Facile Fabrication of Nanoparticles in the Nanospace of Ultrathin TiO2-Gel Films: Composition, Morphology and Catalytic Activity

2003 ◽  
Vol 794 ◽  
Author(s):  
Junhui He ◽  
Toyoki Kunitake
Keyword(s):  
Catalytic Activity ◽  
Low Temperature ◽  
Bimetallic Nanoparticles ◽  
In Situ Synthesis ◽  
Synthesis Of Nanoparticles ◽  
Catalytic Activities ◽  
Monodisperse Nanoparticles ◽  
Facile Fabrication ◽  
Tio2 Gel

ABSTRACTIn this article, we present in-situ synthesis of nanoparticles of various compositions and morphologies in the nanospace of ultrathin TiO2-gel films using low temperature H2 and O2 plasmas as reductant and oxidant, respectively. Parameters that influence the formation of nanoparticles were investigated and discussed. Reversible chemical transformation was found to give monodisperse nanoparticles. Catalytic activities of Pd monometallic and Ag-core/Pd-shell bimetallic nanoparticles were tested for hydrogenation of methyl acrylate. The much enhanced catalytic activity is attributed mainly to a large ratio of the surface Pd atoms.

Facile Fabrication of Ag−Pd Bimetallic Nanoparticles in Ultrathin TiO2-Gel Films:  Nanoparticle Morphology and Catalytic Activity

2003 ◽  
Vol 125 (36) ◽  
pp. 11034-11040 ◽  
Author(s):  
Junhui He ◽  
Izumi Ichinose ◽  
Toyoki Kunitake ◽  
Aiko Nakao ◽  
Yukihide Shiraishi ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Bimetallic Nanoparticles ◽  
Nanoparticle Morphology ◽  
Facile Fabrication ◽  
Tio2 Gel

In situ synthesis of Au–Pd bimetallic nanoparticles on amine-functionalized SiO2 for the aqueous-phase hydrodechlorination of chlorobenzene

RSC Advances ◽  
2014 ◽  
Vol 4 (89) ◽  
pp. 48254-48259 ◽  
Author(s):  
Xinkui Wang ◽  
Qinggang Liu ◽  
Zihui Xiao ◽  
Xiao Chen ◽  
Chuan Shi ◽  
...  
Keyword(s):  
Electronic Properties ◽  
Aqueous Phase ◽  
Reduction Method ◽  
Bimetallic Nanoparticles ◽  
In Situ Synthesis ◽  
High Dispersion ◽  
Amine Functionalized

The homogeneous Au–Pd NPs have been prepared through a facile in situ reduction method. The optimal AuPd1.0/SiO2 catalyst could complete the conversion of chlorobenzene due to the high dispersion and modified electronic properties of Pd.

In situ synthesis and catalytic activity in CO oxidation of metal nanoparticles supported on porous nanocrystalline silicon

2010 ◽  
Vol 36 (22) ◽  
pp. 63-70
Author(s):  
Sergej Polisski ◽  
Bernhard Goller ◽  
Karen Wilson ◽  
Dmitry Kovalev ◽  
Vladimir Zaikowskii ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
Metal Nanoparticles ◽  
Nanocrystalline Silicon ◽  
In Situ Synthesis

Gamma radiation-assisted in situ synthesis of palladium nanoparticles supported on ethylenediamine-functionalized polypropylene fabric as an efficient catalyst for reduction of 4-nitrophenol

2020 ◽  
Vol 44 (44) ◽  
pp. 19337-19350
Author(s):  
Girlie Eunice P. Lopez ◽  
Jordan F. Madrid ◽  
Drexel H. Camacho
Keyword(s):  
Catalytic Activity ◽  
Gamma Radiation ◽  
Palladium Nanoparticles ◽  
In Situ Synthesis ◽  
Chemical Transformations ◽  
Efficient Catalyst ◽  
Polypropylene Fabric ◽  
P Immobilization

Immobilization of Pd nanometals on a functionalized non-woven polypropylene fabric offers heterogenous catalytic activity in many chemical transformations and convenient separation from the reaction mixture.

Phosphorus Promoted HZSM-5 Zeolites for the Coupling Transformation of Methanol with 1-Butene to Propylene

2020 ◽  
Author(s):  
Xiao-hua Tang ◽  
Rui-qiang Liu ◽  
Hai-feng Tian ◽  
Hui Li ◽  
fei zha ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Space Velocity ◽  
In Situ Synthesis ◽  
Synthetic Methods ◽  
Incipient Wetness Impregnation ◽  
Large Specific Surface Area ◽  
Reaction Conditions ◽  
Coupling Transformation ◽  
Incipient Wetness

Phosphorus promoted HZSM-5 zeolites (P-HZSM-5) were prepared by synthetic methods of incipient wetness impregnation and in-situ synthesis, respectively. It was characterized by the means of XRD, SEM, BET, TG and NH3-TPD. The P-HZSM-5 zeolite prepared by incipient wetness impregnation has a large specific surface area and pore size, and the weak acidity is remarkably increased. The catalytic activity of P-HZSM-5 for the coupling transformation of methanol with 1-butene to propylene was investigated. Under the reaction conditions of temperature at 550 ℃, pressure at 0.4 MPa, space velocity at 1800 mL/(gcath) and mole ratio of CH3OH/C4H8 to 1:1, the conversion of C4H8 can reach to 75.8%, and the selectivity and yield of propylene are 42.2% and 31.9%, respectively.

Synthesis and catalytic performance of graphene oxide-Au nanorings composites

2019 ◽  
Vol 12 (03) ◽  
pp. 1950028 ◽  
Author(s):  
Tong Shen ◽  
Zhong Li ◽  
Yue Jiang ◽  
Zai-Gang Luo
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Rate Constant ◽  
Sodium Borohydride ◽  
Catalytic Performance ◽  
Hybrid Structure ◽  
In Situ Synthesis ◽  
Galvanic Replacement ◽  
Hybrid Nanomaterial

A simple and facile method is described for the in situ synthesis of graphene oxide-Ag nanoplates (GO-AgNPs) hybrid structure and then served as sacrificial templates for producing graphene oxide-Au nanorings (GO-AuNRs) by galvanic replacement taken place on the GO surface. The catalytic activity of the resulting hybrid nanomaterial has been investigated for the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) with sodium borohydride (NaBH4). The results showed that the rate constant of GO-AuNRs nanomaterials was 0.205[Formula: see text]min[Formula: see text] and the samples showed significant enhancement in catalytic activity.

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