Progress towards a low-cost commercial coated conductor

2001 ◽  
Vol 689 ◽  
Author(s):  
Suresh Annavarapu ◽  
Nguyet Nguyen ◽  
Sky Cui ◽  
Urs Schoop ◽  
Cees Thieme ◽  
...  

ABSTRACTYBCO films prepared from metal trifluoroacetate (TFA) precursors on oxide-buffered textured non-magnetic substrates have achieved performance levels equaling that on oxide buffered textured Ni substrates. Critical current densities of 0.7 MA/cm2 to 1.0 MA/cm2 have been achieved in 0.4 µm thick YBCO films on short-length of CeO2/YSZ/Y2O3/Ni/Ni-13wt%Cr substrates. High-quality epitaxial buffers comprising a Ni layer, Y2O3 seed, YSZ barrier and CeO2 cap layers have been deposited over meter long tapes of deformation textured Ni and Ni-13%Cr using reel-to-reel processes. High-performance TFA-based YBCO films have been deposited on 0.1 m to 0.3 m lengths of these oxide buffered substrates using reel to reel processes. Critical current densities up to 1.0 MA/cm2 have been achieved in 0.4 µm thick YBCO films on CeO2/YSZ/Y2O3/Ni substrates. Using multiple coats of the metal trifluoroacetate precursors, thicker YBCO films have been demonstrated on oxide buffered substrates. Critical currents in excess of 100A/cm-width have been achieved for 1.2 µm -1.6 µm thick YBCO films on short lengths of CeO2/YSZ/Y2O3/Ni substrates.

MRS Bulletin ◽  
2004 ◽  
Vol 29 (8) ◽  
pp. 552-561 ◽  
Author(s):  
Amit Goyal ◽  
M. Parans Paranthaman ◽  
U. Schoop

AbstractThis article provides an overview of the fabrication of epitaxial, biaxially aligned buffer layers on rolling-assisted biaxially textured substrates (RABiTS) as templates for YBCO films carrying high critical current densities.The RABiTS technique uses standard thermomechanical processing to obtain long lengths of flexible, biaxially oriented substrates with smooth surfaces.The strong biaxial texture of the metal is conferred to the superconductor by the deposition of intermediate metal and/or oxide layers that serve both as a chemical and a structural buffer.Epitaxial YBCO films with critical current densities exceeding 3 106A/cm2at 77K in self-field have been grown on RABiTS using a variety of techniques and demonstrate magnetic-field-dependent critical current values that are similar to those of epitaxial films on single-crystal ceramic substrates.The RABiTS architecture most commonly used consists of a CeO2 (sputtered)/YSZ (sputtered)/Y203 (e-beam)/Ni-W alloy.The desired texture of the base metal has been achieved in 100 m lengths and 10cm widths.Scaleable and cost-effective techniques are also being pursued to deposit the epitaxial multilayers.The results discussed here demonstrate that this technique is a viable route for the fabrication of long lengths of high-critical-current-density wire capable of carrying high currents in magnetic fields and at temperatures accessible by cooling with relatively inexpensive liquid nitrogen (up through the 77K range).


2001 ◽  
Vol 689 ◽  
Author(s):  
Shara S. Shoup ◽  
Marvis K. White ◽  
Steve L. Krebs ◽  
Natalie Darnell ◽  
Adam C. King ◽  
...  

ABSTRACTThe innovative Combustion Chemical Vapor Deposition (CCVD) process is a non-vacuum technique that is being investigated to enable next generation products in several application areas including high-temperature superconductors (HTS). In combination with the Rolling Assisted Biaxially Textured Substrate (RABiTS) technology, the CCVD process has significant promise to provide low-cost, high-quality lengths of YBCO coated conductor. The CCVD technology has been used to deposit both buffer layer coatings as well as YBCO superconducting layers. A buffer layer architecture of strontium titanate and ceria have been deposited by CCVD on textured nickel substrates and optimized to appropriate thicknesses and microstructures to provide templates for growing PLD YBCO with high critical current density values. The CCVD buffer layers have been scaled to meter plus lengths with good epitaxial uniformity along the length. A short sample cut from one of the lengths enabled high critical current density PLD YBCO. Films of CCVD YBCO superconductors have been grown on single crystal substrates with critical current densities over 1 MA/cm2. Work is currently in progress to combine both the buffer layer and superconductor technologies to produce high-quality coupons of HTS tape made entirely by the non-vacuum CCVD process.


1999 ◽  
Vol 10 (07) ◽  
pp. 1335-1345
Author(s):  
I. MORGENSTERN ◽  
W. FETTES ◽  
T. HUSSLEIN

The high-Tc glass model can be combined with the repulsive tt'–Hubbard model as microscopic description of the striped domains found in the high-Tc materials. In this picture, the finite Hubbard clusters are the origin of the d-wave pairing. In this paper we show that the glass model can also explain the critical currents usually observed in the high-Tc materials. We use two different approaches to calculate the critical current densities of the high-Tc glass model. Both lead to a strongly anisotropic critical current. Finally we give an explanation of why we nonetheless expect a nearly perfect isotropic critical current in high-Tc superconductors.


1992 ◽  
Vol 275 ◽  
Author(s):  
T. I. Selinder ◽  
Z. Han ◽  
U. Helmersson ◽  
J. Magnusson ◽  
P. Norling ◽  
...  

ABSTRACTSemi-coherent Y2O3 (yttria) inclusions have been observed in high quality, c-axis oriented YBa2Cu3O6+×,(YBCO) Alms. The inclusions were studied by transmission electron microscopy (TEM), and were found to be embedded in the YBCO matrix without disturbing its structure seriously. Their number density is estimated to higher than 2 × 1016 cm−3 in epitaxial YBCO films, having transport critical current densities in excess of 1 × 106 A cm−2 at 77 K. Magnetization measurements indicate a possible correlation between a high density of yttria inclusions and high pinning strength. The effects of the inclusions on film growth and microstructure is discussed.


1987 ◽  
Vol 108 ◽  
Author(s):  
R. C. Frye

ABSTRACTNew, high temperature superconducting materials could eventually be used for interconnections in electronic systems. Such interconnections would undoubtedly cost more to implement than conventional ones, so the most likely applications would be for complex, high-speed systems that could benefit from the performance advantages of a resistance-free interconnecting medium. The problem with conventional conductors in these systems is that the resistance of wires increases quadratically as dimensions are scaled down. The most important advantage offered by superconductors is that they are not linked to this scaling rule. Their principal limitation is the maximum current density that they will support and this determines the range of applications for which they are superior to conventional conductors. An analysis will be presented which examines the relative advantages of superconductors for different critical current densities, wire dimensions and system sizes.If their critical current densities are adequate, and if they can statisfy a number of processing criteria, then superconductors could find useful applications in a number of high performance electronic systems. The most likely applications will be those demanding very high interconnection densities. Several of these systems will be discussed.


2001 ◽  
Vol 689 ◽  
Author(s):  
Tolga Aytug ◽  
M. Paranthaman ◽  
S. Sathyamurthy ◽  
B. W. Kang ◽  
D. B. Beach ◽  
...  

ABSTRACTA low-cost, non-vacuum reel-to reel dip-coating system has been used to continuously fabricate epitaxial Gd2O3 buffer layers on mechanically strengthened, biaxially textured Ni- (3at.%W-1.7at%Fe), defined as Ni-alloy, metal tapes. X-ray diffraction analysis of the seed Gd2O3 layers indicated that well textured films can be obtained at processing temperatures (Tp) between 1100 and 1175°C. Processing speed did not significantly affect the crystalline quality of the Gd2O3. Scanning electron microscopy revealed a continuous, dense and crack-free surface morphology for these dip-coated buffers. The Gd2O3 layer thickness led to remarkable differences in the growth characteristics of the subsequent YSZ and CeO2 layers deposited by rfmagnetron sputtering. Epitaxial YBCO films grown by pulsed laser deposition on the short prototype CeO2/YSZ/Gd2O3/Ni-(3at%W-1.7at%Fe) conductors yielded self-field critical current densities (Jc) as high as 1.2×106 A/cm2 at 77 K. Pure Ni tapes were used to asses the viability of dip-coated buffers for long length coated conductor fabrication. The YBCO films, grown on 80 cm long and 1 cm wide CeO2/YSZ/Gd2O3 buffered Ni tapes by the industrially scalable ex-situ BaF2 precursor process, exhibited end-to-end self-field Jc of 6.25×105 A/cm2 at 77 K.


1999 ◽  
Vol 9 (2) ◽  
pp. 2244-2247 ◽  
Author(s):  
M. Bauer ◽  
R. Semerad ◽  
H. Kinder ◽  
J. Wiesmann ◽  
J. Dzick ◽  
...  

2006 ◽  
Vol 47 ◽  
pp. 124-130
Author(s):  
Yutaka Yamada ◽  
Teruo Izumi ◽  
Yuh Shiohara

In the present 5-year national project since 2003, the development of YBCO coated conductors (CC) has advanced rapidly. The high performance processing group of SRL-ISTEC and Fujikura Ltd. has been working on the long tape of the PLD-YBCO superconductor on the IBAD-Gd2Zr2O7 buffered substrate tape. Very recently the SRL group achieved the highest value on the product of Ic x L in the world, 51,940 Am (212 m x 245 A). Fujikura Ltd. also realized the longest buffered substrate tape of 500m long IBAD tape and obtained a 200 m long coated conductor with Ic value of 88 A. In the low cost processing group using MOD, CVD and so on, the high Ic value of 525 A was obtained by SRL using the TFA-MOD method on the IBAD substrate. The 45m long TFA-MOD tape was also obtained with the Ic value of 155 A by Showa Electric Wire and Cable Company. Similarly 100- 200 m class long tapes were also obtained by the MOCVD (Chubu Power Electric Company) and PLD-HoBCO processes (Sumitomo Electric Industry Ltd.). Both groups above are further developing for the final goal of 500 m long tapes with the Ic of 300 A/cm-w at the production rate of 5 m/h. Furthermore, the feasibility study for the application has started due to the above success of long tape production. Several kinds of preliminary experiments using long coated conductors are now in progress for the power applications such as (1) Power Cable, (2) Transformer, (3) Motor and so on.


2001 ◽  
Vol 689 ◽  
Author(s):  
T. G. Holesinger ◽  
B. J. Gibbons ◽  
J. Y. Coulter ◽  
S. R. Foltyn ◽  
J. R. Groves ◽  
...  

ABSTRACTEach process used to deposit or make the bi-axially textured template, buffer layer(s), and the superconductor in a coated conductor creates interfaces along which defects or interfacial reactions may result. These defects can be additive and propagate through the entire film structure to affect the growth and properties of the superconducting film. Defects within the films and their corresponding transport properties have been correlated with the differences in the thickness of the underlying buffer layer material. This knowledge can be used to control and engineer the structure of the coated conductor to maximize critical current densities.


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