scholarly journals Sustainable Boron Nitride Nanosheet-Reinforced Cellulose Nanofiber Composite Film with Improved Mechanical Properties and Oxygen Barrier without the Cost of Color and Brittleness

Author(s):  
Hoang-Linh Nguyen ◽  
Zahid Hanif ◽  
Seul-A. Park ◽  
Bong Gill Choi ◽  
Thang Hong Tran ◽  
...  

Herein, we introduce a boron nitride nanosheet (BNNS)-reinforced cellulose nanofiber (CNF) film as a sustainable oxygen barrier film that can potentially be applied in food packaging. Most of commodity plastics are oxygen-permeable. CNF exhibits an ideal oxygen transmittance rate (OTR) of <1 cc/m2/day in highly controlled conditions. A CNF film typically fabricated by the air drying of a CNF aqueous solution reveals an OTR of 19.08 cc/m2/day. The addition of 0-5 wt% BNNS to the CNF dispersion before drying results in a composite film with highly improved OTR, 4.7 cc/m2/day, which is sufficient for meat and cheese packaging. BNNS as a 2D nanomaterial increases the pathway of oxygen gas and reduces the chances of pin-hole formation during film fabrication involving water drying. In addition, BNNS improves the mechanical properties of the CNF films (Young’s modulus and tensile strength) without significant elongation reductions, probably due to the good miscibility of CNF and BNNS in the aqueous solution. BNNS addition also produces negligible color change, which is important for film aesthetics. An in vitro cell experiment was performed to reveal the low cytotoxicity of the CNF/BNNS composite. This composite film has great potential as a sustainable high-performance food packaging material.

Polymers ◽  
2018 ◽  
Vol 10 (5) ◽  
pp. 501 ◽  
Author(s):  
Hoang-Linh Nguyen ◽  
Zahid Hanif ◽  
Seul-A Park ◽  
Bong Choi ◽  
Thang Tran ◽  
...  

2020 ◽  
Vol 10 (6) ◽  
pp. 771-779
Author(s):  
Jing Deng ◽  
Qi Jue Chen ◽  
Ding Jie Chen ◽  
Luo Jie Zheng ◽  
Wen Li ◽  
...  

The aim of this research was to probe the potential application of nano-titanium dioxide (TiO2)/basic magnesium hypochlorite (BMH)-containing linear low-density polyethylene (LLDPE) composite film in grape fresh-keeping. Mechanical properties, transparency, barrier performance and antibacterial activity of the nano-composite membrane were measured, and results showed that the antibacterial zone diameter of TiO2/BMH on pathogen-Aspergillus niger was 31.4 mm, with mixing ratio of BMH/TiO2 to 2:1. It was clearly shown that the synthesized nano-composite films decreased mechanical properties and transparency of the membrane, and also had a significant impact on sensory score, mass loss rate, decay rate, ascorbic acid (Vc) content and titratable acid content compared with LLDPE films. Moreover, the results revealed that the LLDPE antibacterial film can be effectively used for storing grapes, preserving the flavor of grapes and had an obviously effect in prolonging grapes’ shelf life.


Author(s):  
Thefye Sunthar ◽  
Elia Marin ◽  
Francesco Boschetto ◽  
Matteo Zanocco ◽  
Hirofumi Sunahara ◽  
...  

With the increased scientific interest in green technologies, many researches have been focused on the production of polymeric composites containing naturally occurring reinforcing particles. Apart from increasing mechanical properties, these additions can have a wide range of interesting effects, such as increasing the resistance to bacterial and fungal colonization. In this work, different amounts of two different natural products, namely neem and turmeric, have been added to polyethylene to act as a natural antibacterial and antifungal product for food packaging applications. Microscopic and spectroscopic characterization showed that fractions up to 5% of these products can be dispersed into low-molecular weight polyethylene, while higher amounts could not be properly dispersed and resulted in an inhomogeneous, fragile composite. In vitro testing conducted with Escherichia coli, Staphylococcus aureus and Candida albicans showed a reduced proliferation of pathogens when compared to the polyethylene references. In particular, turmeric, resulted to be more effective against E. coli when compared to neem, while they had similar performances against S. aureus. Against C. albicans, only neem was able to show a good antifungal behavior, at high concentrations. Tensile testing showed that the addition of reinforcing particles reduces the mechanical properties of polyethylene, and, in the case of turmeric, it is further reduced by UV irradiation.


2020 ◽  
Vol 55 (29) ◽  
pp. 14501-14515 ◽  
Author(s):  
Changbo Wang ◽  
Jinyang Feng ◽  
Jian Zhou ◽  
Xiaoguang Huang ◽  
Lin Wang ◽  
...  

Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 379
Author(s):  
Seonmin Lee ◽  
Jooheon Kim

Aggregated boron nitride (ABN) is advantageous for increasing the packing and thermal conductivity of the matrix in composite materials, but can deteriorate the mechanical properties by breaking during processing. In addition, there are few studies on the use of Ti3C2 MXene as thermally conductive fillers. Herein, the development of a novel composite film is described. It incorporates MXene and ABN into poly(vinyl alcohol) (PVA) to achieve a high thermal conductivity. Polysilazane (PSZ)-coated ABN formed a heat conduction path in the composite film, and MXene supported it to further improve the thermal conductivity. The prepared polymer composite film is shown to provide through-plane and in-plane thermal conductivities of 1.51 and 4.28 W/mK at total filler contents of 44 wt.%. The composite film is also shown to exhibit a tensile strength of 11.96 MPa, which is much greater than that without MXene. Thus, it demonstrates that incorporating MXene as a thermally conductive filler can enhance the thermal and mechanical properties of composite films.


2018 ◽  
Vol 6 (46) ◽  
pp. 12739-12745 ◽  
Author(s):  
Yapeng Chen ◽  
Xiao Hou ◽  
Ruiyang Kang ◽  
Yun Liang ◽  
Liangchao Guo ◽  
...  

A highly flexible cellulose nanofiber/graphene composite film with metal-like thermal conductivity and outstanding strength was fabricated via simple vacuum-assisted filtration.


2021 ◽  
Vol 321 ◽  
pp. 114920
Author(s):  
Jafar Azamat ◽  
Jaber Jahanbin Sardroodi ◽  
Leila Poursoltani ◽  
Darian Jahanshahi

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