Infrared Studies of the Double Acceptor Zinc in Silicon

1989 ◽  
Vol 163 ◽  
Author(s):  
A. Dörnen ◽  
R. Kienle ◽  
K. Thonke ◽  
P. Stolz ◽  
G. Pensl ◽  
...  
Keyword(s):  
Optical Absorption ◽  
Charge State ◽  
Crystal Field ◽  
Absorption Spectra ◽  
Ground State ◽  
Near Infrared ◽  
Mid Infrared ◽  
Absorption Studies ◽  
Infrared Studies ◽  
Neutral Charge State

AbstractIn the present paper, optical absorption studies on the neutral charge state of the double acceptor zinc in silicon are presented. Measurements were carried out in the mid infrared (MIR) and in the near infrared (NIR) region. The MIR absorption spectra show the excitation series of an effective-masslike hole, from which the Zn° level position is calculated to be at Ev + 319. 1 meV. A splitting of the ground state into 3 sublevels is assigned to hole-hole coupling and crystal-field splitting. Absorption spectra obtained in the NIR are interpreted in terms of an A° X-type bound exciton.

OPTICAL ABSORPTION SPECTRA OF ARSENIC AND PHOSPHORUS IN SILICON

1962 ◽  
Vol 40 (10) ◽  
pp. 1480-1489 ◽  
Author(s):  
J. W. Bichard ◽  
J. C. Giles
Keyword(s):  
Optical Absorption ◽  
Absorption Spectra ◽  
Excited States ◽  
Ground State ◽  
Absorption Lines ◽  
Full Width ◽  
Optical Absorption Spectra ◽  
Phosphorus Impurity ◽  
Line Widths ◽  
Phosphorus In Silicon

The optical absorption spectra of arsenic and phosphorus donor impurities in silicon have been studied under conditions of improved resolution. Absorption lines due to transitions from the impurity ground state to the excited states 2p0, 2p±, 3p0, 3p±, 4p0, 4 p±, and 5p0, and 5p± have been observed at 4.2° K. The relative intensities of some of these absorption lines are compared with existing experimental and theoretical estimates. The contribution of instrumental broadening to the observed line widths is assessed and natural line widths are estimated. The estimates indicate values for the natural line widths which are much less than those previously reported. For phosphorus impurity, the natural line widths are estimated to be less than 0.08 × 10−3 electron volts full width at half-maximum. The possibility of concentration broadening is discussed in connection with the arsenic data.

Two-photon absorption spectra of a near-infrared 2-azaazulene polymethine dye: solvation and ground-state symmetry breaking

2013 ◽  
Vol 15 (20) ◽  
pp. 7666 ◽  
Author(s):  
Honghua Hu ◽  
Olga V. Przhonska ◽  
Francesca Terenziani ◽  
Anna Painelli ◽  
Dmitry Fishman ◽  
...  
Keyword(s):  
Symmetry Breaking ◽  
Absorption Spectra ◽  
Ground State ◽  
Near Infrared ◽  
Photon Absorption ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Polymethine Dye

Optical Absorption Spectra of Crystal‐Field Transitions in MnO

1969 ◽  
Vol 50 (9) ◽  
pp. 4092-4094 ◽  
Author(s):  
Donald R. Huffman ◽  
R. L. Wild ◽  
M. Shinmei
Keyword(s):  
Optical Absorption ◽  
Crystal Field ◽  
Absorption Spectra ◽  
Optical Absorption Spectra

scholarly journals Optical Absorption Spectra of H2O Ice Doped with Ytterbium Chloride YbCl3

1978 ◽  
Vol 21 (85) ◽  
pp. 559-563
Author(s):  
L. Couture
Keyword(s):  
Optical Absorption ◽  
Absorption Spectra ◽  
Infrared Absorption ◽  
Near Infrared ◽  
Dilute Solution ◽  
Optical Absorption Spectra ◽  
Stark Splitting ◽  
Ytterbium Chloride ◽  
Infrared Absorption Spectra ◽  
Frozen Solutions

AbstractNear-infrared absorption spectra of a frozen dilute solution of ytterbium chloride have been obtained at 77 K, 20 K, and 4.2 K. They contain two broad lines revealing a Stark splitting of 60 cm-1 of the excited 2F5/2, level of the Yb3+ ion. Such spectra indicate that in frozen solutions of ytterbium chloride the Yb3+ ions have crystalline or quasi-crystalline surroundings which are similar for most ions; different possibilities are discussed.

Synthesis and Characterization of Novel Platinum Acetylide Oligomers

2003 ◽  
Vol 771 ◽  
Author(s):  
Thomas M. Cooper ◽  
Benjamin C. Hall ◽  
Daniel G. McLean ◽  
Joy E. Rogers ◽  
Aaron R. Burke ◽  
...  
Keyword(s):  
Absorption Spectra ◽  
Ground State ◽  
Near Infrared ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash ◽  
Structure Property ◽  
Ground State Absorption ◽  
Excitation Spectra ◽  
C Nmr

AbstractAs part of an effort to develop a spectroscopic structure-property relationship in platinum acetylide oligomers, we have prepared a series of bidentate Pt(PBu3)2L2 compounds. The ligand was the series o-syd-C6H4-CΞC-(C6H4-CΞC)n-H, n = 0,1,2. The terminal oligomer unit consisted of a sydnone group ortho to the acetylene carbon. The compounds were characterized by various methods, including 13C-NMR, ground state absorption, fluorescence, phosphorescence and laser flash photolysis. The acetylenic 13C-NMR resonances showed sydnone influences that decreased with increasing number of monomer units. The ground state absorption spectra were slightly red shifted from those of the baseline oligomers not having a sydnone group. The low temperature emission and excitation spectra showed complex dependence on excitation and emission wavelengths, suggesting the chromphores resided in a distribution of solvent environments and conformations. Finally, broad triplet state absorption spectra were observed, with absorption throughout the visible and near infrared regions.

Near-Infrared Time-Resolved Optical Absorption Studies of the Reaction of Fully Reduced CytochromecOxidase with Dioxygen†

Biochemistry ◽  
2001 ◽  
Vol 40 (8) ◽  
pp. 2332-2339 ◽  
Author(s):  
Istvan Szundi ◽  
Guang-Ling Liao ◽  
Ólöf Einarsdóttir
Keyword(s):  
Optical Absorption ◽  
Near Infrared ◽  
Time Resolved ◽  
Absorption Studies

A photoconductivity study of trapped electrons in γ-irradiated hydrocarbon glasses at 77 K

1983 ◽  
Vol 61 (12) ◽  
pp. 2799-2803 ◽  
Author(s):  
Naoto Okabe ◽  
Toyoaki Kimura ◽  
Kenji Fueki
Keyword(s):  
Optical Absorption ◽  
Absorption Spectra ◽  
Conduction Band ◽  
Ground State ◽  
Volume Ratio ◽  
Optical Absorption Spectra ◽  
Trapped Electrons ◽  
Trapped Electron

Photoconductivity spectra of trapped electrons in γ-irradiated 3-methylpentane, 2-methylpentane, 3-methylheptane, and 3-methylpentane–methylcyclohexane (1:9 volume ratio) glasses at 77 K were measured. From the comparison of photoconductivity and optical absorption spectra in these systems we have obtained relative values of quantum efficiencies for a trapped electron in the ground state to be excited to the conduction band by photo-induced transition. For electrons stably trapped, we have measured the ranges of trap depths from the shallowest to the deepest in these systems.

Optical Absorption Spectra and Dynamic Jahn-Teller Effect of V2+ Ions in ZnSe

2008 ◽  
Vol 63 (12) ◽  
pp. 830-838
Author(s):  
Yi-Yang Zhou
Keyword(s):  
Optical Absorption ◽  
Crystal Field ◽  
Absorption Spectra ◽  
Optical Absorption Spectra ◽  
Cubic Crystal ◽  
Racah Parameter ◽  
Jahn Teller ◽  
Jahn Teller Effect ◽  
Tetrahedral Crystal ◽  
Good Agreement

The Hamiltonian matrices for 3d3 ions in a cubic crystal field are introduced, based on a molecular orbital model, including the electronic Coulomb and tetrahedral crystal-field interactions and the spin-orbit coupling. The optical absorption spectra of V2+ ions in ZnSe are studied. Moreover, the various additional levels found close to 5680 cm−1 are considered. These levels are assumed to result from the dynamic Jahn-Teller splitting within the excitation levels 2T2 and 2T1 in ZnSe:V2+. The good agreement between the present results and the experimental observations indicates that the contribution of the covalence reduction factors NE and NT2 and of the Racah parameter A to the optical absorption spectra of V2+ ions in ZnSe is important. However, most of the previous theoretical studies of these spectra in ZnSe:V2+ have neglected the Racah parameter A, based on the classical crystalfield model. A significant charge-transfer effect found in recent works is confirmed in ZnSe:V2+.

Optical absorption spectra of octahedrally bonded Fe3+ in vesuvianite

1968 ◽  
Vol 5 (1) ◽  
pp. 89-92 ◽  
Author(s):  
P. G. Manning
Keyword(s):  
Optical Absorption ◽  
Energy Range ◽  
Absorption Spectra ◽  
Excited States ◽  
Ground State ◽  
Electronic Transitions ◽  
Optical Absorption Spectra ◽  
Sharp Band ◽  
Individual Bands ◽  
The Individual

The optical absorption spectra of green vesuvianite crystals from Lowell County, Vermont, are reported in the energy range 12 000 cm−1 to 30 000 cm−1. The principal absorptions have been attributed to octahedrally bonded Fe3+ and the individual bands have been assigned to spin-forbidden electronic transitions from the 6A1 ground state to excited states in Fe3+. In particular, the 6A1 → 4A14E(G) transition is marked by a relatively sharp band at 21 600 cm−1.

Optical Anisotropy of RMnO3 Manganites in the Range of 4f-4f Transitions

2010 ◽  
Vol 168-169 ◽  
pp. 549-552 ◽  
Author(s):  
Natalia N. Loshkareva ◽  
Elena V. Mostovshchikova ◽  
A.S. Moskvin ◽  
Sergey V. Naumov ◽  
Natalia V. Kostromitina ◽  
...  
Keyword(s):  
Optical Absorption ◽  
Absorption Spectra ◽  
Optical Anisotropy ◽  
Polarized Light ◽  
Transparency Window ◽  
Infrared Range ◽  
Spectral Features ◽  
Mid Infrared ◽  
Temperature Range ◽  
Hexagonal Manganites

Optical absorption of orthorhombic and hexagonal manganites RMnO3 (R= Pr3+, Gd3+, Sm3+, Eu3+, Ho3+, Tm3+, Er3+, and Yb3+) were studied in polarized light in the near- and mid-infrared range for the temperature range 80 - 300 K. Several spectral features associated with 4f-4f transitions of R3+ ions were found in the transparency window of RMnO3. Anisotropy of the absorption spectra in the range of multiplet 4f-4f transitions and changes in populations of the multiplet levels with temperature were observed.

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