scholarly journals Preparation And Properties of Electroless Cu/Ni Composite Materials Based On Wood

Author(s):  
Yanfei Pan ◽  
Qiang GUO ◽  
Dingwen YIN ◽  
Mayin DAI ◽  
Xiaofang YU ◽  
...  

Abstract The changes of properties of wood-based Cu-Ni composites were studied via electroless Cu and Ni on wood surface to obtain Cu-Ni multilayer composites with excellent properties. The surface and interface morphology of the composite coatings were investigated via laser confocal microscopy and scanning electron microscope (SEM). The crystal structure was characterized by XRD. The hydrophobic properties of the composite coatings were tested via contact angle meter. The surface conductivity of composites was tested via four-probe. The results showed that the electrical conductivity of wood-based Cu-Ni composites was 2370.76 S/cm. The surface roughness was 9.99 μm and the thickness of uniform coating reached 157 μm via one time electroless Ni deposition and two times electroless Cu deposition. XRD analysis showed that the wood surface was uniformly covered with metal coating. The metal Cu and Ni were closely nested together to form a dense composite layer, and the composite material was light in weight. When the electroless Ni was 55 min, the contact angle could reach 123°, indicating that had best hydrophobicity. The average electromagnetic shielding effectiveness (EMSE) of Cu and Ni wood-based composites can reach 93.8 dB at L band ranging from 0.3×103 to 3.0×103 MHz) with a low thickness (157 μm), verified the multilayer composite materials can block over 99.99% of incident EM waves.

2011 ◽  
Vol 183-185 ◽  
pp. 1563-1567 ◽  
Author(s):  
Hai Bing Liu ◽  
Li Juan Wang

In this paper we prepared electroless Ni-plated wood veneers using two Pa activation methods. One is the traditional Pa colloid activation and the other uses Pa2+ions. SEM-EDS results indicated that the coatings were continuous, uniform and compact with a P content of lower than 4 wt.%. XRD analysis showed that the coatings were crystalline, which was related to the low P content. The plated wood veneers exhibit good electro-conductivity with surface resistivity of lower than 0.3 Ω cm-2and higher electromagnetic shielding effectiveness of over 60 dB in frequencies from 10 MHz to 1.5 GHz.


Coatings ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 740
Author(s):  
Yanfei Pan ◽  
Dingwen Yin ◽  
Xiaofang Yu ◽  
Nanyi Hao ◽  
Jintian Huang

The lightweight multilayer-structured electromagnetic interference shielding composite coatings with controllable electromagnetic gradient on wood surface were prepared via a simple multiple electroless copper–nickel (Cu–Ni) approach. The surface morphology, conductivity, hydrophobicity property and electromagnetic shielding effectiveness of the composite coatings were investigated. The surface roughness and conductivity of the composite coatings were enhanced with the increase in the number of depositions. The surface morphology demonstrated that the roughness was decreased with the process of multiple electroless. The coatings were compact and homogeneous as the deposition run was three. Here, the Sa (Sa illustrated Surface Roughness) value of coatings was 4.497 μm. The ideal conductivity of composite coatings can be obtained as the number of depositions was four. Electromagnetic shielding effectiveness reached average 90.69 dB in the frequency range from 300 kHz to 2.0 GHz. This study provides a new pathway for fabricating lightweight multilayer-structured electromagnetic interference shielding with controllable electromagnetic gradient and hydrophobic composite coatings-based wood.


2013 ◽  
Vol 395-396 ◽  
pp. 37-40 ◽  
Author(s):  
Deng Gao Guan ◽  
Yao Sun ◽  
Guan Li Xu ◽  
Chuan Min Sun ◽  
Hua Wei Li ◽  
...  

A new kind of the electromagnetic shielding composite coatings with high performance was prepared using the Ni-Cu-coated glass fibers and nickel powders as fillers and using epoxy resin as binder. The effects of the fibers on the conductivity and electromagnetic shielding effectiveness of the coatings were studied. The study results show as follows: 1) when the optimum ratio of the fillers to epoxy resin is 4:1, the coatings containing 6 wt% the Ni-Cu-coated glass fibers has best conductivity and electromagnetic shielding effectiveness; when the coating layer thickness is 300 μm, the shielding effectiveness of the coatings is up to 43.71-52.31 dB and increased an average of 13.94 dB compared with the nickel powders/ epoxy resin electromagnetic shielding coatings in the frequency range of 0.3-1000 MHz. This offers a new idea to enhance the added value of the glass fibers and the prevention of electromagnetic environmental pollution.


BioResources ◽  
2020 ◽  
Vol 15 (4) ◽  
pp. 7517-7531
Author(s):  
Yanfei Pan ◽  
Dingwen Yin ◽  
Surigala ◽  
Yinan Hao ◽  
Dong Xing ◽  
...  

A wood-based composite exhibiting excellent electromagnetic shielding performance was prepared by electroless Ni plating. The properties of the material were characterized by a series of tests. The results showed that the growth route of Ni particles was first arranged along the inherent grain of the wood to form a banded metal layer. With extension of the duration of electroless plating, the growth of Ni particles gradually extended around and filled the pores between wood fibers, and finally formed flake-shape structure. The metal coatings formed a strip along the inherent grain of the wood surface and then changed into a sheet until it covered the entire wood surface. The coatings resistance was from 12 Ω to 0.5 Ω with the increase in duration of electroless plating. When the duration was 20 min, the composite coating resistance was 0.5 Ω. Here, the contact angle of composite coatings was 98.3° when the plating time was 15 min. When the wood surface was modified via two depositions of Ni, the average electromagnetic shielding value of the composites was over 80 dB in the frequency ranging from 0.3 kHz to 3.0 GHz.


2014 ◽  
Vol 21 (1) ◽  
pp. 129-135 ◽  
Author(s):  
Devrim Soyaslan ◽  
Özer Göktepe ◽  
Selçuk Çömlekçi

AbstractIn this study, it was aimed to investigate the effects of fabric lamination angle and fabric ply number on electromagnetic shielding effectiveness (EMSE) of weft knitted fabric-reinforced polypropylene composites. Knitted fabric-reinforced composites are composed of aramid yarn, polypropylene yarn, and copper wire. Polypropylene is the matrix phase and the aramid yarn and copper wires are the reinforcement phase of the composite materials. It was achieved to form 1.5 to 3 mm thickness composites. The composites have nearly 20–50 dB electromagnetic shielding values. To form the knitted fabrics, 7G semiautomatic flat knitting machine was used. The composites were formed by a laboratory-type hot press. EMSE of composites were tested by using ASTM D 4935 coaxial test fixture in 27–3000 MHz frequency band. Lamination angle and ply number parameters were examined related to EMSE of structures. For this study, three different structures were knitted and named as plain knit, 1×1 rib knit, and half cardigan knit. To determine the effect of lamination angle of composites on electromagnetic shielding performance, the composites were produced in two different lamination angles as 0°/90°/0°/90° and 0°/45°/0°/45°. To determine the effect of fabric ply number of composites on electromagnetic shielding performance, the composites were produced in two and four plies. It was observed that the fabric ply number and lamination angle does not affect the EMSE of composite materials very much. It was determined that weft knitted reinforced composite structures have appropriate and high EMSE values for electromagnetic applications. This knitted fabric-reinforced polypropylene composites are flexible and suitable for other industrial applications as civil engineering, aerospace, etc.


2010 ◽  
Vol 150-151 ◽  
pp. 917-920 ◽  
Author(s):  
Sheng Xi Liao ◽  
Peng Zhang ◽  
Kun Li ◽  
Qing Feng Sun

This paper examined the in situ growth of hydrophobic anatase TiO2 coating on wood surface using a cosolvent-controlled hydrothermal method. EDXA, FTIR and XRD analysis confirmed that the growth of TiO2 coating on wood surface was bonded to hydrocarbon chains. The relative contact angle of before and after treated wood sample was changed from 46.5o to 136.8o with the examination of contact angle analyzer, which induced a change of the untreated wood surface from hydrophilic to hydrophobic. As observed on SEM image, some slippery TiO2 spheres with about 300-600 nm in diameter evenly dispersed on treated wood surface.


2017 ◽  
Vol 739 ◽  
pp. 148-151
Author(s):  
Chih I Hsu ◽  
Kung Hsu Hou ◽  
Ming Der Ger

In this study, hardness and wear resistance of electroless Ni–P and Ni–P/Al2O3 composite coating have been investigated. These composite coatings are applied on iron substrate by electroless deposition process and then they were heat treated at 400°C for 1h. Surface and cross-section morphology of composite deposits have been investigated by scanning electron microscopy (SEM) and microstructural changes were evaluated by X-ray diffraction (XRD) analysis. The results showed that the Al2O3 particles co-deposited in Ni–P matrix led to an increase in the hardness and improve wear resistance, especially when the heat treated at 400°C will have the maximum hardness and wear resistance.


Proceedings ◽  
2020 ◽  
Vol 63 (1) ◽  
pp. 23
Author(s):  
Cezar Afilipoaei ◽  
Horatiu Teodorescu-Draghicescu

The aim of this paper is to review and compare the response to the electromagnetic radiation of different structural or non-structural composites on absorption, reflections and re-reflection grades. The area of interest has been reduced to the carbon allotropy and conducting non-magnetic/magnetic fillers (inclusions, metallic powders, granular ferrites) in dielectric hosts characterized by existing mixing rules. The results could be grouped in distinctive ranges, SE ≤ 10 dB corresponding to a poor shielding, 10–30 dB describing an acceptable effectiveness and SE ≥ 30 dB exceeding the acceptable range for industrial and commercial applications of 20 dB.


2017 ◽  
Vol 898 ◽  
pp. 2065-2070 ◽  
Author(s):  
Wei Lin Yao ◽  
Guo Xuan Xiong ◽  
Ying Yang

The nickel fiber was added into the cement-based composite materials as a shielding medium. Influences of the three different types and amount of dispersants and weight fraction of nickel fiber on the electrical conductivity and electromagnetic shielding effectiveness of the cement matrix composite were discussed. The conductivity of cement based composite materials and the uniformity distribution of shielding medium were characterized by four-point probe meter and scanning electron microscopy, respectively. Electromagnetic interference shielding effectiveness in the frequency range of 1 MHz to 1500 MHz was characterized by coaxial cable method. The results indicated that the improved dispersion of nickel by incorporation of dispersants might yield the enhancement of the electrical properties of nickel fiber-reinforced cement composites. When the dosage of methyl cellulose reaches 0.4 wt.%, the pre-dispersing nickel fiber enhances the electrical conductivity of the cement-based composite materials significantly. With the increase of fiber volume fraction, the shielding effectiveness and trend of frequency change of the corresponding fiber-reinforced concrete were enhanced. When the content of nickel fiber powder was 9.0 vol.%, the conductivity was 2.65×10-3 s·cm-1, and the average shielding effectiveness of the specimen in 1MHz-1500 MHz was about 21.78 dB, with the maximum shielding effectiveness of 24.48 dB and the minimum shielding effectiveness 19.85 dB.


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