scholarly journals Dielectric Properties and Substantiation of Electromagnetic Technologies for Oil Sludge Processing

2020 ◽  
Author(s):  
Eldar Rinatovich Abdeev ◽  
Minikhan Abuzarovich Fatykhov ◽  
Rail Idiatovich Saitov ◽  
Rinat Gazizyanovich Abdeev ◽  
Lenart Minnehanovich Fatykhov

In the process of reception, storage and preparation of oil for processing, significant volumes of oil-containing sludge are formed, which are not only a source of pollution, but also a valuable hydrocarbon feedstock. Long-term storage of oil with water, contact with atmospheric oxygen, and the presence of solid particles hydrophobized with asphalt-resinous and paraffinous substances contribute to the formation of “intermediate layers” in these sludges, which are ultra-stable oil-water emulsions. It is proposed to use the energy of the electromagnetic field of the high and microwave ranges when developing a technology for the destruction of oil-water emulsions. After analyzing the composition of the oil sludge, experimental studies were conducted of the dielectric loss tangenttgδδ of oil with the addition of sand and paraffin, depending on the frequency of electromagnetic oscillations in the range of 30 - 160 MHz and temperature in the range of 25 - 80 ∘ С using the cumeter method. Studies have shown that two technologies for the disposal of oil sludge are possible: HF and UHF methods. To assess the effectiveness of their application, it is necessary to conduct experimental studies of the dielectric properties of oil sludge. Keywords: oil sludge, oil sludge disposal,oil storage, oil-water emulsions, electromagnetic field

Author(s):  
Р.Р. Зиннатуллин ◽  
Л.А. Ковалева

The degree of influence of the electromagnetic field on oil dispersed systems depends on the dielectric properties of these systems, in particular oil. Dielectric properties of oil depend on the content of high molecular weight polar components: asphaltenes and resins. In this regard, a study was carried out of the dielectric properties of oil in the radio-frequency range, depending on the content of asphalt-resinous substances in it. The obtained results of experimental studies show the correlation of dielectric parameters with the ratio of the content of resins and asphaltenes in oil.


Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1593 ◽  
Author(s):  
Hajo Yagoub ◽  
Liping Zhu ◽  
Mahmoud H. M. A. Shibraen ◽  
Ali A. Altam ◽  
Dafaalla M. D. Babiker ◽  
...  

The complex aerogel generated from nano-polysaccharides, chitin nanocrystals (ChiNC) and TEMPO-oxidized cellulose nanofibers (TCNF), and its derivative cationic guar gum (CGG) is successfully prepared via a facile freeze-drying method with glutaraldehyde (GA) as cross-linkers. The complexation of ChiNC, TCNF, and CGG is shown to be helpful in creating a porous structure in the three-dimensional aerogel, which creates within the aerogel with large pore volume and excellent compressive properties. The ChiNC/TCNF/CGG aerogel is then modified with methyltrichlorosilane (MTCS) to obtain superhydrophobicity/superoleophilicity and used for oil–water separation. The successful modification is demonstrated through FTIR, XPS, and surface wettability studies. A water contact angle of 155° on the aerogel surface and 150° on the surface of the inside part of aerogel are obtained for the MTCS-modified ChiNC/TCNF/CGG aerogel, resulting in its effective absorption of corn oil and organic solvents (toluene, n-hexane, and trichloromethane) from both beneath and at the surface of water with excellent absorption capacity (i.e., 21.9 g/g for trichloromethane). More importantly, the modified aerogel can be used to continuously separate oil from water with the assistance of a vacuum setup and maintains a high absorption capacity after being used for 10 cycles. The as-prepared superhydrophobic/superoleophilic ChiNC/TCNF/CGG aerogel can be used as a promising absorbent material for the removal of oil from aqueous media.


2013 ◽  
Vol 652-654 ◽  
pp. 749-752
Author(s):  
Dan Dan Yuan ◽  
Hong Jun Wu ◽  
Hai Xia Sheng ◽  
Xin Sui ◽  
Bao Hui Wang

In order to meet the need of separating oil from water in the settling tank of the oilfield, ClO2 treatment for oil-water transition layer in settling tank is introduced. The field test displayed that the technique was achieved by a good performance. For understanding the oxidation and mechanism, compositions of oil-water transition layer were comparatively studied for before/after ClO2-treatment in this paper.The experimental results show that the compositions before and after ClO2-treatment, including physical structure and chemical composition, were varied in the great extension. The physical structure, consisting of water, oil and solid phase, was reduced to less than 5% of water and 0.5% of solid particle and increased to 95% of oil in layer compared with before-treatment, easily leading to clearly separating water from oil. The chemical composition of iron sulfide and acid insoluble substance in solid phase was decreased to more than 90% while the carbonate was reduced more than 70% . After the treatment, the viscosity reduction of the water phase in the layer was reached to 50% after oxidation demulsification with ClO2. The chemistry was discussed based on the principles and experiments. Due to ClO2 destroying (oxidizing) the rigid interface membrane structure which is supported by natural surfactant, polymer and solid particles with interface-active materials, the action accelerates the separating of water and oil and sedimentation of insoluble residue of acid in the layer. By demonstrating the experimental data and discussion, we can effectively control the oxidation performance of chlorine dioxide, which is very meaningful for oilfield on the aspect of stable production of petroleum.


2000 ◽  
Vol 3 (05) ◽  
pp. 401-407 ◽  
Author(s):  
N. Nishikiori ◽  
Y. Hayashida

Summary This paper describes the multidisciplinary approach taken to investigate and model complex water influx into a water-driven sandstone reservoir, taking into account vertical water flux from the lower sand as a suspected supplemental source. The Khafji oil field is located offshore in the Arabian Gulf. Two Middle Cretaceous sandstone reservoirs are investigated to understand water movement during production. Both reservoirs are supported by a huge aquifer and had the same original oil-water contact. The reservoirs are separated by a thick and continuous shale so that the upper sand is categorized as edge water drive and the lower sand as bottomwater drive. Water production was observed at the central up structure wells of the upper sand much earlier than expected. This makes the modeling of water influx complicated because it is difficult to explain this phenomenon only by edge water influx. In this study, a technical study was performed to investigate water influx into the upper sand. A comprehensive review of pressure and production history indicated anomalous higher-pressure areas in the upper sand. Moreover, anomalous temperature profiles were observed in some wells in the same area. At the same time, watered zones were trailed through thermal-neutron decay time(TDT) where a thick water column was observed in the central area of the reservoir. In addition, a three-dimensional (3D) seismic survey has been conducted recently, revealing faults passing through the two reservoirs. Therefore, as a result of data review and subsequent investigation, conductive faults from the lower sand were suspected as supplemental fluid conduits. A pressure transient test was then designed and implemented, which suggested possible leakage from the nearby fault. Interference of the two reservoirs and an estimate of supplemental volume of water influx was made by material balance. Finally, an improved full-scale numerical reservoir model was constructed to model complex water movement, which includes suspected supplemental water from the lower sand. Employment of two kinds of water influx—one a conventional edge water and another a supplemental water invasion from the aquifer of the lowers and through conductive faults—achieved a water breakthrough match. Introduction The Khafji oil field is located in the Arabian Gulf about 40 km offshore Al-Khafji as shown by Fig. 1. The length and width of the field are about 20 and 8 km, respectively. The upper sandstone reservoir, the subject of this study, lies at a depth of about 5,000 ft subsea and was discovered in1960. The average thickness of the reservoir is about 190 ft. The reservoir is of Middle Cretaceous geologic age. Underlying the upper sandstone reservoir is another sandstone reservoir at a depth of about 5,400 ft. It has an average gross thickness of about 650 ft and is separated from the upper sand by a thick shale bed of about 200 ft. Both reservoirs had the same original oil-water contact level as shown by the subsurface reservoir profile in Fig. 2. Both sandstone reservoirs are categorized as strong waterdrive that can maintain reservoir pressure well above the bubblepoint. On the other hand, water production cannot be avoided because of an unfavorable water-to-oil mobility ratio of 2 to 4 and high formation permeability in conjunction with a strong waterdrive mechanism. In a typical edge water drive reservoir, water production normally begins from the peripheral wells located near the oil-water contact and water encroaches as oil production proceeds. However, some production wells located in the central up structure area of the upper sand started to produce formation water before the wells located in the flank area near the water level. In 1996, we started an integrated geological and reservoir study to maximize oil recovery, to enhance reservoir management, and to optimize the production scheme for both sandstone reservoirs. This paper describes a part of the integrated study, which focused on the modeling of water movement in the upper sand. The contents of the study described in this paper are outlined as:diagnosis and description of the reservoir by fully utilizing available data, which include comprehensive review of production history, TDT logs, formation temperatures, pressures, and 3D seismic; introduction of fluid conductive faults as a suspected supplemental water source in the central upstructure area; design and implementation of a pressure transient test to investigate communication between the reservoirs and conductivity of faults; running of material balance for the two reservoirs simultaneously to assess their interference; and construction of an improved full-scale reservoir simulation model and precise modeling of complex water movement. Brief Geological Description of the Upper Sand The structure of the upper sand is anticline with the major axis running northeast to southwest. The structure dip is gentle (Fig. 3) at about3° on the northwestern flank and 2° on the southeastern flank. The upper sand is composed mainly of sandstone-dominated sandstone and shale sequences. It is interpreted that the depositional environment is complex, consisting of shoreface and tide-influenced fluvial channels.


2011 ◽  
Vol 34 (9) ◽  
pp. 1581-1586 ◽  
Author(s):  
X. Li ◽  
C. Yang ◽  
G. Zhang ◽  
Z.-S. Mao ◽  
H. Zhou

2016 ◽  
Vol 54 (4) ◽  
pp. 612-614 ◽  
Author(s):  
L. A. Kovaleva ◽  
R. R. Zinnatullin ◽  
A. I. Mullayanov ◽  
I. I. Shrubkovskii

2021 ◽  
Author(s):  
Nasser Faisal Al-Khalifa ◽  
Mohammed Farouk Hassan ◽  
Deepak Joshi ◽  
Asheshwar Tiwary ◽  
Ihsan Taufik Pasaribu ◽  
...  

Abstract The Umm Gudair (UG) Field is a carbonate reservoir of West Kuwait with more than 57 years of production history. The average water cut of the field reached closed to 60 percent due to a long history of production and regulating drawdown in a different part of the field, consequentially undulating the current oil/water contact (COWC). As a result, there is high uncertainty of the current oil/water contact (COWC) that impacts the drilling strategy in the field. The typical approach used to develop the field in the lower part of carbonate is to drill deviated wells to original oil/water contact (OOWC) to know the saturation profile and later cement back up to above the high-water saturation zone and then perforate with standoff. This method has not shown encouraging results, and a high water cut presence remains. An innovative solution is required with a technology that can give a proactive approach while drilling to indicate approaching current oil/water contact and geo-stop drilling to give optimal standoff between the bit and the detected water contact (COWC). Recent development of electromagnetic (EM) look-ahead resistivity technology was considered and first implemented in the Umm Gudair (UG) Field. It is an electromagnetic-based signal that can detect the resistivity features ahead of the bit while drilling and enables proactive decisions to reduce drilling and geological or reservoir risks related to the well placement challenges.


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