New Analytical Method to Calculate Matrix- and Fluid-Corrected Total Porosity in Organic Shale

2014 ◽  
Author(s):  
Edwin Ortega ◽  
Carlos Torres-Verdin
2015 ◽  
Vol 18 (04) ◽  
pp. 609-623
Author(s):  
Edwin Ortega ◽  
Carlos Torres-Verdín

Summary Estimation of total porosity from neutron and density porosity logs in organic shale (source rock) is challenging because these logs are substantially affected by fluid and matrix-composition effects. Conventional interpretation of neutron and density porosity logs often includes corrections for shale concentration in which the main objective is to improve the calculation of nonshale porosity in hydrocarbon-bearing zones. These corrections are not desirable in unconventional rock formations because shale pores can be hydrocarbon-saturated. Neutron and density porosity readings across shale zones are sometimes averaged by use of the root-mean-square (RMS) method. We introduce a new and simple analytical expression for total porosity that effectively separates both matrix and fluid effects on neutron and density porosity logs. The expression stems from a new nonlinear mixing law for neutron migration length that is coupled with the linear-density mixing law to calculate total porosity and fluid density. The method is applied in two sequential steps: First, separate corrections for only matrix effects are implemented to enhance the neutron-density crossover for qualitative interpretation of fluid type; second, the coupled equation is used to estimate fluid density and actual porosity devoid of matrix and fluid effects. Calculated porosity and fluid density can be used further to calculate water saturation from density logs. One remarkable feature of this method is the ease with which it can be applied to obtain accurate and reliable results. Application of the method only requires knowledge of single-component nuclear properties and mineral volumetric concentrations. One can obtain nuclear properties from a set of charts for multiple fluid types and minerals provided in this paper, whereas one can calculate mineral concentrations on the basis of available triple combo logs or gamma ray spectroscopy logs. Two synthetic and four field examples (two conventional and two shale-gas reservoirs) are used to test the method. First, we describe an application in a conventional siliciclastic sedimentary sequence in which only shale concentration calculated from gamma ray logs is required to improve the estimation of porosity in shaly sections. Second, we document several applications in which gamma ray spectroscopy logs are used together with a reliable hypothesis for clay type to define mineral properties. Results compare well with nuclear-magnetic-resonance (NMR) and core measurements, whereas the new method outperforms the conventional RMS procedure, especially in the cases of gas-bearing, low-porosity organic shale. The new analytical method can be readily implemented on an Excel spreadsheet and requires minimal adjustments for its operation.


2021 ◽  
Author(s):  
Xinglin Wang ◽  
◽  
Philip M. Singer ◽  
Zeliang Chen ◽  
Yunke Liu ◽  
...  

Of particular interest in unconventional reservoir characterization is an NMR log of total porosity and macro-pore hydrocarbon saturation, where both quantities are independent of a mineralogy model. A log of the macro-pore hydrocarbon saturation has a direct impact on calculating hydrocarbon reserves. It helps identify sweet spots in the reservoir to optimize horizontal-well placement for hydraulic fracturing and production. It also helps avoid water production which would negatively affect the economics of the well. However, NMR logs in unconventional shale are challenging due to potential overlapping signal in the 1-dimensional (1-D) 𝑇𝑇2 domain between micropore water and bound hydrocarbon (i.e. bitumen), and, macro-pore water and hydrocarbons. In response to this challenge, NMR core-analysis in unconventional organic-shale has proven that 2-dimensional (2-D) 𝑇𝑇1 − 𝑇𝑇2 correlation maps and the 𝑇𝑇1/𝑇𝑇2 ratio can be a powerful technique for fluid typing and saturation. One limitation is that these techniques often just compare fully hydrocarbon-saturated with fully brine-saturated cores to calibrate a set of cutoffs in 𝑇𝑇1, 𝑇𝑇2, and/or 𝑇𝑇1/𝑇𝑇2 ratio. These cutoffs are then blindly applied to 𝑇𝑇1 − 𝑇𝑇2 maps from logs or cores of unknown saturation to determine the macro-pore hydrocarbon saturation in the unconventional organic shale. An example from the unconventional Point-Pleasant formation is shown where the traditional 𝑇𝑇1 − 𝑇𝑇2 cutoff technique to determine macro-pore hydrocarbon saturation breaks down, which is remedied by measuring 𝑇𝑇1 − 𝑇𝑇2 maps on mixed hydrocarbon-water saturated cores. The results show that instead of using cutoffs, the log-mean 𝑇𝑇1 , log-mean 𝑇𝑇2 , and log-mean 𝑇𝑇1/𝑇𝑇2 ratio correlate strongly against macro-pore hydrocarbon saturation of the mixed-saturated cores. In particular, for the Point-Pleasant organic-shale formation, the log-mean 𝑇𝑇1 is much more sensitive to macro-pore hydrocarbon saturation than the log-mean 𝑇𝑇2 or log-mean 𝑇𝑇1/𝑇𝑇2 ratio. The calibration of macro-pore hydrocarbon saturation from log-mean 𝑇𝑇1 is found to be different above and below a para-sequence boundary (nonconformity) in the organic-shale interval, the results of which can be used to interpret NMR logs. Details of the time-efficient technique used to obtain the mixed hydrocarbon-water saturated cores are shown.


2013 ◽  
Vol 1 (1) ◽  
pp. T113-T123 ◽  
Author(s):  
Zoya Heidari ◽  
Carlos Torres-Verdín

Reliable estimates of petrophysical and compositional properties of organic shale are critical for detecting perforation zones or candidates for hydro-fracturing jobs. Current methods for in situ formation evaluation of organic shale largely rely on qualitative responses and empirical formulas. Even core measurements can be inconsistent and inaccurate when evaluating clay minerals and other grain constituents. We implement a recently introduced inversion-based method for organic-shale evaluation from conventional well logs. The objective is to estimate total porosity, total organic carbon (TOC), and volumetric/weight concentrations of mineral/fluid constituents. After detecting bed boundaries, the first step of the method is to perform separate inversion of individual well logs to estimate bed physical properties such as density, neutron migration length, electrical conductivity, photoelectric factor (PEF), and thorium, uranium , and potassium volumetric/weight concentrations. Next, a multilayer petrophysical model specific to organic shale is constructed with an initial guess obtained from conventional well-log interpretation or X-ray diffraction data; bed physical properties are calculated with the initial layer-by-layer values. Final estimates of organic shale petrophysical and compositional properties are obtained by progressively minimizing the difference between calculated and measured bed properties. A unique advantage of this method is the correction of shoulder-bed effects on well logs, which are prevalent in shale-gas plays. Another advantage is the explicit calculation of accurate well-log responses for specific petrophysical, mineral, fluid, and kerogen properties based on chemical formulas and volumetric concentrations of minerals/kerogen and fluid constituents. Examples are described of the successful application of the new organic-shale evaluation method in the Haynesville shale-gas formation. This formation includes complex solid compositions and thin beds where rapid depth variations of mineral/fluid constituents are commonplace. Comparison of estimates for total porosity, total water saturation, and TOC obtained with (a) commercial software for multimineral analysis, (b) our organic-shale evaluation method, and (c) core/X-ray diffraction measurements indicates a significant improvement in estimates of total porosity and water saturation yielded by our interpretation method. The estimated TOC is also in agreement with core laboratory measurements.


Author(s):  
John A. Trotter

Hemoglobin is the specific protein of red blood cells. Those cells in which hemoglobin synthesis is initiated are the earliest cells that can presently be considered to be committed to erythropoiesis. In order to identify such early cells electron microscopically, we have made use of the peroxidatic activity of hemoglobin by reacting the marrow of erythropoietically stimulated guinea pigs with diaminobenzidine (DAB). The reaction product appeared as a diffuse and amorphous electron opacity throughout the cytoplasm of reactive cells. The detection of small density increases of such a diffuse nature required an analytical method more sensitive and reliable than the visual examination of micrographs. A procedure was therefore devised for the evaluation of micrographs (negatives) with a densitometer (Weston Photographic Analyzer).


Author(s):  
P. Echlin ◽  
M. McKoon ◽  
E.S. Taylor ◽  
C.E. Thomas ◽  
K.L. Maloney ◽  
...  

Although sections of frozen salt solutions have been used as standards for x-ray microanalysis, such solutions are less useful when analysed in the bulk form. They are poor thermal and electrical conductors and severe phase separation occurs during the cooling process. Following a suggestion by Whitecross et al we have made up a series of salt solutions containing a small amount of graphite to improve the sample conductivity. In addition, we have incorporated a polymer to ensure the formation of microcrystalline ice and a consequent homogenity of salt dispersion within the frozen matrix. The mixtures have been used to standardize the analytical procedures applied to frozen hydrated bulk specimens based on the peak/background analytical method and to measure the absolute concentration of elements in developing roots.


Planta Medica ◽  
2008 ◽  
Vol 74 (09) ◽  
Author(s):  
K Miyagi ◽  
T Fujise ◽  
N Koga ◽  
K Wada ◽  
M Yano ◽  
...  

Author(s):  
Jianqi Li ◽  
Yu Zhou ◽  
Jianying Li

This paper presented a novel analytical method for calculating magnetic field in the slotted air gap of spoke-type permanent-magnet machines using conformal mapping. Firstly, flux density without slots and complex relative air-gap permeance of slotted air gap are derived from conformal transformation separately. Secondly, they are combined in order to obtain normalized flux density taking account into the slots effect. The finite element (FE) results confirmed the validity of the analytical method for predicting magnetic field and back electromotive force (BEMF) in the slotted air gap of spoke-type permanent-magnet machines. In comparison with FE result, the analytical solution yields higher peak value of cogging torque.


The Synergist ◽  
2000 ◽  
Vol 11 (8) ◽  
pp. 26 ◽  
Author(s):  
Robert P. Streicher ◽  
Christopher M. Reh ◽  
Rosa Key-Schwartz ◽  
Paul C. Schlecht ◽  
Mary Ellen Cassinelli ◽  
...  
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