scholarly journals Corrosion protection of tin by some carboxylic acids in sodium chloride solution

2020 ◽  
Vol 39 (2) ◽  
pp. 167
Author(s):  
Ivana Škugor Rončević ◽  
Nives Vladislavić ◽  
Marijo Buzuk ◽  
Maša Buljac ◽  
Anđela Lukin

Tin is a moderately corrosion resistant material that is widely used in tinplate for food beverages. However, despite its excellent corrosion resistance, the presence of oxidizing agents enhances tin dissolution. Dissolution of metallic tin, especially from the inside of a can body into the food content has a major influence on the food quality and may cause toxicological effects. To overcome the problem, different chemical compounds are added. The most utilized inhibitors in the food industry are nitrites and nitrates well-known as hazardous to health. The present study aimed to investigate the influence of carboxylic acids on the corrosion resistance of tin since they are present in fruit juices and different foodstuffs. The corrosion protection efficiency of the carboxylate coatings was investigated in a sodium chloride solution using electrochemical and spectroscopic techniques. The structural characteristics of the surface coatings were investigated using the FTIR spectroscopy and optical microscope.

RSC Advances ◽  
2015 ◽  
Vol 5 (1) ◽  
pp. 706-716 ◽  
Author(s):  
F. Ansari ◽  
R. Naderi ◽  
C. Dehghanian

An eco-friendly silane sol–gel coating incorporating nanoclay was formulated to provide an effective corrosion protection for stainless steel 304L in a NaCl solution.


2005 ◽  
Vol 498-499 ◽  
pp. 93-97
Author(s):  
L. De Micheli ◽  
Isolda Costa

In this study a corrosion protection method was used with AISI 304 SS filters and its effect on their corrosion resistance was evaluated in a sodium chloride solution (0.5 mol/L). The corrosion resistance of the surface treated filters was investigated at increasing temperatures, from 22 oC to 100 oC. It was found that the treatment improved the corrosion resistance of the filters at all temperatures tested. The film formed was maintained on the filters surface during the whole period of test (3 weeks). Surface analysis of untreated and treated filters, after corrosion tests, supported the indication of the beneficial effect of the corrosion protection treatment evaluated in this study.


2019 ◽  
Vol 18 ◽  
pp. 2881-2886 ◽  
Author(s):  
Samuel Olukayode Akinwamide ◽  
Neo Tshabalala ◽  
Oluwasegun Eso Falodun ◽  
Samuel Ranti Oke ◽  
Ojo Jeremiah Akinribide ◽  
...  

2008 ◽  
Vol 373-374 ◽  
pp. 240-243 ◽  
Author(s):  
Long Hao ◽  
Ye Ming Zhang ◽  
Chao Yang ◽  
Hua Zhu ◽  
Xu Hui Mao ◽  
...  

With suitable pretreatment, a compact and even nickel-phosphorus alloy coating was obtained on W-Cu alloy by electroless deposition from solutions containing nickel sulphate as a source of nickel and sodium hypophosphite as the reducing agent and a source of phosphorus. The Ni-P coating was normally prepared from acidic baths at high temperature of the order of 90oC with the pH of 4.8 and it was smooth and uniform and exhibited high crystal refinement and high microhardness and superior corrosion resistance. The microhardness, adhesion and corrosion resistance mechanism of Ni-P deposit were studied. The microhardness of the Ni-P alloy deposit increases greatly by tempering at various temperatures. The Ni-P deposit has a strong adhesive force with W-Cu alloy substrate checked by thermal shock test and scribe test. The anti-corrosion ability of Ni-P coating and its anti-corrosion mechanism were measured using immersion experiment and potentiodynamic polarization techniques. The results showed that the corrosion resistance of Ni-P coating was higher than that of W-Cu alloy substrate in the 10vol.% sulfuric acid, monitoring sweat solution and 3.5wt.% sodium chloride solution. The anti-corrosion mechanism of electroless Ni-P coating immersed in 3.5wt.% sodium chloride solution was studied using potentiodynamic polarization techniques. The surface micromorphological morphology and structure of the Ni-P coating were investigated using Scanning Electronic Microscope (SEM) and X-ray Diffraction (XRD). The results indicated that the Ni-P alloy coating consisted of microcrystals and it was amorphous in structure, and the electrochemical measurement showed passive film formed on Ni-P coating during immersion test in the 3.5wt.% sodium chloride solution.


2014 ◽  
Vol 893 ◽  
pp. 440-443
Author(s):  
Li Na Zhang ◽  
Jerzy A. Szpunar ◽  
Jian Xin Dong ◽  
Mai Cang Zhang

The influence of ions chloride concentration and pH value on the corrosion resistance of high-alloyed material UNS N08028 in the sodium chloride solution is investigated. Results show that the corrosion potential is active cathodically with the increase of chloride concentration. The current density and corrosion rate both increase with increasing chloride concentration and decreasing pH value.


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