scholarly journals Multimineral reactions controlling secondary phase evolution in a hyperalkaline plume

2019 ◽  
Vol 6 (8) ◽  
pp. 521-527 ◽  
Author(s):  
XiaoHui Chen ◽  
Steven Thornton
2021 ◽  
Vol 14 (3) ◽  
pp. 2327-2343
Author(s):  
Ying Li ◽  
Gottfried Kirchengast ◽  
Marc Schwärz ◽  
Florian Ladstädter ◽  
Yunbin Yuan

Abstract. We introduce a new method to detect and monitor sudden stratospheric warming (SSW) events using Global Navigation Satellite System (GNSS) radio occultation (RO) data at high northern latitudes and demonstrate it for the well-known January–February 2009 event. We first construct RO temperature, density, and bending angle anomaly profiles and estimate vertical-mean anomalies in selected altitude layers. These mean anomalies are then averaged into a daily updated 5∘ latitude × 20∘ longitude grid over 50–90∘ N. Based on the gridded mean anomalies, we employ the concept of threshold exceedance areas (TEAs), the geographic areas wherein the anomalies exceed predefined threshold values such as 40 K or 40 %. We estimate five basic TEAs for selected altitude layers and thresholds and use them to derive primary-, secondary-, and trailing-phase TEA metrics to detect SSWs and to monitor in particular their main-phase (primary- plus secondary-phase) evolution on a daily basis. As an initial setting, the main phase requires daily TEAs to exceed 3×106 km2, based on which main-phase duration, area, and overall event strength are recorded. Using the January–February 2009 SSW event for demonstration, and employing RO data plus cross-evaluation data from analysis fields of the European Centre for Medium-Range Weather Forecasts (ECMWF), we find the new approach has strong potential for detecting and monitoring SSW events. The primary-phase metric shows a strong SSW emerging on 20 January, reaching a maximum on 23 January and fading by 30 January. On 22–23 January, temperature anomalies over the middle stratosphere exceeding 40 K cover an area of more than 10×106 km2. The geographic tracking of the SSW showed that it was centered over east Greenland, covering Greenland entirely and extending from western Iceland to eastern Canada. The secondary- and trailing-phase metrics track the further SSW development, where the thermodynamic anomaly propagated downward and was fading with a transient upper stratospheric cooling, spanning until the end of February and beyond. Given the encouraging demonstration results, we expect the method to be very suitable for long-term monitoring of how SSW characteristics evolve under climate change and polar vortex variability, using both RO and reanalysis data.


2008 ◽  
Vol 368-372 ◽  
pp. 970-972 ◽  
Author(s):  
Yan Xiong ◽  
Zheng Yi Fu ◽  
Hao Wang

Effect of adding up to 5wt% CaF2 on the densification and microstructural development of hot pressed aluminum nitride (AlN) was investigated. SEM investigation showed that the grain size of the sintered sample decreases with the increasing content of CaF2. Secondary-phase evolution paths converge from CA6 to CA phase above 1650°C. TEM micrographs showed that formed secondary phases could evaporate from sintered bodies at higher temperatures in the carbon-containing nitrogen atmosphere and the residuals were mainly distributed at triple grain junctions, keeping direct connections of AlN grains. Translucnet AlN ceramics were prepared using CaF2 additive sintered at 1850°C for 5 h.


2010 ◽  
Vol 152-153 ◽  
pp. 801-804 ◽  
Author(s):  
Kai Xin Song ◽  
Zhi Hua Ying ◽  
Liang Zheng ◽  
Zheng Liu ◽  
Hui Bin Qin

In this paper, the microwave dielectric properties in the systems of nominal chemical composition (Mg1-xCax)2SiO4 (0≤x≤0.5)ceramics were investigated, together with their phase evolution. With the increase of x value, the major phase in the ceramic systems gradually changes from Mg2SiO4 to MgCaSiO4, besides with the some secondary phase of MgSiO3 and Ca2MgSi2O7, The relative dielectric constant in the systems of ceramics gradually increased from 6.8 to 8.7. The quality factor of value was well improved, and especially, the absolute value of the ceramic resonant frequency of temperature coefficients was optimized to reach zero, from -61 to +3 . The best optimum chemical composition was equal to 0.4, where the microwave dielectric properties was = 7.2, = 24,170 GHz, = +5 .


2020 ◽  
Author(s):  
Ying Li ◽  
Gottfried Kirchengast ◽  
Marc Schwärz ◽  
Florian Ladstädter ◽  
Yunbin Yuan

Abstract. We introduce a new method to detect and monitor Sudden Stratospheric Warming (SSW) events using Global Navigation Satellite System (GNSS) Radio Occultation (RO) data at high northern latitudes and demonstrate it for the well-known Jan–Feb 2009 event. We first construct RO temperature, density, and bending angle anomaly profiles and estimate vertical-mean anomalies in selected altitude layers. These mean anomalies are then averaged into a daily-updated 5° latitude × 20° longitude grid over 50° N–90° N. Based on the gridded mean anomalies, we employ the concept of Threshold Exceedance Areas (TEAs), the geographic areas wherein the anomalies exceed predefined threshold values such as 40 K or 40 %. We estimate five basic TEAs for selected altitude layers and thresholds and use them to derive primary-, secondary-, and trailing-phase TEA metrics to detect SSWs and to monitor in particular their main-phase (primary- plus secondary-phase) evolution on a daily basis. As an initial setting, the main-phase requires daily TEAs to exceed 3 Mio. km2, based on which main-phase duration, area, and overall event strength are recorded. Using the Jan–Feb 2009 SSW event for demonstration, and employing RO data plus cross-evaluation data from analysis fields of the European Centre for Medium-range Weather Forecasts (ECMWF), we find the new approach of strong potential for detecting and monitoring SSW events. The TEA metrics show a strong SSW emerging on Jan 17, reaching a maximum on Jan 23, and the strong primary-phase temperature anomaly fading by Jan 27. On Jan 22–23 a MSTA-TEA40 value (TEA of middle stratosphere temperature anomaly > 40 K) of about 9 Mio. km2 was reached. The geographic tracking of the SSW showed that it was centered over East Greenland, covering Greenland entirely and extending from Western Norway to Eastern Canada. The secondary- and trailing-phase metrics track the further SSW development, where the thermodynamic anomaly propagated downward and was fading with a transient upper stratospheric cooling, spanning until end February and beyond. Given the encouraging demonstration results, we expect the method very suitable for long-term monitoring of how SSW characteristics evolve under climate change and variability using both RO and reanalysis data.


2009 ◽  
Vol 624 ◽  
pp. 91-108 ◽  
Author(s):  
Koushik Biswas

In view of considerable attention in the development of liquid phase sintered SiC, a comprehensive study of the data on processing, structure and properties seems highly relevant. This article provides a detailed and critical overview of liquid phase sintered silicon carbide ceramics with primary emphasis of grain-boundary/secondary phase evolution, their structure, distribution on the final properties of the sintered materials. The roles of individual additives in developing boundary microstructures will be identified and demonstrated to be critical in optimizing the mechanical properties, including fracture toughness, flexural strength and creep resistance. Numerous methods of structure-properties modification, like in-situ-toughening, -SiC phase transformation, volume of liquid phase, partial/full crystallization of grain-boundary and/or secondary phases are conclusively discussed. Apart from conventional pressureless sintering of SiC, enhanced spark plasma sintering with different oxide and non-oxide sintering additives are also discussed in terms of phase evolution, microstructure and their structure mechanical properties are correlated.


Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1823
Author(s):  
Jessica Satta ◽  
Alberto Casu ◽  
Daniele Chiriu ◽  
Carlo Maria Carbonaro ◽  
Luigi Stagi ◽  
...  

CsPbI3 inorganic perovskite is synthesized by a solvent-free, solid-state reaction, and its structural and optical properties can be deeply investigated using a multi-technique approach. X-ray Diffraction (XRD) and Raman measurements, optical absorption, steady-time and time-resolved luminescence, as well as High-Resolution Transmission Electron Microscopy (HRTEM) imaging, were exploited to understand phase evolution as a function of synthesis time length. Nanoparticles with multiple, well-defined crystalline domains of different crystalline phases were observed, usually surrounded by a thin, amorphous/out-of-axis shell. By increasing the synthesis time length, in addition to the pure α phase, which was rapidly converted into the δ phase at room temperature, a secondary phase, Cs4PbI6, was observed, together with the 715 nm-emitting γ phase.


1994 ◽  
Vol 346 ◽  
Author(s):  
H. Miao ◽  
V. Primo ◽  
R. Ibañez ◽  
F. Sapiña ◽  
A. Beltran ◽  
...  

ABSTRACTA variation of the solid-state matrix technique has been developed as a procedure for the preparation of 2223 bismuth superconducting phases [(Bi,Pb)2Sr2Ca1-nCunO4+2n, n=3]. The adequate processing of samples of nominal compositions 2223+x 0021, obtained both by this procedure and by the polymer matrix method, has allowed the modification of the microstructure of the calcium copper excess, with no noticeable change in that of the 2223 grains. The study of the phase evolution in the processing of the samples has shown that the formation rate of the 2223 phase is faster when the particle size of the calcium cuprate is smaller. A dependence of the intergranular superconducting properties on the secondary phase is observed, appearing as a maximum in Jc0/μcer at x=0.2 and x=0.5 for samples prepared by solid state matrix and polymer matrix methods, respectively.


Author(s):  
Anthony V. DeCeanne ◽  
Aubrey L. Fry ◽  
Collin J. Wilkinson ◽  
Marc Dittmer ◽  
Christian Ritzberger ◽  
...  

2019 ◽  
Author(s):  
Roberto Köferstein

Full text also available at: http://rdcu.be/v7Fn A one-pot polymerization method using citric acid and glucose for the synthesis of nano-crystalline BaFe0.5Nb0.5O3 is described. Phase evolution and the development of the crystallite size during decomposition of the (Ba,Fe,Nb)-gel were examined up to 1100 °C. Calcination at 850 °C of the gel leads to a phase-pure nano-crystalline BaFe0.5Nb0.5O3 powder with a crystallite size of 28 nm. The shrinkage of compacted powders starts at 900 °C. Dense ceramic bodies (relative density ≥ 90%) can be obtained either after conventional sintering above 1250 °C for 1 h or after two-step sintering at 1200 °C. Depending on the sintering regime, the ceramics have average grain sizes between 0.3 and 52 μm. The optical band gap of the nano-sized powder is 2.75(4) eV and decreases to 2.59(2) eV after sintering. Magnetic measurements of ceramics reveal a Neel temperature of about 23 K. A weak spontaneous magnetization might be due to the presence of a secondary phase not detectable by XRD. Dielectric measurements show that the permittivity values increase with decreasing frequency and rising temperature. The highest permittivity values of 10.6 9 104 (RT, 1 kHz) were reached after sintering at 1350 °C for 1 h. Tan δ values of all samples show a maximum at 1–2 MHz at RT. The frequency dependence of the impedance can be well described using a single RC-circuit.


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