scholarly journals DETERMINATION OF ARSENIC CONTENT IN WASTEWATER-FED FISH POND IN HOANG MAI DISTRICT, HANOI, VIETNAM

2018 ◽  
Vol 54 (2A) ◽  
pp. 321
Author(s):  
Le Thai Ha
Keyword(s):  
Heavy Metals ◽  
Graphite Furnace ◽  
Arsenic Concentration ◽  
Absorption Spectrometry ◽  
Dry Weight ◽  
Fish Pond ◽  
Human Consumption ◽  
Arsenic Content ◽  
Water Spinach ◽  
Gf Aas

Aquaculture in pond fed with wastewater has been practiced since the 1960s in Hoang Mai and Thanh Tri districts in Hanoi, Vietnam. Wastewater after directly discharged in to Kim Nguu and To Lich river is currently used for cultivation of vegetables and fishes. According to the previous studies, the content of some heavy metals in water and sediments from Kim Nguu and To Lich river exceeded the Vietnamese standard values. In this study, arsenic concentration in water, sediment, fish and plant collected from a wastewater fed-fish pond in Hoang Mai district, Ha Noi, Vietnam were determined by graphite furnace atomic absorption spectrometry (GF/AAS). Arsenic concentration in water collected from inlet and outlet sites of the pond were of 45.86 and 23.22 μg/L, respectively and those levels were higher than the Vietnamese standard. About 14% of arsenic entered the fish pond was in the suspended particulate mater (SPM) form. Arsenic concentration in the sediment ranged from 12.26 to 23.87 mg/kg (dry weight). The highest levels of arsenic found in the sediment near the pond outlet were probably caused by the movement of the sediment and heavy metals with the water flow. Based on the Vietnamese standards for agriculture soils, the studied pond sediment is not safe for crop application. Arsenic contents of 0.20 and 0.06 mg/kg (dry weight) were found in tissues of common carp and tilapia. The lower As contents in the outlet water in comparison to the inlet water showed that part of As was removed in the fish pond by different processes including the sedimentation and bio-adsorption. The As contents in the coarse stems/leaves of the water spinach samples were about 2.6 times higher than those in the shoot tips/younger leaves. As the findings, the water spinach and fish in this wastewater –fed fish pond were considered safe for human consumption with respect to arsenic content and Vietnamese standard.

scholarly journals DETECTION AND SAFETY AWARENESS OF HEAVY METALS IN COSMETIC PRODUCTS FREQUENTLY USED IN SAUDI ARABIA

2021 ◽  
Vol 9 (10) ◽  
pp. 1439-1448
Author(s):  
Samia S. Barghash ◽  
◽  
Hatem Abdel Moniem Ahmed ◽  
Modhi K. Al-Baker ◽  
◽  
...  
Keyword(s):  
Heavy Metals ◽  
Saudi Arabia ◽  
Graphite Furnace ◽  
Absorption Spectrometry ◽  
Cosmetic Products ◽  
Cross Sectional Survey ◽  
Cross Sectional ◽  
Saudi Women ◽  
Cadmium Lead ◽  
Gf Aas

Background: Heavymetalscontaminationincosmeticproducts isbecoming animportant healthprobleminboth worldwide and locally at the level of the Kingdom of Saudi Arabia (KSA).The aim of this study was to detectthe concentration of heavy metals in the most commonly used eyeliners purchased in Saudi Arabia. Also, to assesssafetyawarenessoftoxicelementsofmostconcernheavymetalsin cosmetics. Methods: A cross-sectional survey was designed and distributed electronically in Saudi Arabia in November 2015.The questionnairewas conducted on 769 Saudi women aged from15-60 years old that is using cosmetic products. Secondly, 10samples from 10 different types of eyeliners frequently used in Saudi Arabia were digested. The digested sampleswere analyzed for lead, cadmium andmercury using graphite furnace- atomic absorption spectrometry (GF-AAS). Results:Themajorityofcosmetictypesusedbyparticipantswereeye-linerkohl(73.9%).About(34.59 %) of participants were not aware about heavy metals contents in cosmetics. The heavy metals, cadmium, lead andmercury were detected in all samples with varying concentrations. The level of lead was the highest. There was asignificant difference of cadmium, lead and mercury concentration p< (0.05) in different brands of eyeliner. Therewasstatisticallysignificant difference betweencadmiumandlead alsobetweenmercuryandlead p<0.05ofdifferenteyelinerbrands. Conclusion: It was foundthatthemajorityofparticipantsexpectedthatexpensivecosmeticsaresafe and theypreferred internationalbrandswhichisnotnecessarytobesafe.

scholarly journals Levels of Heavy Metals in Popular Cigarette Brands and Exposure to These Metals via Smoking

2012 ◽  
Vol 2012 ◽  
pp. 1-5 ◽  
Author(s):  
Muhammad Waqar Ashraf
Keyword(s):  
Heavy Metals ◽  
Saudi Arabia ◽  
Atomic Absorption Spectrometry ◽  
Graphite Furnace ◽  
Absorption Spectrometry ◽  
Dry Weight ◽  
International Studies ◽  
Graphite Furnace Atomic Absorption ◽  
Average Quantity ◽  
Cadmium And Lead

The levels of selected heavy metals in popular cigarette brands sold and/or produced in Saudi Arabia were determined by graphite furnace-atomic absorption spectrometry (GFAAS). Average concentrations of Cadmium and Lead in different cigarette brands were 1.81 and 2.46 μg g−1(dry weight), respectively. The results obtained in this study estimate the average quantity of Cd inhaled from smoking one packet of 20 cigarettes to be in the range of 0.22–0.78 μg. Results suggest that the quantity of Pb inhaled of smoking one packet of 20 cigarettes is estimated to be 0.97–2.64 μg. The concentrations of Cd and Pb in cigarettes were significantly different between cigarette brands tested. The results of the present study were compared with those of other regional and international studies.

scholarly journals Determination of Cd, Mn and Ni accumulated in fruits, vegetables and soil in the Thohoyandou town area, South Africa

Water SA ◽  
2020 ◽  
Vol 46 (2 April) ◽  
Author(s):  
Babra Moyo ◽  
Vhahangwele Matodzi ◽  
Malebogo A Legodi ◽  
Vusumzi E Pakade ◽  
Nikita T Tavengwa
Keyword(s):  
Heavy Metals ◽  
South Africa ◽  
Fruits And Vegetables ◽  
Graphite Furnace ◽  
Absorption Spectrometry ◽  
Dry Weight ◽  
Limpopo Province ◽  
Leafy Vegetables ◽  
Town Area

The accumulation of heavy metals such as Cd, Mn and Ni was investigated in seven different vegetables, fruits and soil samples from Thohoyandou, Limpopo Province, South Africa. Heavy metals were quantified using graphite furnace atomic absorption spectrometry. Concentrations of heavy metals in fruits and vegetables were in the range of 0.23–2.94 mg∙kg-1 for Cd, 11.72–50.16 mg∙kg-1 for Mn and 5.73 – 44.11 mg∙kg-1 for Ni on a dry weight basis. Analysis of soils from where fruits and vegetables were sampled showed that Cd in the soil was in the range of 0.08–1.07 mg∙kg-1, Mn levels were 204.99–249.13 mg∙kg-1 and Ni levels were 48.47–88.23 mg∙kg-1. Cd was below the instrument detection limit for soils on which onions and bananas were grown. Vegetables showed different accumulation abilities, with leafy vegetables being the highest accumulators of heavy metals. The obtained results showed that concentrations of Cd in fruits, vegetables and soils exceeded the recommended maximum acceptable levels proposed by FAO/WHO and, hence, may pose a health risk to consumers. Ni concentrations in bananas, onion, beetroot, spinach and Chinese cabbage exceeded recommended standards by FAO/WHO.

scholarly journals Lead, mercury and arsenic content in spices: Black, white and green pepper, black cumin and ginger

2015 ◽  
Vol 13 (3) ◽  
pp. 191-202 ◽  
Author(s):  
Slavica Blagojevic ◽  
Stevan Blagojevic ◽  
Biljana Begovic
Keyword(s):  
Maximum Concentration ◽  
Graphite Furnace ◽  
Microwave Digestion ◽  
Hydride Generation ◽  
Absorption Spectrometry ◽  
Human Consumption ◽  
Arsenic Content ◽  
Mineral Contents ◽  
Green Pepper ◽  
Black Cumin

In order to evaluate the safety of selected commercial spices brands, concentration of lead, mercury and arsenic, as well as moisture and mineral contents were analyzed in samples of dried black and white pepper powders, black, white and green peppercorns, black cumin seeds and ginger powder. Lead (Pb), mercury (Hg) and arsenic (As) concentrations in spice samples purchased from local markets in Belgrade were determined, after a microwave digestion of the samples, by atomic absorption spectrometry (AAS), using the graphite furnace AAS technique (Pb), cold vapor AAS technique (Hg) and hydride generation AAS technique (As). Trace levels of Pb, Hg and As in the selected dried spices samples were in the range 0.10 ppm - 0.79 ppm, 0.01 ppm - 0.10 ppm and 0.01 ppm - 0.51 ppm, respectively. The maximum Pb concentration was determined in the sample of ginger and it was 0.79 ppm, the maximum concentration of Hg was 0.10 ppm, determined in green peppercorns samples, while the maximum concentration of As in powdered black pepper sample was 0.51 ppm. The moisture and mineral contents in the different analyzed spices were in the range 1.70-13.10% and 3.40-6.50%, respectively. According to the obtained results, the concentrations of the analyzed toxic elements, as well as the moisture and mineral content in selected spices, were below the maximum permissible limits declared by the national legislations deemed safe for human consumption.

scholarly journals Quality and safety of some commercial spices brands

2013 ◽  
pp. 1-9 ◽  
Author(s):  
Slavica Blagojevic ◽  
Stevan Blagojevic ◽  
Natasa Pejic ◽  
Biljana Begovic ◽  
Spasenka Gajinov
Keyword(s):  
Heavy Metals ◽  
Graphite Furnace ◽  
Microwave Digestion ◽  
Hydride Generation ◽  
Absorption Spectrometry ◽  
Human Consumption ◽  
Quality And Safety ◽  
Sweet Basil ◽  
Graphite Furnace Aas

In this study, in order to evaluate the quality and safety of selected commercial spices brands, contents of moisture and minerals, as well as the concentration of certain heavy metals (As, Hg and Pb) were determined in oregano, sweet basil, parsley and celery. The spice samples were subjected to microwave digestion, and were analyzed by atomic absorption spectrometry (AAS), using hydride generation AAS technique, cold vapor AAS technique, and graphite furnace AAS technique for determination of As, Hg and Pb, respectively. Maximum concentrations of As and Pb were determined in the same brand sample of celery, and are 0.75 ppm and 0.40 ppm, respectively, while the maximum concentration of Hg in various brands sweet basil samples is 0.05 ppm. According to the results, the contents of moisture and minerals, as well as the concentrations of heavy metals in all selected spices were below the maximum permissible limits declared by the national legislations, and are safe for human consumption.

scholarly journals Determination of Cd, Mn and Ni accumulated in fruits, vegetables and soil in the Thohoyandou town area, South Africa

Water SA ◽  
2020 ◽  
Vol 46 (2 April) ◽  
Author(s):  
Babra Moyo ◽  
Vhahangwele Matodzi ◽  
Malebogo A Legodi ◽  
Vusumzi E Pakade ◽  
Nikita T Tavengwa
Keyword(s):  
Heavy Metals ◽  
South Africa ◽  
Fruits And Vegetables ◽  
Graphite Furnace ◽  
Absorption Spectrometry ◽  
Dry Weight ◽  
Limpopo Province ◽  
Leafy Vegetables ◽  
Town Area

The accumulation of heavy metals such as Cd, Mn and Ni was investigated in seven different vegetables, fruits and soil samples from Thohoyandou, Limpopo Province, South Africa. Heavy metals were quantified using graphite furnace atomic absorption spectrometry. Concentrations of heavy metals in fruits and vegetables were in the range of 0.23–2.94 mg∙kg-1 for Cd, 11.72–50.16 mg∙kg-1 for Mn and 5.73 – 44.11 mg∙kg-1 for Ni on a dry weight basis. Analysis of soils from where fruits and vegetables were sampled showed that Cd in the soil was in the range of 0.08–1.07 mg∙kg-1, Mn levels were 204.99–249.13 mg∙kg-1 and Ni levels were 48.47–88.23 mg∙kg-1. Cd was below the instrument detection limit for soils on which onions and bananas were grown. Vegetables showed different accumulation abilities, with leafy vegetables being the highest accumulators of heavy metals. The obtained results showed that concentrations of Cd in fruits, vegetables and soils exceeded the recommended maximum acceptable levels proposed by FAO/WHO and, hence, may pose a health risk to consumers. Ni concentrations in bananas, onion, beetroot, spinach and Chinese cabbage exceeded recommended standards by FAO/WHO.

scholarly journals Transfer of Arsenic from Groundwater and Paddy Soil to Rice (Oryza sativa L.) Grain: A Micro Level Study in Chandina, Comilla

2015 ◽  
Vol 12 (2) ◽  
pp. 74-82 ◽  
Author(s):  
Md. Habibur Rahman ◽  
Md. Mohashin Farazi ◽  
Kohinoor Begum ◽  
Md. Serazul Islam
Keyword(s):  
Oryza Sativa ◽  
Irrigation Water ◽  
Agricultural Soil ◽  
Oryza Sativa L ◽  
Arsenic Concentration ◽  
Dry Weight ◽  
Permissible Limit ◽  
Arsenic Content ◽  
Soil Arsenic ◽  
Micro Level

Rice (Oryza sativa L.) is one of the major food crops in many countries. As the cultivation of rice requires huge volume of water, long term use of Arsenic contaminated groundwater for irrigation may result in the increase of arsenic concentration in the agricultural soil and eventually accumulation in rice grains. A micro level study was conducted to investigate the transfer of arsenic from irrigation water and soil to rice plants in the arsenic affected 8 unions of Chandina upazilla, Comilla district. The level of arsenic in irrigation water (0.12±0.08 and 0.67±0.07 mg l-1) was much above the WHO permissible limit of 0.01 mg l-1 for drinking water and FAO permissible limit of 0.10 mg l-1 for irrigation water. The total soil arsenic concentrations ranged from 3.21±0.80 to 8.74±2.83 mg kg-1 dry weight of soil, which was below the maximum acceptable limit for agricultural soil of 20.0 mg kg-1 as recommended by the European Community. The accumulation of arsenic in the grain ranged from 0.12±0.04 to 0.58±0.06 mg kg-1 in Boro and 0.16±0.04 to 1.06±0.20 mg kg-1 in T. Aman. Except grain sample (T. Aman) of one union, the grains in both Boro and T. Aman of all unions did not exceed 1.0 mg kg-1 dry weight of arsenic (the permissible limit of arsenic in rice according to WHO recommendation). Thus, till now rice has remained harmless for consumption in the study area. The results clearly showed that the arsenic content in the grains of Boro rice is correlated to the intensity of arsenic contamination of irrigation water and soil. The Agriculturists 2014; 12(2) 74-82

scholarly journals Human health risk assessment of heavy metals in soils and commonly consumed food crops from quarry sites located at Isiagwu, Ebonyi State

2018 ◽  
Vol 29 (1) ◽  
pp. 8-24 ◽  
Author(s):  
Uchechi Bliss Onyedikachi ◽  
Donatus Chuka Belonwu ◽  
Mattew Owhonda Wegwu
Keyword(s):  
Heavy Metals ◽  
Health Risk ◽  
Human Health ◽  
Human Health Risk ◽  
Daily Intake ◽  
Absorption Spectrometry ◽  
Carcinogenic Risk ◽  
Human Consumption ◽  
Us Epa ◽  
Bioaccumulation Index

Abstract In view of ensuring healthy agricultural foods for human consumption, this study assessed the human health risk implicated in selected heavy metals in some commonly consumed vegetables, tubers, nuts and fruits grown around the quarry sites at Ishiagu, Ebonyi State, Nigeria. Samples from agriculture area of Umudike, Abia State, Nigeria, constituted the control. The concentration of Mn, Zn, Fe, Cu, Cd, and Pb, were determined using atomic absorption spectrometry. The potential non-carcinogenic health risk for consumers which included Estimated Daily Intake (EDI) and Target Hazard Quotients (THQ) for Pb, Fe, Mn, Zn, Cd and Cu while carcinogenic health risk using Cancer Slope Factors (CSF) was established for Cd and Pb. Relative abundance of heavy metals across the locations and all samples was in the order Fe > Mn > Zn > Pb > Cu > Cd. There was statistical significant effect of quarrying activities on the concentration of the heavy metals (Fe, Mn, Zn, Pb, Cu, Cd) at p < 0.05 level. Based on the observed bioconcentration factors, cassava showed more hyperaccumulation potential compared to other samples. Pumpkin and bitter leaf also could be used in remediation owing to their high bioaccumulation index for Pb and Zn. THQ obtained for Mn and Pb were >1 indicating that the residents at the quarry site may be exposed to potential non-carcinogenic health risk due to Mn and Pb intoxication. With respect to US EPA prescriptions, average carcinogenic risk values obtained for Pb and Cd in this study indicated a lifetime (70 years) probability of contracting cancer suggesting that they be placed for further consideration as chemicals of concern with respect to the assessed locals.

scholarly journals Screening of Heavy Metal-Immobilizing Bacteria and Its Effect on Reducing Cd2+ and Pb2+ Concentrations in Water Spinach (Ipomoea aquatic Forsk.)

2020 ◽  
Vol 17 (9) ◽  
pp. 3122 ◽  
Author(s):  
Tiejun Wang ◽  
Xiaoyu Wang ◽  
Wei Tian ◽  
Lunguang Yao ◽  
Yadong Li ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Dry Weight ◽  
Water Spinach ◽  
Rhizosphere Soils ◽  
Microbial Resources ◽  
Heavy Pollution ◽  
Ipomoea Aquatic ◽  
Bacillus Thuringensis ◽  
Strong Ability

Microbial immobilization is considered as a novel and environmentally friendly technology that uses microbes to reduce heavy metals accumulation in plants. To explore microbial resources which are useful in these applications, three water spinach rhizosphere soils polluted by different levels of heavy metals (heavy pollution (CQ), medium pollution (JZ), and relative clean (NF)) were collected. The community composition of heavy metal-immobilizing bacteria in rhizosphere soils and its effects on reducing the Cd2+ and Pb2+ concentrations in water spinach were evaluated. Four hundred strains were isolated from the CQ (belonging to 3 phyla and 14 genera), JZ (belonging to 4 phyla and 25 genera) and NF (belonged to 6 phyla and 34 genera) samples, respectively. In the CQ sample, 137 strains showed a strong ability to immobilize Cd2+ and Pb2+, giving Cd2+ and Pb2+ removal rates of greater than 80% in solution; Brevundimonas, Serratia, and Pseudoarthrobacter were the main genera. In total, 62 strains showed a strong ability to immobilize Cd2+ and Pb2+ in the JZ sample and Bacillus and Serratia were the main genera. A total of 22 strains showed a strong ability to immobilize Cd2+ and Pb2+ in the NF sample, and Bacillus was the main genus. Compared to the control, Enterobacter bugandensis CQ-7, Bacillus thuringensis CQ-33, and Klebsiella michiganensis CQ-169 significantly increased the dry weight (17.16–148%) of water spinach and reduced the contents of Cd2+ (59.78–72.41%) and Pb2+ (43.36–74.21%) in water spinach. Moreover, the soluble protein and Vc contents in the shoots of water spinach were also significantly increased (72.1–193%) in the presence of strains CQ-7, CQ-33 and CQ-169 compared to the control. In addition, the contents of Cd and Pb in the shoots of water spinach meet the standard for limit of Cd2+ and Pb2+ in vegetables in the presence of strains CQ-7, CQ-33 and CQ-169. Thus, the results provide strains as resources and a theoretical basis for the remediation of Cd- and Pb-contaminated farmlands for the safe production of vegetables.

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