scattering were analyzed, contribution of these mechanisms to resistivity were discussed, taking into consideration existing theoretical models and available experimental data, where some new results and ideas were investigated.

Ultramafic-alkaline-carbonatite complexes as a result of two-stage melting of mantle plume: evidence from the mid-paleoproterozoic Tiksheozero intrusion, Northern Karelia, Russia

2019 ◽  
Vol 486 (4) ◽  
pp. 460-465
Author(s):  
E. V. Sharkov ◽  
A. V. Chistyakov ◽  
M. M. Bogina ◽  
O. A. Bogatikov ◽  
V. V. Shchiptsov ◽  
...  
Keyword(s):  
Fractional Crystallization ◽  
Mantle Plume ◽  
Large Igneous Province ◽  
Intrusive Complex ◽  
Incongruent Melting ◽  
Isotopic Data ◽  
Two Stage ◽  
Similar Composition ◽  
Igneous Province ◽  
Alkaline Magmas

Tiksheozero ultramafic-alkaline-carbonatite intrusive complex, like numerous carbonatite-bearing complexes of similar composition, is a part of large igneous province, related to the ascent of thermochemical mantle plume. Our geochemical and isotopic data evidence that ultramafites and alkaline rocks are joined by fractional crystallization, whereas carbonatitic magmas has independent origin. We suggest that origin of parental magmas of the Tiksheozero complex, as well as other ultramafic-alkaline-carbonatite complexes, was provided by two-stage melting of the mantle-plume head: 1) adiabatic melting of its inner part, which produced moderately-alkaline picrites, which fractional crystallization led to appearance of alkaline magmas, and 2) incongruent melting of the upper cooled margin of the plume head under the influence of CO2-rich fluids  that arrived from underlying zone of adiabatic melting gave rise to carbonatite magmas.

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