scholarly journals Achieving Net Zero Carbon Dioxide by Sequestering Biomass Carbon

Author(s):  
Jeffrey Amelse

Mitigation of global warming requires an understanding of where energy is produced and consumed, the magnitude of carbon dioxide generation, and proper understanding of the Carbon Cycle. The latter leads to the distinction between and need for both CO2 and biomass CARBON sequestration. Short reviews are provided for prior technologies proposed for reducing CO2 emissions from fossil fuels or substituting renewable energy, focusing on their limitations. None offer a complete solution. Of these, CO2 sequestration is poised to have the largest impact. We know how to do it. It will just cost money, and scale-up is a huge challenge. Few projects have been brought forward to semi-commercial scale. Transportation accounts for only about 30% of U.S. overall energy demand. Biofuels penetration remains small, and thus, they contribute a trivial amount of overall CO2 reduction, even though 40% of U.S. corn and 30% of soybeans are devoted to their production. Bioethanol is traced through its Carbon Cycle and shown to be both energy inefficient, and an inefficient use of biomass carbon. Both biofuels and CO2 sequestration reduce FUTURE CO2 emissions from continued use of fossil fuels. They will not remove CO2 ALREADY in the atmosphere. The only way to do that is to break the Carbon Cycle by growing biomass from atmospheric CO2 and sequestering biomass CARBON. Theoretically, sequestration of only a fraction of the world’s tree leaves, which are renewed every year, can get the world to Net Zero CO2 without disturbing the underlying forests.

Author(s):  
Jeffrey Amelse

Mitigation of global warming requires an understanding of where energy is produced and consumed, the magnitude of carbon dioxide generation, and proper understanding of the Carbon Cycle. The latter leads to the distinction between and need for both CO2 and biomass CARBON sequestration. Short reviews are provided for prior technologies proposed for reducing CO2 emissions from fossil fuels or substituting renewable energy, focusing on their limitations. None offer a complete solution. Of these, CO2 sequestration is poised to have the largest impact. We know how to do it. It will just cost money, and scale-up is a huge challenge. Few projects have been brought forward to semi-commercial scale. Transportation accounts for only about 30% of U.S. overall energy demand. Biofuels penetration remains small, and thus, they contribute a trivial amount of overall CO2 reduction, even though 40% of U.S. corn and 30% of soybeans are devoted to their production. Bioethanol is traced through its Carbon Cycle and shown to be both energy inefficient, and an inefficient use of biomass carbon. Both biofuels and CO2 sequestration reduce FUTURE CO2 emissions from continued use of fossil fuels. They will not remove CO2 ALREADY in the atmosphere. The only way to do that is to break the Carbon Cycle by growing biomass from atmospheric CO2 and sequestering biomass CARBON. Theoretically, sequestration of only a fraction of the world’s tree leaves, which are renewed every year, can get the world to Net Zero CO2 without disturbing the underlying forests. Thoughts are put forth on how to achieve secure permanent biomass sequestration.


Author(s):  
Jeffrey Amelse

Many corporations aspire to become Net Zero Carbon Dioxide by 2030-2050. This paper examines what it will take. It requires understanding where energy is produced and consumed, the magnitude of CO2 generation, and the Carbon Cycle. Reviews are provided for prior technologies for reducing CO2 emissions from fossil to focus on their limitations and to show that none offer a complete solution. Both biofuels and CO2 sequestration reduce future CO2 emissions from fossil fuels. They will not remove CO2 already in the atmosphere. Planting trees has been proposed as one solution. Trees are a temporary solution. When they die, they decompose and release their carbon as CO2 to the atmosphere. The only way to permanently remove CO2 already in the atmosphere is to break the Carbon Cycle by growing biomass from atmospheric CO2 and sequestering biomass carbon. Permanent sequestration of leaves is proposed as a solution. Leaves have a short Carbon Cycle time constant. They renew and decompose every year. Theoretically, sequestrating a fraction of the world’s tree leaves can get the world to Net Zero without disturbing the underlying forests. This would be CO2 capture in its simplest and most natural form. Permanent sequestration may be achieved by redesigning landfills to discourage decomposition. In traditional landfills, waste undergoes several stages of decomposition, including rapid initial aerobic decomposition to CO2, followed by slow anaerobic decomposition to methane and CO2. The latter can take hundreds to thousands of years. Understanding landfill chemistry provides clues to disrupting decomposition at each phase.


Author(s):  
Jeffrey Amelse

Many corporations aspire to become Net Zero Carbon Dioxide by 2030-2050. This paper examines what it will take. It requires understanding where energy is produced and consumed, the magnitude of CO2 generation, and the Carbon Cycle. Reviews are provided for prior technologies for reducing CO2 emissions from fossil to focus on their limitations and to show that none offer a complete solution. Both biofuels and CO2 sequestration reduce future CO2 emissions from fossil fuels. They will not remove CO2 already in the atmosphere. Planting trees has been proposed as one solution. Trees are a temporary solution. When they die, they decompose and release their carbon as CO2 to the atmosphere. The only way to permanently remove CO2 already in the atmosphere is to break the Carbon Cycle by growing biomass from atmospheric CO2 and sequestering biomass carbon. Permanent sequestration of leaves is proposed as a solution. Leaves have a short Carbon Cycle time constant. They renew and decompose every year. Theoretically, sequestrating a fraction of the world’s tree leaves can get the world to Net Zero without disturbing the underlying forests. This would be CO2 capture in its simplest and most natural form. Permanent sequestration may be achieved by redesigning landfills to discourage decomposition. In traditional landfills, waste undergoes several stages of decomposition, including rapid initial aerobic decomposition to CO2, followed by slow anaerobic decomposition to methane and CO2. The latter can take hundreds to thousands of years. Understanding landfill chemistry provides clues to disrupting decomposition at each phase.


Author(s):  
Jeffrey Amelse ◽  
Paul K. Behrens

Many corporations and governments aspire to become Net Zero Carbon Dioxide by 2030-2050. Achieving Net Zero CO2 requires understanding where energy is produced and consumed, the magnitude of CO2 generation, and the Carbon Cycle. It is unreasonable to assume that fossil fuel can be completely replaced, and thus, atmospheric CO2 will continue to accumulate. Many prior proposed solutions focus on reducing future CO2 emissions from continued use of fossil fuels. Examination of these technologies exposes their limitations and shows that none offer a complete solution. Direct Capture technologies are needed to reduce CO2 already in the air. However, some of those already proposed would lead to a very high cost of Carbon Capture, Use, and Storage (CCUS). Biofuels can help achieve reduction goals. However, two of the six carbons in sugar fermented to bioethanol produce CO2 per the stoichiometry of the reaction. Four carbons go to ethanol, which go back to the atmosphere upon burning in an engine. Thus, without CCUS, which most current bioethanol plants do not practice, bioethanol would at best be sustainable. The only way to permanently remove CO2 already in the atmosphere is to break the Carbon Cycle by growing biomass from atmospheric CO2 and permanently sequestering that biomass carbon. Permanent sequestration can be achieved in landfills modified to discourage biomass decomposition to CO2 and methane. Sequestration of biomass carbon is proposed as a simple and natural means of Direct Capture. Tree leaves are proposed as a good source of biomass for this purpose. Left unsequestered, leaves decompose with a short Carbon Cycle time constant releasing CO2 back to the atmosphere. Leaves represent a substantial fraction of the total biomass generated by a tree when integrated over a tree’s lifetime. High yield crops, such as switchgrass would also be a good source of biomass. The cost for growing switchgrass and sequestering it in a landfill is estimated to be on the order of $120/mt CO2 for a conservative yield of 3.5 tons/acre and may be reduced to as low as $88/mt CO2 if the development of high yield switchgrass is successful. This compares to an estimated cost of CCUS from the Steam Reforming of Methane to produce hydrogen of about $190/mt. Thus, sequestration of biomass is shown to be a natural, carbon efficient, and low-cost method of Direct Capture.


Author(s):  
Jeffrey Amelse ◽  
Paul K. Behrens

Many corporations and governments aspire to become Net Zero Carbon Dioxide by 2030-2050. Achieving Net Zero CO2 requires understanding where energy is produced and consumed, the magnitude of CO2 generation, and the Carbon Cycle. It is unreasonable to assume that fossil fuel can be completely replaced, and thus, atmospheric CO2 will continue to accumulate. Many prior proposed solutions focus on reducing future CO2 emissions from continued use of fossil fuels. Examination of these technologies exposes their limitations and shows that none offer a complete solution. Direct Capture technologies are needed to reduce CO2 already in the air. However, some of those already proposed would lead to a very high cost of Carbon Capture, Use, and Storage (CCUS). Biofuels can help achieve reduction goals. However, two of the six carbons in sugar fermented to bioethanol produce CO2 per the stoichiometry of the reaction. Four carbons go to ethanol, which go back to the atmosphere upon burning in an engine. Thus, without CCUS, which most current bioethanol plants do not practice, bioethanol would at best be sustainable. The only way to permanently remove CO2 already in the atmosphere is to break the Carbon Cycle by growing biomass from atmospheric CO2 and permanently sequestering that biomass carbon. Permanent sequestration can be achieved in landfills modified to discourage biomass decomposition to CO2 and methane. Sequestration of biomass carbon is proposed as a simple and natural means of Direct Capture. Tree leaves are proposed as a good source of biomass for this purpose. Left unsequestered, leaves decompose with a short Carbon Cycle time constant releasing CO2 back to the atmosphere. Leaves represent a substantial fraction of the total biomass generated by a tree when integrated over a tree’s lifetime. High yield crops, such as switchgrass would also be a good source of biomass. The cost for growing switchgrass and sequestering it in a landfill is estimated to be on the order of $120/mt CO2 for a conservative yield of 3.5 tons/acre and may be reduced to as low as $88/mt CO2 if the development of high yield switchgrass is successful. This compares to an estimated cost of CCUS from the Steam Reforming of Methane to produce hydrogen of about $190/mt. Thus, sequestration of biomass is shown to be a natural, carbon efficient, and low-cost method of Direct Capture.


2020 ◽  
pp. 149-159
Author(s):  
Jatinder Kataria ◽  
Saroj Kumar Mohapatra ◽  
Amit Pal

The limited fossil reserves, spiraling price and environmental impact due to usage of fossil fuels leads the world wide researchers’ interest in using alternative renewable and environment safe fuels that can meet the energy demand. Biodiesel is an emerging renewable alternative fuel to conventional diesel which can be produced from both edible and non-edible oils, animal fats, algae etc. The society is in dire need of using renewable fuels as an immediate control measure to mitigate the pollution level. In this work an attempt is made to review the requisite and access the capability of the biodiesel in improving the environmental degradation.


Molecules ◽  
2021 ◽  
Vol 26 (2) ◽  
pp. 500
Author(s):  
Juan Antonio Cecilia ◽  
Daniel Ballesteros Plata ◽  
Enrique Vilarrasa García

After the industrial revolution, the increase in the world population and the consumption of fossil fuels has led to an increase in anthropogenic CO2 emissions [...]


Author(s):  
Tuan-Dung Hoang ◽  
Nhuan Nghiem

Ethanol produced from various biobased sources (bioethanol) has been gaining high attention lately due to its potential to cut down net emissions of carbon dioxide while reducing burgeoning world dependence on fossil fuels. Global ethanol production has increased more than six-fold from 18 billion liters at the turn of the century to 110 billion liters in 2019 (1,2). Sugar cane and corn have been used as the major feedstocks for ethanol production. Lignocellulosic biomass has recently been considered as another potential feedstock. This paper reviews recent developments and current status of commercial production of ethanol across the world. The review includes the ethanol production processes used for each type of feedstock, both currently practiced at commercial scale and newly developed technologies, and production trends in various regions and countries in the world.


2009 ◽  
Vol 4 (4) ◽  
pp. 93-100 ◽  
Author(s):  
Mira Heinze ◽  
Karsten Voss

Zero energy consumption. The goal sounds simple and is presented excessively in variations all over the world. Energy and environmental politics demand zero consumption as a long-term goal, marketing has discovered the concept and first buildings and settlements aiming at balanced energy or emission budgets have been constructed. As an example, the German Federal Government specifies in its fifth energy research programme (2005): For new buildings, the goal is to reduce the primary energy demand, i.e. the energy demand for heating, domestic hot water, ventilation, air-conditioning, lighting and auxiliary energy, again by half compared to the current state of the art. The long-term goal is zero-emission buildings. England and the USA aim for zero carbon developments and net-zero energy buildings (DOE, 2009) in political programmes. The Vatican accepted the offer of climatic “indulgence”—and thus became the first country in the world to completely compensate its carbon emission (Spiegel online, 2007). Megaprojects in the growth regions of the Arabian Gulf and China advertise with a CO2-neutral balance. A Zero Carbon Community is to be created in Masdar, Abu Dhabi (Foster, 2007), and the first Chinese carbon-neutral ecocity was planned for Dongtan, Shanghai (Pearce, 2009). Not only to aid international communication, but also to further the processes required to solve energy-related problems, it is essential that key words, central concepts, their usage and their relationships be clarified. This article intends to contribute to this clarification based on the monitored example of a solar estate. Net zero energy building, equilibrium building, carbon neutral city—the accounting method varies, depending on motivation and point of view. If the focus is on finite and scarce resources, energy is the currency; CO2-equivalent emissions are considered if global warming and public health is the issue; the cost of energy is what concerns a tenant paying for heating and electricity. A balance in one set of units can be converted to another, but the conversion factors often also shift the balance point. Energy will be used as the reference quantity in the following article, which prevents confusion with non-energy measures (e.g. carbon credits for forestry) and avoids the nuclear power debate, in which nuclear power is partly calculated as being CO2 neutral. The diversity of concepts is an indicator that a scientifically based methodology is still lacking, though initial publications focus hereon (Pless et al. 2009). Since October 2008, a group of experts in the International Energy Agency has been addressing this issue under the heading, Towards Net Zero Energy Solar Buildings (Riley et al. 2008). The goal is to document and analyse outstanding examples that are close to being net zero-energy buildings, and while doing so, to develop the methodology and tools for working with such buildings. The Chair of Technical Building Services, University of Wuppertal, is co-ordinating the methodological work. The zero-energy approach—still under construction—will here be presented using a solar estate as an illustration.


Energies ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 596 ◽  
Author(s):  
Samuel Simon Araya ◽  
Vincenzo Liso ◽  
Xiaoti Cui ◽  
Na Li ◽  
Jimin Zhu ◽  
...  

This review presents methanol as a potential renewable alternative to fossil fuels in the fight against climate change. It explores the renewable ways of obtaining methanol and its use in efficient energy systems for a net zero-emission carbon cycle, with a special focus on fuel cells. It investigates the different parts of the carbon cycle from a methanol and fuel cell perspective. In recent years, the potential for a methanol economy has been shown and there has been significant technological advancement of its renewable production and utilization. Even though its full adoption will require further development, it can be produced from renewable electricity and biomass or CO2 capture and can be used in several industrial sectors, which make it an excellent liquid electrofuel for the transition to a sustainable economy. By converting CO2 into liquid fuels, the harmful effects of CO2 emissions from existing industries that still rely on fossil fuels are reduced. The methanol can then be used both in the energy sector and the chemical industry, and become an all-around substitute for petroleum. The scope of this review is to put together the different aspects of methanol as an energy carrier of the future, with particular focus on its renewable production and its use in high-temperature polymer electrolyte fuel cells (HT-PEMFCs) via methanol steam reforming.


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