scholarly journals Rheological and Component Characterization of an Innovative Bio-Binder Using Guayule Resin in Partial and Entire Asphalt Replacement

Author(s):  
Ahmed Hemida ◽  
Magdy Abdelrahman

Asphalt cement will not last for a long time as the world encounters a diminishment in the crude oil. For sustainable, flexible pavement development, new resources can provide a contribution to replace it partially or entirely. In this study, asphalt was partially and entirely replaced by guayule resin as a bioresource by-product, extracted during the guayule natural rubber production. Crumb rubber modifier (CRM) was used as an asphalt enhancer. The Superpave grading system was followed at high, intermediate, and low temperatures to evaluate such innovative binder for rutting, fatigue, and thermal cracking, respectively, in addition to viscosity. Therefore, the original, short-term aging and long-term aging were simulated using tank, rolling thin film oven, and pressure aging vessel materials. Additionally, component analysis using Fourier-transform infrared spectroscopy was provided to link the rheological properties with the chemical changes. Outcomes showed a relatively much lower viscosity of guayule in the same high-temperature asphalt grade indicating savings in plant energy consumption and reduced environmental emissions. CRM enhanced guayule, but not as much as asphalt, proven by polymeric component migration through liquid binder. This enhancement was reflected in the rheological performance besides other factors. As-received guayule seems to have high oxygen content proven by strong absorption peak intensities of oxidative bonds (e.g., Carbonyl and sulfoxide). Such pre-oxidation was negatively reflected in the intermediate- and low-temperature performance of guayule and guayule-based binders. However, the investigated guayule had potential to compensate for asphalt replacement in the presence of CRM by 23–42% by weight of blend.

2016 ◽  
Vol 2016 ◽  
pp. 1-11 ◽  
Author(s):  
Octavian Pastravanu ◽  
Mihaela-Hanako Matcovschi

The main purpose of this work is to show that the Perron-Frobenius eigenstructure of a positive linear system is involved not only in the characterization of long-term behavior (for which well-known results are available) but also in the characterization of short-term or transient behavior. We address the analysis of the short-term behavior by the help of the “(M,β)-stability” concept introduced in literature for general classes of dynamics. Our paper exploits this concept relative to Hölder vectorp-norms,1≤p≤∞, adequately weighted by scaling operators, focusing on positive linear systems. Given an asymptotically stable positive linear system, for each1≤p≤∞, we prove the existence of a scaling operator (built from the right and left Perron-Frobenius eigenvectors, with concrete expressions depending onp) that ensures the best possible values for the parametersMandβ, corresponding to an “ideal” short-term (transient) behavior. We provide results that cover both discrete- and continuous-time dynamics. Our analysis also captures the differences between the cases where the system dynamics is defined by matrices irreducible and reducible, respectively. The theoretical developments are applied to the practical study of the short-term behavior for two positive linear systems already discussed in literature by other authors.


Author(s):  
Zhurinov M.Zh., ◽  
◽  
Teltayev B.B., ◽  
Kalybay A.A., ◽  
Rossi C.O., ◽  
...  

A comparative analysis of the low temperature resistance for a nanocarbon bitumen and other 30 neat and modified bitumens has been performed in the work. The stiffness at the temperatures of -24°С, -30°С and -36°С under technical system Superpave has been accepted as an indicator of low temperature resistance of the bitumens. The stiffness of the bitumens has been determined on a bending beam rheometer (standard ASTM D 6648-08). Before testing the bitumens have been subjected to the double artificial aging: short-term aging – under standard AASHTO Т 240-13 and long-term aging – under standard ASTM D 6521-08. The nanocarbon bitumen has been prepared in the laboratory of the Kazakhstan Highway Research Institute (KazdorNII) with the use of a road bitumen of the grade BND 70/100 produced by the Pavlodar petrochemical plant (PNHZ) and a nanocarbon powder (2% by weight) manufactured from a coal rock of the deposit “Saryadyr” “Corporation “ON-Olzha” LLP, Akmola region, Kazakhstan). The nanocarbon powder (150-200 nm) has been manufactured by three-stage size reduction of the coal rock: I – a mechanical dispergator (up to 2-3 mm), II – an aerodynamic mill (up to 20 mcm), III – a reactor with a rotating electromagnetic field. The neat bitumens of the grades BND 50/70, BND 70/100, BND 100/130 have been produced by the plants of Kazakhstan and Russia; they satisfy the requirements of the standard ST RK 1373-2013. The modified bitumens have been prepared in the laboratory of KazdorNII with the use of the neat bitumens, 7 types of the polymers, crumb rubber and polyphosphoric acid and they satisfy the requirements of the standard ST RK 2534-2014. It has been determined that the nanocarbon bitumen is one of the most resistant at the low temperatures: -24°С, -30°С and -36°С.


2021 ◽  
Vol 7 (3D) ◽  
pp. 450-457
Author(s):  
Dmitry V. Pashchenko ◽  
Dmitry A. Trokoz ◽  
Alexey I. Martyshkin ◽  
Elena A. Balzannikova

This article discusses one of the main problems of user identification by keyboard handwriting - short-term changes in the keystroke dynamics of users in connection with its psychophysical state, as well as changes over a long time associated with the formation of keystroke dynamics by a new user or when switching to a new device. A method for determining the phase of working capacity by the time characteristics of the keystroke dynamics is proposed.


Author(s):  
Roberto Llorente ◽  
Marta Beltran ◽  
Joaquin Perez ◽  
Noboru Uehara ◽  
Md. Khan ◽  
...  

2020 ◽  
pp. 096739112097116
Author(s):  
Yuru Wang ◽  
He Ren ◽  
Yibin Yan ◽  
Shuyan He ◽  
Shuang Wu ◽  
...  

The effects of four hindered phenolic antioxidants in the short-term heat-oxygen stability of High-Density Polyethylene (HDPE) was evaluated by the Melt Flow Rate (MFR) and Oxidation Induction Time (OIT) analyses. The results showed that Irganox 1330 and Irganox 1010 had more excellent processing property and oxidation resistance behavior in HDPE than Irganox 1024 and Irganox 3114. The OIT values of HDPE with Irganox 1330 and Irganox 1010 were up to 97.25 min and 89.73 min respectively. The long-term accelerated heat-oxygen stability tests of HDPE containing hindered phenolic antioxidants were carried out at 110°C in deionized water pressurized with pure oxygen at a pressure of 10 MPa. The characterization of the long-term heat-oxygen stability was performed by Fourier Transform Infrared (FTIR), Differential Scanning Calorimetry (DSC) and tensile testing. However, the results exhibited that the aging resistance of HDPE containing Irganox 1010 was inferior to that of HDPE containing Irganox 1024 and Irganox 3114, which is quite contrary to their short-term effect on HDPE stabilization. It may be speculated that the ester groups of Irganox 1010 undergo hydrolysis during the long-term heat-oxygen stability tests, leading to the formation of 3-(3,5-ditert-butyl-4-hydroxy-phenyl) propanoic acid and pentaerythritol.


Author(s):  
Omid Noorikalkhoran ◽  
Massimiliano Gei

During a severe accident or Beyond Design Basis Accident (BDBA), the reaction of water with zirconium alloy as fuel clad, radiolysis of water, molten corium-concrete interaction (MCCI) and post-accident corrosion can generate a source of hydrogen. In the present work, hydrogen distribution due to in-vessel reaction (between zircaloy and steam) has been simulated inside a WWER-1000 reactor containment. In the first step, the thermal hydraulic parameters of containment have been simulated for a DECL (Double Ended Cold Leg) accident (DBA phase) in both short and long time and the effects of spray as Engineering Safety Features (ESFs) on mitigating the parameters have been studied. In the second step, it has been assumed that the accident developed into an in-vessel core melting accident. While in pre-phase of core melting (severe accident phase), hydrogen will be produced as a result of zircaloy and steam reaction (BDBA phase), the hydrogen distribution has been simulated for 23 cells inside the reactor containment by using CONTAIN 2.0 (Best estimate code) and MELCOR 1.8.6 codes. Finally, the results have been compared to FSAR results. As it can be seen from the comparisons, both CONTAIN and MELCOR codes can predict the results in good agreement with FSAR (ANGAR code) results. CONTAIN shows peak pressure around 0.36 MPa in short-term and this amount is about 0.38 and 0.4 MPa for MELCOR and ANGAR (FSAR) results respectively. All these values are under design pressure that is around 0.46 MPa. Cell 20 has the maximum mole fraction of hydrogen in long-term about 9.5% while the maximum amount of hydrogen takes place in cell 22. The differences between the results of codes are because of different equations, Models, Numerical methods and assumptions that have been considered by the codes. The simulated Hydrogen Distribution Map (HDM) can be used for upgrading the location of HCAV systems and Hydrogen Mitigator features (like the recombiners and ignitors) inside the containment to reduce the risk of hydrogen explosion.


Perception ◽  
1996 ◽  
Vol 25 (2) ◽  
pp. 207-220 ◽  
Author(s):  
James V Stone

An unsupervised method is presented which permits a set of model neurons, or a microcircuit, to learn low-level vision tasks, such as the extraction of surface depth. Each microcircuit implements a simple, generic strategy which is based on a key assumption: perceptually salient visual invariances, such as surface depth, vary smoothly over time. In the process of learning to extract smoothly varying invariances, each microcircuit maximises a microfunction. This is achieved by means of a learning rule which maximises the long-term variance of the state of a model neuron and simultaneously minimises its short-term variance. The learning rule involves a linear combination of anti-Hebbian and Hebbian weight changes, over short and long time scales, respectively. The method is demonstrated on a hyperacuity task: estimating subpixel stereo disparity from a temporal sequence of random-dot stereograms. After learning, the microcircuit generalises, without additional learning, to previously unseen image sequences. It is proposed that the approach adopted here may be used to define a canonical microfunction, which can be used to learn many perceptually salient invariances.


2004 ◽  
Vol 56 (2-3) ◽  
pp. 229-246 ◽  
Author(s):  
Alwynne B. Beaudoin

Abstract The Northern Great Plains region is especially sensitive to drought and is likely to be even more drought-prone under projected global warming. Drought has been invoked as an explanatory factor for changes seen in postglacial paleoenvironmental records. These proxy records may extend drought history derived from instrumental data. Moreover, in the last decade, some paleoenvironmental studies have been expressly undertaken for the examination of long-term drought history. Nevertheless, few such studies explicitly define drought. This makes it difficult to compare results or to understand what the results mean in terms of the operational drought definitions that are used in resource management. Operational drought is defined as usually short-term; longer sustained dry intervals reflect a shift to aridity. Therefore, high resolution paleoenvironmental proxies (annual or subdecadal) are best for the investigation of drought history. Such proxies include tree rings and some lake records. However, most lake-based records are sampled at lower resolution (decadal or subcentury) and are therefore providing aridity signals.


2018 ◽  
Vol 7 (4) ◽  
pp. 50
Author(s):  
Al-Hadidy A.I. ◽  
Abdullah M. Rashed

Short and long term aging were conducted on the dense graded asphalt mixtures (DGAMs) containing 40-50 penetration grade asphalt cement binders. The short term oven aging (STOA) was conducted on loose mixtures at temperature of 135 °C for four hours and at temperature of 154 °C for two hours, whereas, the long term oven aging (LTOA) was conducted at temperature of 85 °C and at two periods of time between four and eight days. Marshall properties, tensile and compressive strength at 25 and 60°C, flexural strength at 0 and -10°C, cohesion at 60°C, tensile strength ratio, and index of retained strength were carried out on unaged and aged DGAM. A mechanistic-empirical design approach using BISAR program was adopted for estimating the improvement in service life of the pavement or reduction in thickness of DGAM and base layer for the same service life due to the aging of DGAM. The results showed that the STOA and LTOA: (1) increases resistance of DGAM against permanent deformation, stripping, and flexural strength; (2) increases traffic benefit ratio between 10 and 20%; (3) reduces the thickness of the surface layer between 8 and 14%; and (4) the base thickness reduces between 35% and 57%.


2008 ◽  
Vol 8 (6) ◽  
pp. 1217-1228 ◽  
Author(s):  
A. Sánchez-Arcilla ◽  
D. González-Marco ◽  
R. Bolaños

Abstract. This paper reviews the characterization of wave storms along the Spanish/Catalan Mediterranean coast. It considers the "physical" and "statistical" description of wave parameters and how they are affected by the prevailing meteo patterns and the sharp gradients in orography and bathymetry. The available field data and numerically simulated wave fields are discussed from this perspective. The resulting limits in accuracy and predictability are illustrated with specific examples. This allows deriving some conclusions for both short-term operational predictions and a long-term climatic assessment.


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