scholarly journals Biodiagnostics of stability of soils of southern Russia to silver pollution

2021 ◽  
Vol 16 (1) ◽  
pp. 61-75
Author(s):  
S. I. Kolesnikov ◽  
N. I. Tsepina ◽  
Т. V. Minnikova ◽  
L. V. Sudina ◽  
К. Sh. Kazeev

Aim. To assess the resistance of soils in the south of Russia to silver pollution using biological indicators.Methods. The contamination of soils in southern Russia (ordinary chernozem, grey sandy and brown forest soils) was simulated with silver under laboratory conditions. Soils were contaminated with water‐soluble silver nitrate in order to reveal the maximum ecotoxicity of silver. Soil stability was assessed according to the most sensitive and informative biological parameters in dynamics of 10, 30 and 90 days after pollution. Results. Silver contamination inhibits the activity of oxidoreductases (catalase and dehydrogenases), reduces the total number of bacteria and the growth and development of radish. For all soils, a direct relationship was noted between silver concentration and the degree of deterioration of soil properties. The toxic effect of silver was most pronounced on the 30th day after contamination. According to their resistance to silver pollution, the soils investigated form the following sequence: ordinary chernozem> grey sandy soil ≥ brown forest soil. Conclusion. The light granulometric composition of grey sandy soils and the acidic reaction of the environment of brown forest soils, as well as the low organic matter content, contribute to the high mobility and high ecotoxicity of silver in these soils. Regional maximum permissible concentrations (MPCs) of silver content in ordinary chernozems, grey sandy and brown forest soils have been determined as ‐ 4.4, 0.9 and 0.8 mg/kg, respectively. 

2020 ◽  
Vol 2020 ◽  
pp. 1-9
Author(s):  
S. I. Kolesnikov ◽  
N. I. Tsepina ◽  
L.V. Sudina ◽  
T. V. Minnikova ◽  
K. Sh. Kazeev ◽  
...  

The use of silver in various spheres of life and production leads to an increase in environmental pollution, including soil. At the same time, the environmental consequences of silver pollution of soils have been studied to a much lesser extent than those of other heavy metals. The aim of this study is to estimate silver ecotoxicity using the soil state biological indicators. We studied soils that are significantly different in resistance to heavy metal pollution: ordinary chernozem (Haplic Chernozems, Loamic), sierosands (Haplic Arenosols, Eutric), and brown forest acidic soil (Haplic Cambisols, Eutric). Contamination was simulated in the laboratory. Silver was introduced into the soil in the form of nitrate in doses of 1, 10, and 100 mg/kg. Changes in biological parameters were assessed 10, 30, and 90 days after contamination. Silver pollution of soils in most cases leads to deterioration of their biological properties: the total number of bacteria, the abundance of bacteria of the genus Azotobacter, the activity of enzymes (catalase and dehydrogenases), and the phytotoxicity indicators decrease. The degree of reduction in biological properties depends on the silver concentration in the soil and the period from the contamination moment. In most cases, there is a direct relationship between the silver concentration and the degree of deterioration of the studied soil properties. The silver toxic effect was most pronounced on the 30th day after contamination. In terms of their resistance to silver pollution, the studied soils are in the following order: ordinary chernozem > sierosands ≥ brown forest soil. The light granulometric composition of sierosands and the acidic reaction of the environment of brown forest soils, as well as the low content of organic matter, contribute to high mobility and, consequently, high ecotoxicity of silver in these soils. The regional maximum permissible concentration (rMPC) of silver in ordinary chernozem (Haplic Chernozems, Loamic) is 4.4 mg/kg, in sierosands (Haplic Arenosols, Eutric) 0.9 mg/kg, and in brown forest soils (Haplic Cambisols, Eutric) 0.8 mg/kg.


2021 ◽  
Vol 25 (1) ◽  
pp. 65-71
Author(s):  
S.I. Kolesnikov ◽  
D.I. Moshchenko ◽  
A.A. Kuzina ◽  
T.A. Ter-Misakyants ◽  
E.N. Nevedomyaya ◽  
...  

This article assesses the resistance of brown forest soils of the Republic of Crimea, the Western and Central Caucasus to pollution by lead, chromium, nickel, and copper, and develops regional maximum permissible concentrations of these heavy metals. Soil contamination was modeled under laboratory conditions. Heavy metals were added in the form of oxides. Soil stability assessment was carried out by biological indicators. The brown forest soil of the Republic of Crimea proved to be the most resistant to pollution. The higher stability of the brown forest soils of the Western Caucasus relative to similar soils of the Central Caucasus, apparently, is determined by the higher content of organic matter in them, despite their lower acidity. Heavy metals formed the following series in terms of ecotoxicity for brown forest soils: Cr> Cu ≥ Ni ≥ Pb. The values of regional maximum permissible concentrations of lead, chromium, nickel and copper in the brown forest soils of the Crimea, Central and Western Caucasus are proposed.


2021 ◽  
Vol 11 (10) ◽  
pp. 4663
Author(s):  
Raquel Cela-Dablanca ◽  
Carolina Nebot ◽  
Lucia Rodríguez López ◽  
David Ferández-Calviño ◽  
Manuel Arias-Estévez ◽  
...  

Antibiotics in wastewater, sewage sludge, manures, and slurries constitute a risk for the environment when spread on soils. This work studies the adsorption and desorption of the antibiotic cefuroxime (CFX) in 23 agricultural and forest soils, using batch-type experiments. Our results show that the adsorption values were between 40.75 and 99.57% in the agricultural soils, while the range was lower (from 74.57 to 93.46%) in forest soils. Among the Freundlich, Langmuir, and Linear models, the Freundlich equation shows the best fit for the adsorption results. In addition, agricultural soils with higher pH are the ones that present the highest adsorption. Further confirmation of the influence of pH on adsorption is given by the fact that Freundlich’s KF parameter and the Linear model Kd parameter shows a positive correlation with pH and with the exchangeable Ca and Mg values, which are known to affect the charges of the soil colloids and the formation of cationic bridges between adsorbents and adsorbate. In addition, Freundlich’s n parameter shows a positive and significant correlation with the organic matter content, related to the high adsorption taking place on forest soils despite their pH < 5. Regarding desorption, in most cases, it is lower than 1%, which indicates that CFX is adsorbed in a rather irreversible way onto these soils. Overall, these results can be considered relevant regarding their potential impact on environmental quality and public health.


2015 ◽  
Vol 667 ◽  
pp. 370-375 ◽  
Author(s):  
Xiao Hua Luo ◽  
Xin Qiu ◽  
Yu Jie Wang ◽  
Jin Hong Wu ◽  
Shang Lin Xiao

In order to study the treatment mechanism of the ionic liquid soil stabilizer, a series tests were performed for a typical soil, the red-brown clay. The basic physical parameters of typical soil were conducted by variety of tests, including particle size analysis, crucial water content coefficient, loss on ignition, organic matter content, etc. Furthermore, the treatment mechanism of the ionic soil stabilizer was analyzed, involving PH, conductivity, plasma emission spectra, scanning electron microscopy, X-ray diffraction and BET test. The results indicate: Firstly, the ionic soil stabilizer is a sulfonated oleoresin with the features of water soluble, high conductivity and strongly acidic, which exchanged with cations adsorbed on the surface of clay particles to reduce the thickness of hydrated film and the electric double layer thickness. Secondly, it reduced the mutual repulsion energy between soil particles and made the flaky particles of clay minerals contact closely. Finally, it made the particles of clay be close to each other and gradually formed larger particles. Hence, the clay became denser. Therefore, the research provided a theoretical foundation and practical basis for the wide application of the ionic soil stabilizer in China's highway construction.


Soil Research ◽  
1980 ◽  
Vol 18 (2) ◽  
pp. 163 ◽  
Author(s):  
EL Greacen ◽  
R Sands

The problem of soil compaction in forestry differs from that in agriculture because of differences in the nature of the crop, in particular the weight and size of the plant members and the length of time that they persist. The roots compact the soil as they increase in size, but they also transmit the weight of the tree and forces generated by the wind onto the soil. There are important differences in management practices; in forestry modern harvesting machines apply heavy loads and, for reasons of cost, tend to be kept in operation throughout the year. As a consequence the structure of the soil suffers some damage, often manifested as compaction. Compaction arising from such sources may reduce the growth of the current trees or trees subsequently planted on the site. But it is difficult to predict the extent of such reduction, if any, because of the complex of interactions involved. Important factors concerned, namely, the soil water regime and the organic matter content, are emphasized. A conceptual model is proposed as a predictive tool. The mechanics of soil compaction, the effects of compaction on the physical properties of the soil, and techniques for the prevention and amelioration of compaction of forest soils, are discussed.


Author(s):  
Д.А. Данилов ◽  
А.В. Жигунов ◽  
Б.Н. Рябинин ◽  
А.А. Вайман

Используя потенциальное плодородие посагрогенных почв, можно выращивать целевые древесные насаждения и получать балансовую и товарную древесину в более короткие сроки, чем на землях лесного фонда. Проблематика данного вопроса мало исследована и в настоящее время необходимо оценить перспективность выращивания насаждений высокой продуктивности на постагрогенных. Целью проведённого исследования было сравнение лесных и постагрогенных почв по таким параметрам, как содержание углерода органического вещества и общего азота, для прогнозирования перспективности организации хозяйства с ускоренным выращиванием продуктивных древесных насаждений на залежных землях. На постагрогенных и лесопокрытых землях были подобраны площади со сходными условиями почвообразования под спелыми древостоями, относящихся к типам леса: черничник, кисличник и дубравнотравный и почвенными комплексами постагрогенных залежных земель. Проводилась оценка ряда физико-химических показателей почв по общепринятым в почвоведении методикам: определялся гранулометрический состав, плотность сложения и мощность генетических почвенных горизонтов. Плотность сложения всех горизонтов оценивалась по Качинскому; определение углерода проводилось сухим озолением, общего азота по Кьельдалю, рН солевой вытяжки потенциометрическим методом.Анализ запасов углерода органического вещества (Сорг) и азота (Nобщ) в генетических горизонтах почв черничного, кисличного и дубравнотравного типов леса показывает увеличение содержания органического вещества и общего азота от черничного к дубравнотравному типу леса. Происходит снижение содержания органического углерода от гумусового горизонта к оподзоленному: в дубравнотравных типах леса – в 2,8; кисличных – в 7,6; в черничных – в 8,5 раз. Возобновление на постагрогенных землях носит куртинный характер или происходит по микро понижениям бывших борозд. Содержание органического вещества в пахотном горизонте данных участков постагрогенных земель находится на уровне кисличного типа леса. Содержание общего азота в данных почвах высокое от 5 до 7,4 т/га – на уровне дубравнотравного типа леса. Отношение С:N, которое характеризует обогащенность гумуса азотом, для большинства гумусовых горизонтов почв составляет 8–10, что отвечает высокой и средней степени обеспеченности этим элементом. По содержанию Сорг и Nобщ в верхнем горизонте почвы образуют следующий убывающий ряд: травяно-дубравный тип леса > залежные земли > кисличный тип леса > черничный тип леса > пашня. Проведённый сравнительный анализ физического и агрохимического состояния постагрогенных и лесных почв показал, что несмотря на предшествующее антропогенное воздействие, агрозёмный горизонт сохраняет высокое содержание органического вещества и общего азота. Ухудшение свойств постагрогенных почв на исследуемых участках не происходит и трансформации в сторону природных лесных почв региона не наблюдается, несмотря на длительный период залежности (свыше 30 лет). Соотношение углерода и азота в постагрогенных почвах по почвенному профилю показывает более высокое плодородие, чем в лесных почвах, где показатель С:N оптимален только части горизонта А1. Оценивая пригодность обследованных участков залежных земель на предмет ускоренного выращивания различных древесных пород для получения биомассы, можно констатировать, что уровень содержания органического вещества и общего азота превышает или соответствует условиям произрастания по IA –I классу бонитета для региона исследования. Using potential fertility mosagrogen soil you can grow of target woody plants and to balance and marketable timber in a shorter time than in the lands of the forest Fund. The problem of this issue is little investigated and now it is necessary to assess the prospects of growing high productivity plantations on postagrogenic. The aim of the study was to compare forest and postagrogenic soils in such parameters as the carbon content of organic matter and total nitrogen, to predict the prospects for the organization of the economy with the accelerated cultivation of productive tree plantations on fallow lands. In postagrogenic and wooded land were selected in the area with similar conditions of soil formation under ripe forest stands belonging to the forest types: myrtillus, oxalis and quercus-herbosa and postagrogenic soil complexes of fallow lands. Conducted assessment of some physico-chemical parameters of soil common in soil science methods: determined particle size distribution, the density of the composition and power of the genetic soil horizons. The density of addition of all horizons was estimated by Kaczynski; determination of carbon was carried out by dry ashing, total Kjeldahl nitrogen, pH salt extraction by the potentiometric method. Analysis of carbon stocks of organic matter (С) and nitrogen (N) in the genetic horizons of soils of blueberry, acidic and oak-grass forest types shows an increase in the content of organic matter and total nitrogen from blueberry to oak-grass forest type. There is a decrease in the content of organic carbon from the humus horizon to the ashed one: in quercus-herbosa forest types – 2.8, acidic – 7.6, myrtillus – 8.5 times. The postagrogenic restoration to the land is curtains character or occurs at the micro depressions of the former furrows. The organic matter content in the arable horizon of postagrogenic parcel of land be at the level of parents type of the wood. The content of total nitrogen in these soils is high from 5 to 7.4 t/ha – at the level of oak-grass forest type. The ratio C: N, which characterizes the enrichment of humus nitrogen, for most humus horizons of soils is 8-10, which corresponds to a high and medium degree of security with this element. According to the content of weeds and Communities in the upper horizon of the soil form the following decreasing series: quercus-herbosa type forest > lands >forest oxalis type > myrtillus type forest > arable land. Comparative analysis of physical and agrochemical condition of postagrogenic and forest soils showed that, in spite of previous anthropogenic impact, agronomy horizon maintains a high organic matter content and total nitrogen. Deterioration of the properties of postagrogenic soils in the study areas does not occur and transformation in the direction of natural forest soils of the region is not observed, despite the long period of occurrence (over 30 years). The ratio of carbon and nitrogen in postagrogenic soils by soil profile shows a higher fertility than in forest soils, where the indicator C:N is optimal only part of the horizon A1. Assessing the suitability of the surveyed areas of fallow lands for the accelerated cultivation of different species of wood to produce biomass, it can be stated that the level of organic matter and total nitrogen exceeds or corresponds to the conditions of growth in Ia –I class of bonitet for the region of the study.


2019 ◽  
Vol 23 (10) ◽  
pp. 56-60
Author(s):  
S.I. Kolesnikov ◽  
N.A. Vernigorova ◽  
A.A. Kuzina ◽  
K.Sh. Kazeev ◽  
I.V. Kostenko ◽  
...  

A study is carried out to determine the limits of resistance of soils and ecosystems of Crimea to pollution of Pb, Cr, Cu, Ni by biological indicators. It is established that the Crimean soil in terms of resistance to Pb, Cr, Cu, Ni pollution is located as follows: residual carbonate chernozems> southern chernozems> dark chestnut alkaline ≥ mountain meadow ≥ brown carbonate> brown forest soils, and terrestrial ecosystems have the following series of stability: true steppes> dry steppes ≥ mountain meadows ≥ light forests> broad-leaved forests. In terms of ecotoxicity to heavy soils and ecosystems of Crimea, heavy metals form a series: Cr> Cu ≥ Pb ≥ Ni. The regional standards of the maximum permissible content of Pb, Cr, Cu, Ni in the main soils of the Crimea and the most effective ways of their rehabilitation in case of pollution are proposed.


1966 ◽  
Vol 46 (2) ◽  
pp. 133-138 ◽  
Author(s):  
N. S. Miljkovic ◽  
B. C. Matthews ◽  
M. H. Miller

The available boron content of the genetic horizons of eight Ontario soils was determined using a hot-water extraction and a sunflower test. The available boron was highest in the surface horizons and decreased in the zones of eluviation to a level equal to or lower than that in the parent material. The content in the horizons was generally higher than that in the C horizons.The water-soluble boron was closely related to the organic matter content in a quadratic regression (R2 = 0.691). When pH and clay content were included in regressions, a positive organic matter × pH component was the single most important variable, explaining 64.4% of the variability. Additional terms involving clay content and pH did not greatly increase the R2 value.


2016 ◽  
Vol 2016 ◽  
pp. 1-9 ◽  
Author(s):  
Mária Mörtl ◽  
Orsolya Kereki ◽  
Béla Darvas ◽  
Szandra Klátyik ◽  
Ágnes Vehovszky ◽  
...  

Movement of two neonicotinoid insecticide active ingredients, clothianidin (CLO) and thiamethoxam (TMX), was investigated in different soil types (sand, clay, or loam) and in pumice. Elution profiles were determined to explore differences in binding capacity. Soil characterized by high organic matter content retained the ingredients, whereas high clay content resulted in long release of compounds. Decrease in concentration was strongly influenced by soil types: both CLO and TMX were retained in loam and clay soils and showed ready elution through sandy soil and pumice. Elution capability of the active ingredients in sandy soil correlated with their water solubility, indicating approximately 30% higher rapidity for TMX than for CLO. Soil organic carbon-water partitioning coefficients (Koc) determined were in good agreement with literature values with somewhat lower value for CLO in sandy soil and substantially higher values for TMX in clay soil. High mobility of these neonicotinoid active ingredients in given soil types urges stronger precautionary approach taken during their application.


2007 ◽  
Vol 146 (1-3) ◽  
pp. 1-17 ◽  
Author(s):  
Ian D. Yesilonis ◽  
Bruce R. James ◽  
Richard V. Pouyat ◽  
Bahram Momen

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