Halogens in amphibole and mica from mantle xenoliths: Implications for the halogen distribution and halogen budget of the metasomatized continental lithosphere

2020 ◽  
Vol 105 (6) ◽  
pp. 781-794 ◽  
Author(s):  
Johannes G. Hecker ◽  
Michael A.W. Marks ◽  
Thomas Wenzel ◽  
Gregor Markl
Keyword(s):  
Partial Melting ◽  
Volcanic Rocks ◽  
Mantle Xenoliths ◽  
Continental Lithosphere ◽  
Initial Composition ◽  
Halogen Content ◽  
The Impact

Abstract This study reports halogen contents (F and Cl) of amphibole and phlogopite derived from mantle xenoliths and one peridotite massif, for amphibole and phlogopite megacrysts and ultramafic magmatic cumulates (hornblendites) found in alkaline volcanic rocks from 12 localities in Europe and Africa. Amphibole and phlogopite contain more F than Cl with F/Cl ratios reaching about 160 in phlogopites and 50 in amphiboles. Phlogopites are higher in F (median of 3400 μg/g) than amphibole (median of 1000 μg/g), while median Cl contents are higher in amphibole (290 μg/g) compared to phlogopite (180 μg/g). The Cl contents and the F/Cl ratios in amphibole and phlogopite from mantle xenoliths exhibit large differences between samples of the same region, recording very large variations of halogen contents in the continental lithosphere. We suggest that the halogen content in such samples largely depends on the initial composition of percolating melts and fluids in the continental lithosphere. During reaction of these agents with peridotitic wall-rocks, Cl is preferentially retained in the fluid as it is much more incompatible compared to water and F. This desiccation effect continuously increases salinity (Cl content) and decreases the F/Cl ratio in the agent with time, causing variable Cl contents and F/Cl ratios in amphibole and phlogopite at a specific locality. Subsequent partial melting processes may then sequester and re-distribute, especially Cl among amphibole, phlogopite and melts/fluids as a result of its strong incompatibility, whereas F is much less affected as it behaves slightly compatible. The impact of even small amounts of amphibole and mica on the total halogen budget in the continental lithosphere is significant and both minerals can effectively contribute to the high halogen contents typical of alkaline melts.

Experimental study on a basanite from the McMurdo Volcanic Group, Antarctica: inference on its mantle source

2000 ◽  
Vol 12 (1) ◽  
pp. 105-116 ◽  
Author(s):  
Andrea Orlando ◽  
Sandro Conticelli ◽  
Pietro Armienti ◽  
Daniele Borrini
Keyword(s):  
Experimental Study ◽  
Partial Melting ◽  
Mantle Source ◽  
Volcanic Rocks ◽  
Liquidus Curve ◽  
Mantle Xenoliths ◽  
Primary Magma ◽  
Geochemical Evidence ◽  
Volcanic Group ◽  
Phase Relationships

Experiments to reconstruct the liquidus curve and establish the phase relationships of a basanite (Mg# = 72) from the McMurdo Volcanic Group, (thought to represent a nearly primary magma) used 1.0– 3.0 GPa and 1175–1550°C. The results suggest that this basanite could be generated by partial melting either of a spinel Iherzolite (at P = 1.5–2.0 GPa and T = 1390–1490°C) or of a garnet pyroxenite (at P > 3.0 GPa and T > 1550°C) source. Several lines of petrological and geochemical evidence support the latter hypothesis. Moreover, experimental results indicate the presence of mica in the source if it is assumed that the magma lost some water during its ascent to the surface. This is supported by the presence of mica and amphibole-bearing mantle xenoliths hosted in the most primitive volcanic rocks of the McMurdo Volcanic Group. These results and observations suggest that the source of magmas underwent metasomatism prior to partial melting.

Petrology of ultramafic xenoliths from Rayfield River, south-central British Columbia

1987 ◽  
Vol 24 (8) ◽  
pp. 1679-1687 ◽  
Author(s):  
Dante Canil ◽  
Mark Brearley ◽  
Christopher M. Scarfe
Keyword(s):  
British Columbia ◽  
Phase Equilibrium ◽  
Partial Melting ◽  
Upper Mantle ◽  
Mantle Xenoliths ◽  
Spinel Lherzolite ◽  
Equilibrium Constraints ◽  
Host Magma ◽  
South Central ◽  
Ultramafic Xenoliths

One hundred mantle xenoliths were collected from a hawaiite flow of Miocene–Pliocene age near Rayfield River, south-central British Columbia. The massive host hawaiite contains subrounded xenoliths that range in size from 1 to 10 cm and show protogranular textures. Both Cr-diopside-bearing and Al-augite-bearing xenoliths are represented. The Cr-diopside-bearing xenolith suite consists of spinel lherzolite (64%), dunite (12%), websterite (12%), harzburgite (9%), and olivine websterite (3%). Banding and veining on a centimetre scale are present in four xenoliths. Partial melting at the grain boundaries of clinopyroxene is common and may be due to natural partial melting in the upper mantle, heating by the host magma during transport, or decompression during ascent.Microprobe analyses of the constituent minerals show that most of the xenoliths are well equilibrated. Olivine is Fo89 to Fo92, orthopyroxene is En90, and Cr diopside is Wo47En48Fs5. More Fe-rich pyroxene compositions are present in some of the websterite xenoliths. The Mg/(Mg + Fe2+) and Cr/(Cr + Al + Fe3+) ratios in spinel are uniform in individual xenoliths, but they vary from xenolith to xenolith. Equilibration temperatures for the xenoliths are 860–980 °C using the Wells geothermometer. The depth of equilibration estimated for the xenoliths using geophysical and phase equilibrium constraints is 30–40 km.

Subduction-related magmatic imprint of most Philippine ophiolites: implications on the early geodynamic evolution of the Philippine archipelago

2004 ◽  
Vol 175 (5) ◽  
pp. 443-460 ◽  
Author(s):  
Rodolfo A. Tamayo* ◽  
René C. Maury* ◽  
Graciano P. Yumul ◽  
Mireille Polvé ◽  
Joseph Cotten ◽  
...  
Keyword(s):  
Partial Melting ◽  
Subduction Zone ◽  
Volcanic Rocks ◽  
The Philippines ◽  
Island Arc ◽  
Island Arcs ◽  
Geodynamic Evolution ◽  
Wide Range ◽  
Opening And Closing ◽  
Back Arc

Abstract The basement complexes of the Philippine archipelago include at least 20 ophiolites and ophiolitic complexes. These complexes are characterised by volcanic sequences displaying geochemical compositions similar to those observed in MORB, transitional MORB-island arc tholeiites and arc volcanic rocks originating from modern Pacific-type oceans, back-arc basins and island arcs. Ocean island basalt-like rocks are rarely encountered in the volcanic sequences. The gabbros from the ophiolites contain clinopyroxenes and plagioclases showing a wide range of XMg and An values, respectively. Some of these gabbros exhibit mineral chemistries suggesting their derivation from basaltic liquids formed from mantle sources that underwent either high degrees of partial melting or several partial melting episodes. Moreover, some of the gabbros display a crystallization sequence where orthopyroxene and clinopyroxene appeared before plagioclase. The major element compositions of coexisting orthopyroxenes and olivines from the mantle peridotites are consistent with low to high degrees of partial melting. Accessory spinels in these peridotites display a wide range of XCr values as well with some of them above the empirical upper limit of 0.6 often observed in most modern mid-oceanic ridge (MOR) mantle rocks. Co-existing olivines and spinels from the peridotites also exhibit compositions suggesting that they lastly equilibrated under oxidizing mantle conditions. The juxtaposition of volcanic rocks showing affinities with modern MOR and island arc environments suggests that most of the volcanic sequences in Philippine ophiolites formed in subduction-related geodynamic settings. Similarly, their associated gabbros and peridotites display mineralogical characteristics and mineral chemistries consistent with their derivation from modern supra-subduction zone-like environments. Alternatively, these rocks could have, in part, evolved in a supra-subduction zone even though they originated from a MOR-like setting. A simplified scenario regarding the early geodynamic evolution of the Philippines is proposed on the basis of the geochemical signatures of the ophiolites, their ages of formation and the ages and origins of the oceanic basins actually bounding the archipelago, including basins presumed to be now totally consumed. This scenario envisages the early development of the archipelago to be largely dominated by the opening and closing of oceanic basins. Fragments of these basins provided the substratum on top of which the Cretaceous to Recent volcanic arcs of the Philippines were emplaced.

Ultramafic mantle xenoliths in the Late Cenozoic Volcanic rocks of the Antarctic Peninsula and Jones Mountains, West Antarctica

2021 ◽  
pp. M56-2019-44
Author(s):  
Philip T. Leat ◽  
Aidan J. Ross ◽  
Sally A. Gibson
Keyword(s):  
Antarctic Peninsula ◽  
Upper Mantle ◽  
Lithospheric Mantle ◽  
Volcanic Rocks ◽  
Oceanic Lithosphere ◽  
Incompatible Trace Element ◽  
Mantle Xenoliths ◽  
South Shetland Islands ◽  
West Antarctica ◽  
Gondwana Margin

AbstractAbundant mantle-derived ultramafic xenoliths occur in Cenozoic (7.7-1.5 Ma) mafic alkaline volcanic rocks along the former active margin of West Antarctica, that extends from the northern Antarctic Peninsula to Jones Mountains. The xenoliths are restricted to post-subduction volcanic rocks that were emplaced in fore-arc or back-arc positions relative to the Mesozoic-Cenozoic Antarctic Peninsula volcanic arc. The xenoliths are spinel-bearing, include harzburgites, lherzolites, wehrlites and pyroxenites, and provide the only direct evidence of the composition of the lithospheric mantle underlying most of the margin. The harzburgites may be residues of melt extraction from the upper mantle (in a mid-ocean ridge type setting), that accreted to form oceanic lithosphere, which was then subsequently tectonically emplaced along the active Gondwana margin. An exposed highly-depleted dunite-serpentinite upper mantle complex on Gibbs Island, South Shetland Islands, supports this interpretation. In contrast, pyroxenites, wehrlites and lherzolites reflect percolation of mafic alkaline melts through the lithospheric mantle. Volatile and incompatible trace element compositions imply that these interacting melts were related to the post-subduction magmatism which hosts the xenoliths. The scattered distribution of such magmatism and the history of accretion suggest that the dominant composition of sub-Antarctic Peninsula lithospheric mantle is likely to be harzburgitic.

Petrogenesis of the Upper Cretaceous volcanism in the Kefken region, Western Pontides, NW Turkey

2021 ◽  
Author(s):  
Turgut Duzman ◽  
Ezgi Sağlam ◽  
Aral I. Okay
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Partial Melting ◽  
Upper Cretaceous ◽  
Volcanic Rocks ◽  
Early Eocene ◽  
Heavy Rare Earth ◽  
Heavy Rare Earth Elements ◽  
Cretaceous Volcanism ◽  
Oceanic Slab

<p>The Upper Cretaceous volcanic and volcaniclastic rocks crop out along the Black Sea coastline in Turkey. They are part of a magmatic arc that formed as a result of northward subduction of the Tethys ocean beneath the southern margin of Laurasia. The lower part of the Upper Cretaceous volcanism in the Kefken region, 100 km northeast of Istanbul, is represented by basaltic andesites, andesites, agglomerates and tuffs, which have yielded Late Cretaceous (Campanian, ca. 83 Ma) U-Pb zircon ages. The volcanic and volcanoclastic rocks are stratigraphically overlain by shallow to deep marine limestones, which range in age from Late Campanian to Early Eocene.  Geochemically, basaltic andesites and andesites display negative anomalies in Nb, Ta and Ti, enrichment in large ion lithophile elements (LILE) relative to high field strength elements (HFSE). Light rare earth elements (LREE) show slightly enrichment relative to heavy rare earth elements (La<sub>cn</sub>/Yb<sub>cn</sub> =2.51-3.63) and there are slight negative Eu anomalies (Eu/Eu* = 0.71-0.95) in basaltic andesite and andesite samples. The geochemical data indicate that Campanian volcanic rocks were derived from the partial melting of the mantle wedge induced by hydrous fluids released by dehydration of the subducted oceanic slab.</p><p>There is also a horizon of volcanic rocks, about 230 m thick, within the Late Campanian-Early Eocene limestone sequence.  This volcanic horizon, which consists of pillow basalts, porphyritic basalts,  andesites and dacites, is of Maastrichtian age based on paleontological data from the intra-pillow sediments and U-Pb zircon ages from the andesites and dacites (72-68 Ma).  The Maastrichtian andesites and dacites are geochemically distinct from the Campanian volcanic rocks. They show distinct adakite-like geochemical signatures with high ratios of Sr/Y (>85.5), high La<sub>cn</sub>/Yb<sub>cn </sub>(16.4-23.7) ratios, low content of Y (7.4-8.6 ppm) and low content of heavy rare-earth elements (HREE). The adakitic rocks most probably formed as a result of partial melting of the subducting oceanic slab under garnet and amphibole stable conditions.</p><p>The Upper Cretaceous arc sequence in the Kefken region shows a change from typical subduction-related magmas to adakitic ones, accompanied by decrease in the volcanism.</p><p> </p><p> </p>

scholarly journals Redox state of southern Tibetan upper mantle and ultrapotassic magmas

Geology ◽  
2020 ◽  
Vol 48 (7) ◽  
pp. 733-736 ◽  
Author(s):  
Weikai Li ◽  
Zhiming Yang ◽  
Massimo Chiaradia ◽  
Yong Lai ◽  
Chao Yu ◽  
...  
Keyword(s):  
Upper Mantle ◽  
Lithospheric Mantle ◽  
Redox State ◽  
Volcanic Rocks ◽  
Mantle Xenoliths ◽  
Continental Plate ◽  
Cratonic Mantle ◽  
Tectonic Settings ◽  
Mantle Condition ◽  
Typical Range

Abstract The redox state of Earth’s upper mantle in several tectonic settings, such as cratonic mantle, oceanic mantle, and mantle wedges beneath magmatic arcs, has been well documented. In contrast, oxygen fugacity () data of upper mantle under orogens worldwide are rare, and the mechanism responsible for the mantle condition under orogens is not well constrained. In this study, we investigated the of mantle xenoliths derived from the southern Tibetan lithospheric mantle beneath the Himalayan orogen, and that of postcollisional ultrapotassic volcanic rocks hosting the xenoliths. The of mantle xenoliths ranges from ΔFMQ = +0.5 to +1.2 (where ΔFMQ is the deviation of log from the fayalite-magnetite-quartz buffer), indicating that the southern Tibetan lithospheric mantle is more oxidized than cratonic and oceanic mantle, and it falls within the typical range of mantle wedge values. Mineralogical evidence suggests that water-rich fluids and sediment melts liberated from both the subducting Neo-Tethyan oceanic slab and perhaps the Indian continental plate could have oxidized the southern Tibetan lithospheric mantle. The conditions of ultrapotassic magmas show a shift toward more oxidized conditions during ascent (from ΔFMQ = +0.8 to +3.0). Crustal evolution processes (e.g., fractionation) could influence magmatic , and thus the redox state of mantle-derived magma may not simply represent its mantle source.

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