scholarly journals Physical and mechanical properties of low, ultralow and no cement refractory castables containing MgO nanoparticles developed in situ by means of polymeric resins

Cerâmica ◽  
2019 ◽  
Vol 65 (376) ◽  
pp. 592-598
Author(s):  
J. A. Alves Júnior ◽  
J. B. Baldo
Keyword(s):  
Pechini Method ◽  
Physical And Mechanical Properties ◽  
High Alumina ◽  
Mgo Nanoparticles ◽  
Low Viscosity ◽  
Refractory Castables ◽  
The Matrix ◽  
Polymeric Resins ◽  
Mixing Water

Abstract The introduction of MgO nanoparticles developed in situ in the matrix of high-alumina low cement, ultra-low and no cement refractory castables was made by means of a low viscosity containing aqueous polymeric resin, produced by the Pechini method. The addition of the liquid resin to the castables played two roles: first to serve as a supplier of mixing water and second as a precursor of nanoparticles of MgO, which were formed in situ in the castables matrices during firing. The results confirmed the benefits brought by the developed in situ MgO nanoparticles on the refractory properties of the investigated castables.

Effect of pouring temperature on A356-TiB2 MMCs cast in sand and permanent moulds by in-situ method

2016 ◽  
Vol 25 (5-6) ◽  
pp. 165-169
Author(s):  
C. Rajaravi ◽  
P.R. Lakshminarayanan
Keyword(s):  
Evaluation Studies ◽  
Physical And Mechanical Properties ◽  
Xrd Analysis ◽  
Matrix Composites ◽  
Structure Property ◽  
Pouring Temperature ◽  
Matrix Metal ◽  
Property Evaluation ◽  
The Matrix

AbstractThe paper describes a different condition of pouring temperature by sand and permanent mould to produce A356-6 wt% TiB2 metal matrix composites by in-situ method salt metal reaction route. The observation of SEM micrographs shows particle distribution of the TiB2 and it appears in hexagonal shape in Al matrix. The results of X-ray diffraction (XRD) analysis confirmed the formation of those TiB2 particulates and the results showed TiB2 particles are homogeneously dispersed throughout the matrix metal. Subsequent structure-property evaluation studies indicated sub-micron size reinforcement of in-situ formed TiB2 particles with improved physical and mechanical properties as compared to sand and permanent mould of Al-TiB2 composites. From, the permanent mould Al-TiB2 composite has an advantage of increase the properties over sand mould Al-TiB2 composite.

In Situ Coagulation of High-Alumina Zero-Cement Refractory Castables

2002 ◽  
Vol 85 (8) ◽  
pp. 1947-1953 ◽  
Author(s):  
André R. Studart ◽  
Victor C. Pandolfelli ◽  
Elena Tervoort ◽  
Ludwig J. Gauckler
Keyword(s):  
High Alumina ◽  
Refractory Castables

scholarly journals Investigation of Mechanical Properties of Low-Density Polyethylene with Copper Nanoparticles

2021 ◽  
Vol 15 ◽  
pp. 181-188
Author(s):  
M. V. Klychnikova ◽  
Kyaw Ye Ko
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Filler Content ◽  
Physical And Mechanical Properties ◽  
Ex Situ ◽  
Flow State ◽  
In Situ Preparation ◽  
The Matrix ◽  
The Relationship

In this work, it is shown that the method of the in situ preparation of Cu/LLDPE by combining the formation of a composite and a nanodispersed phase in the viscous-flow state of a polymer makes it possible to achieve a uniform distribution of nanoparticles in the matrix and effectively regulate their mechanical and functional properties. The optimal concentration of Cu nanofiller was found to be 2-5%, allowing to achieve the best mechanical properties. Comparative analysis of the physical and mechanical properties of Cu/LLDPE nanocomposites obtained by various methods shows that the deformation and strength characteristics of the 3CuLLDPE nanocomposite obtained by the in situ method are improved in comparison with the properties of the 3CuLLDPE nanocomposite, prepared by ex situ method. The relationship between the filler content and the modulus of elasticity/tensile strength has been determined. With an increase in the filler content, the elastic modulus increases by 10-20%, and the tensile strength decreases by 30%. Elongation at break for samples with nanofiller content up to 3 wt. % higher than unfilled polymer

scholarly journals Supramolecular ionic polymer/carbon nanotube composite hydrogels with enhanced electromechanical performance

2020 ◽  
Vol 9 (1) ◽  
pp. 478-488 ◽  
Author(s):  
Yun-Fei Zhang ◽  
Fei-Peng Du ◽  
Ling Chen ◽  
Ka-Wai Yeung ◽  
Yuqing Dong ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Ion Mobility ◽  
Artificial Muscles ◽  
Ionic Polymer ◽  
Composite Hydrogels ◽  
The Matrix ◽  
Electromechanical Performance ◽  
Carbon Nanotube Composite ◽  
Robotic Devices

AbstractElectroactive hydrogels have received increasing attention due to the possibility of being used in biomimetics, such as for soft robotics and artificial muscles. However, the applications are hindered by the poor mechanical properties and slow response time. To address these issues, in this study, supramolecular ionic polymer–carbon nanotube (SIPC) composite hydrogels were fabricated via in situ free radical polymerization. The polymer matrix consisted of carbon nanotubes (CNTs), styrene sulfonic sodium (SSNa), β-cyclodextrin (β-CD)-grafted acrylamide, and ferrocene (Fc)-grafted acrylamide, with the incorporation of SSNa serving as the ionic source. On applying an external voltage, the ions accumulate on one side of the matrix, leading to localized swelling and bending of the structure. Therefore, a controllable and reversible actuation can be achieved by changing the applied voltage. The tensile strength of the SIPC was improved by over 300%, from 12 to 49 kPa, due to the reinforcement effect of the CNTs and the supramolecular host–guest interactions between the β-CD and Fc moieties. The inclusion of CNTs not only improved the tensile properties but also enhanced the ion mobility, which lead to a faster electromechanical response. The presented electro-responsive composite hydrogel shows a high potential for the development of robotic devices and soft smart components for sensing and actuating applications.

scholarly journals In situ structure and organization of the influenza C virus surface glycoprotein

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Steinar Halldorsson ◽  
Kasim Sader ◽  
Jack Turner ◽  
Lesley J. Calder ◽  
Peter B. Rosenthal
Keyword(s):  
Membrane Fusion ◽  
Hexagonal Lattice ◽  
Surface Glycoprotein ◽  
Structural Basis ◽  
Virus Surface ◽  
The Matrix ◽  
Influenza C Virus ◽  
Subtomogram Averaging ◽  
Electron Cryotomography

AbstractThe lipid-enveloped influenza C virus contains a single surface glycoprotein, the haemagglutinin-esterase-fusion (HEF) protein, that mediates receptor binding, receptor destruction, and membrane fusion at the low pH of the endosome. Here we apply electron cryotomography and subtomogram averaging to describe the structural basis for hexagonal lattice formation by HEF on the viral surface. The conformation of the glycoprotein in situ is distinct from the structure of the isolated trimeric ectodomain, showing that a splaying of the membrane distal domains is required to mediate contacts that form the lattice. The splaying of these domains is also coupled to changes in the structure of the stem region which is involved in membrane fusion, thereby linking HEF’s membrane fusion conformation with its assembly on the virus surface. The glycoprotein lattice can form independent of other virion components but we show a major role for the matrix layer in particle formation.

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