Characteristics and significance of aegirine and arfvedsonite in Boziguoer Nb-Ta-Zr-Rb-REE deposit related to alkaline granite, Xinjiang

2021 ◽  
Vol 37 (12) ◽  
pp. 3687-3711
Author(s):  
SUN ZhengHao ◽  
◽  
QIN KeZhang ◽  
MAO YaJing ◽  
TANG DongMei ◽  
...  
Keyword(s):  
Author(s):  
S. Aspiotis ◽  
S. Jung ◽  
F. Hauff ◽  
R. L. Romer

AbstractThe late-tectonic 511.4 ± 0.6 Ma-old Nomatsaus intrusion (Donkerhoek batholith, Damara orogen, Namibia) consists of moderately peraluminous, magnesian, calc-alkalic to calcic granites similar to I-type granites worldwide. Major and trace-element variations and LREE and HREE concentrations in evolved rocks imply that the fractionated mineral assemblage includes biotite, Fe–Ti oxides, zircon, plagioclase and monazite. Increasing K2O abundance with increasing SiO2 suggests accumulation of K-feldspar; compatible with a small positive Eu anomaly in the most evolved rocks. In comparison with experimental data, the Nomatsaus granite was likely generated from meta-igneous sources of possibly dacitic composition that melted under water-undersaturated conditions (X H2O: 0.25–0.50) and at temperatures between 800 and 850 °C, compatible with the zircon and monazite saturation temperatures of 812 and 852 °C, respectively. The Nomatsaus granite has moderately radiogenic initial 87Sr/86Sr ratios (0.7067–0.7082), relatively radiogenic initial εNd values (− 2.9 to − 4.8) and moderately evolved Pb isotope ratios. Although initial Sr and Nd isotopic compositions of the granite do not vary with SiO2 or MgO contents, fSm/Nd and initial εNd values are negatively correlated indicating limited assimilation of crustal components during monazite-dominated fractional crystallization. The preferred petrogenetic model for the generation of the Nomatsaus granite involves a continent–continent collisional setting with stacking of crustal slices that in combination with high radioactive heat production rates heated the thickened crust, leading to the medium-P/high-T environment characteristic of the southern Central Zone of the Damara orogen. Such a setting promoted partial melting of metasedimentary sources during the initial stages of crustal heating, followed by the partial melting of meta-igneous rocks at mid-crustal levels at higher P–T conditions and relatively late in the orogenic evolution.


2021 ◽  
Author(s):  
Long Zhang ◽  
Zhenyu Chen ◽  
Fangyue Wang ◽  
Noel C. White ◽  
Taofa Zhou

Abstract Uraninite is the main contributor to the bulk-rock uranium concentration in many U-rich granites and is the most important uranium source for granite-related uranium deposits. However, detailed textural and compositional evolution of magmatic uraninite in granites during alteration and associated uranium mobilization have not been well documented. In this study, textures and geochemistry of uraninites from the Zhuguangshan batholith (South China) were investigated by scanning electron microscopy (SEM) and electron probe microanalysis (EPMA). The geochemical data indicate that the Longhuashan and Youdong plutons are peraluminous leucogranite, the Changjiang pluton is highly fractionated high-K calc-alkaline granite, and the Jiufeng pluton belongs to a high-K calc-alkaline association. Uraninites from the Longhuashan and Youdong granites have lower concentrations of ThO2 (0.9–4.0 wt %) and rare earth elements (REE)2O3 (0.1–1.0 wt %) than those from the Changjiang and Jiufeng granites (ThO2 = 4.4–7.6 wt %, REE2O3 = 0.7–5.1 wt %). Uraninites observed in the Longhuashan, Youdong, Changjiang, and Jiufeng granites yielded chemical ages of 223 ± 3, 222 ± 2, 157 ± 1, and 161 ± 2 Ma, respectively. The samples (including altered and unaltered) collected from the Longhuashan, Youdong, and Changjiang granites are characterized by highly variable whole-rock U concentrations of 6.9 to 44.7 ppm and Th/U ratios of 0.9 to 7.0, consistent with crystallization of uraninite in these granites being followed by uranium leaching during alteration. Alteration of uraninite, indicated by altered domains developing microcracks and appearing darker in backscattered electron (BSE) images compared to unaltered domains, results in the incorporation of Si and Ca and mobilization of U. In contrast, the least altered samples of the unmineralized Jiufeng granite have low U concentrations (5.3–16.4 ppm) and high ΣREE/U (13.6–49.4) and Th/U ratios (2.1–5.6), which inhibit crystallization of uraninite, as its crystallization occurs when the U concentration is high enough to exceed the substitution capacity of other U-bearing minerals. These results indicate that the Longhuashan, Youdong, and Changjiang granites were favorable uranium sources for the formation of uranium deposits in this area. This study highlights the potential of uraninite alteration and geochemistry to assist in deciphering uranium sources and enrichment processes of granite-related uranium deposits.


2020 ◽  
Vol 57 (4) ◽  
pp. 506-523
Author(s):  
Jin-hua Qin ◽  
Cui Liu ◽  
Jin-fu Deng

We present systematic U–Pb age data collected by laser ablation multi-collector inductively coupled plasma mass spectrometry, precise geochemical data, and Nd isotope data for igneous rocks from the southeastern Lesser Xing’an Range (SE LXR). The results indicate that the formation ages as follows: Maojiatun alkaline granite, 207.2 ± 0.84 Ma and 204.6 ± 0.93 Ma; Diorite porphyrite, 164.5 ± 0.97 Ma; and Tieli syenogranite, 186.7 ± 1.50 Ma. The alkaline granite has high silicon, potassium, alkali, and FeOT contents; it is enriched in high field strength elements, Zr, Hf, Th, Rb, and U; is depleted in Ba, Sr, Nb, Ta, P, Ti, etc.; and has high ratios of 10000Ga/Al. It shows an A2-type granite affinity. The Tieli alkali-feldspar granite has high total alkali contents and is enriched in high field strength elements and rare earth elements and depleted in Sr, Ba, Ti, and P, and shows varying degrees of alkalinity. Rocks from SE LXR display similar εNd (t) values with corresponding to Nd model ages of 1095 to 813 Ma. The igneous rocks from the SE LXR are proposed to be derived from melting of the Neoproterozoic lower crust and potential magma mixing with ancient crystalline basement. The formation of the Maojiatun alkaline granite occurred in response to a postorogenic event following the closure of the Paleo-Asian Ocean. However, the SE LXR exhibited an extensional back-arc tectonic setting in the Early Jurassic. The Middle Jurassic diorite porphyrite could be related to the temporary stagnation of the westward subduction of the Paleo-Pacific plate.


2016 ◽  
Vol 4 (9) ◽  
pp. 787-801 ◽  
Author(s):  
TaysserA. Lashen ◽  
◽  
MohamedF. Cheira ◽  
DoaaI. Zaki ◽  
EmanM. Allam ◽  
...  

2017 ◽  
Vol 1 (T2) ◽  
pp. 114-123
Author(s):  
Minh Pham ◽  
Hieu Trung Pham ◽  
Hoang Kim Nguyen

Alkaline granites of the Muong Hum are distributed mainly in the NW Phan Si Pan zone. The granite closely has striped or clear gneissoid structures, coinciding with general NW-SE trends. It consists mainly of plagioclase (~20–30 %), alkaline feldspar (~30–50 %), quartz (~20–25 %), biotite (~1–5 %), aegirine (~1–3 %), and riebeckite (~1–2 %). It has 10,000×Ga/Al ratios of 4.70–4.93, A/CNK values of 0.87–0.90, and negative Eu-anomalies as well as apparent depletion of Ba, Sr, Ti, and P. The mineral assemblages and chemical characteristics show that it is typical of A-type granites. Compared with other adjacent Late Permian to Early Triassic A-type granitic plutons, geochemical characteristics of the Muong Hum granite are similar to the Phu Sa Phìn, Phan Si Pan, Ye Yen Sun, and Nam Xe-Tam Duong granites in NW Vietnam as well as the Taihe, and Panzhihua granites in SW China. Thus, the Phan Si Pan zone must have been a displaced portion of the Emeishan large igneous province. This might be a direct result of the left-lateral Cenozoic Red River shear zone.


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