Sulfur solubility in the Earth magma ocean – testing the hypothesis of the “Hadean matte”

2021 ◽  
2019 ◽  
Vol 520 ◽  
pp. 241-249 ◽  
Author(s):  
Hideharu Kuwahara ◽  
Takanori Kagoshima ◽  
Ryoichi Nakada ◽  
Nobuhiro Ogawa ◽  
Asuka Yamaguchi ◽  
...  
Keyword(s):  

Author(s):  
Sonia M. Tikoo ◽  
Linda T. Elkins-Tanton

The Earth is likely to have acquired most of its water during accretion. Internal heat of planetesimals by short-lived radioisotopes would have caused some water loss, but impacts into planetesimals were insufficiently energetic to produce further drying. Water is thought to be critical for the development of plate tectonics, because it lowers viscosities in the asthenosphere, enabling subduction. The following issue persists: if water is necessary for plate tectonics, but subduction itself hydrates the upper mantle, how is the upper mantle initially hydrated? The giant impacts of late accretion created magma lakes and oceans, which degassed during solidification to produce a heavy atmosphere. However, some water would have remained in the mantle, trapped within crystallographic defects in nominally anhydrous minerals. In this paper, we present models demonstrating that processes associated with magma ocean solidification and overturn may segregate sufficient quantities of water within the upper mantle to induce partial melting and produce a damp asthenosphere, thereby facilitating plate tectonics and, in turn, the habitability of Earth-like extrasolar planets. This article is part of the themed issue ‘The origin, history and role of water in the evolution of the inner Solar System’.


Author(s):  
James M. D. Day ◽  
Frederic Moynier

The Moon is depleted in volatile elements relative to the Earth and Mars. Low abundances of volatile elements, fractionated stable isotope ratios of S, Cl, K and Zn, high μ ( 238 U/ 204 Pb) and long-term Rb/Sr depletion are distinguishing features of the Moon, relative to the Earth. These geochemical characteristics indicate both inheritance of volatile-depleted materials that formed the Moon and planets and subsequent evaporative loss of volatile elements that occurred during lunar formation and differentiation. Models of volatile loss through localized eruptive degassing are not consistent with the available S, Cl, Zn and K isotopes and abundance data for the Moon. The most probable cause of volatile depletion is global-scale evaporation resulting from a giant impact or a magma ocean phase where inefficient volatile loss during magmatic convection led to the present distribution of volatile elements within mantle and crustal reservoirs. Problems exist for models of planetary volatile depletion following giant impact. Most critically, in this model, the volatile loss requires preferential delivery and retention of late-accreted volatiles to the Earth compared with the Moon. Different proportions of late-accreted mass are computed to explain present-day distributions of volatile and moderately volatile elements (e.g. Pb, Zn; 5 to >10%) relative to highly siderophile elements (approx. 0.5%) for the Earth. Models of early magma ocean phases may be more effective in explaining the volatile loss. Basaltic materials (e.g. eucrites and angrites) from highly differentiated airless asteroids are volatile-depleted, like the Moon, whereas the Earth and Mars have proportionally greater volatile contents. Parent-body size and the existence of early atmospheres are therefore likely to represent fundamental controls on planetary volatile retention or loss.


Author(s):  
Stein B Jacobsen ◽  
Michael C Ranen ◽  
Michael I Petaev ◽  
John L Remo ◽  
Richard J O'Connell ◽  
...  

Measurable variations in 182 W/ 183 W, 142 Nd/ 144 Nd, 129 Xe/ 130 Xe and 136 Xe Pu / 130 Xe in the Earth and meteorites provide a record of accretion and formation of the core, early crust and atmosphere. These variations are due to the decay of the now extinct nuclides 182 Hf, 146 Sm, 129 I and 244 Pu. The l82 Hf– 182 W system is the best accretion and core-formation chronometer, which yields a mean time of Earth's formation of 10 Myr, and a total time scale of 30 Myr. New laser shock data at conditions comparable with those in the Earth's deep mantle subsequent to the giant Moon-forming impact suggest that metal–silicate equilibration was rapid enough for the Hf–W chronometer to reliably record this time scale. The coupled 146 Sm– 147 Sm chronometer is the best system for determining the initial silicate differentiation (magma ocean crystallization and proto-crust formation), which took place at ca 4.47 Ga or perhaps even earlier. The presence of a large 129 Xe excess in the deep Earth is consistent with a very early atmosphere formation (as early as 30 Myr); however, the interpretation is complicated by the fact that most of the atmospheric Xe may be from a volatile-rich late veneer.


2021 ◽  
Author(s):  
Stephane Labrosse ◽  
Adrien Morison ◽  
Daniela Bolrão ◽  
Antoine Rozel ◽  
Maxim Ballmer ◽  
...  

<p>The early evolution of the Earth was likely affected by a large scale magma ocean, in particular in the aftermath of the giant impact that formed the Moon. The exact structure and dynamics of the Earth following that event is unknown but several possible scenarios feature the existence of a basal magma ocean (BMO), whose last remaining drops may explain the current seismically detected ultra low velocity zones. The presence of a BMO covering the core carries many implications for the dynamics and evolution of the overlying solid mantle. The phase equilibrium between the magma and the solid mantle allows matter to flow through the boundary by melting and freezing. In practice, convective stresses in the solid create a topography of the interface which displaces the equilibrium. Heat and solute transfer in the liquid acts to erase this topography and, if this process is faster than that the producing topography, the boundary appears effectively permeable to flow. This leads to convective motions much faster than in usual mantle convection. We developed a mantle convection model coupled to a model for the thermal and compositional evolution of the BMO and the core that takes into account the phase equilibrium at the bottom of the solid mantle. It also includes the fractional crystallisation at the interface and net freezing of the magma ocean. Early in the history, convection in the mantle is very fast and dominated by down-welling currents. As fractional crystallisation proceeds, the magma ocean gets enriched in FeO which makes the cumulate to also get richer. Eventually, it becomes too dense to get entrained by mantle convection and starts to pile up at the bottom of the mantle, which inhibits direct mass flow through the phase change boundary. This allows a thermal boundary layer and hot plumes to develop.</p><p>This model therefore allows to explain the present existence of both residual partial melt and large scale compositional variations in the lower mantle, as evidenced by seismic velocity anomalies. It also predicts a regime change between early mantle convection dominated by down-welling flow to the onset of hot plumes in the more recent past.</p>


2020 ◽  
Author(s):  
Paolo Sossi ◽  
Antony Burnham ◽  
James Badro ◽  
Antonio Lanzirotti ◽  
Matt Newville ◽  
...  

<p>Outgassing of an early magma ocean on Earth plays a dominant role in determining the composition of its secondary atmosphere, and hence bears on the potential for the emergence of life. The stability of gaseous species in such an atmosphere reflects the redox state of the magma ocean. However, the relationship between oxygen fugacity (fO<sub>2</sub>) and the oxidation state of the most abundant polyvalent element, Fe, in likely magma ocean compositions is poorly constrained. Here we determine Fe<sup>2+</sup>/Fe<sup>3+</sup> ratios as a function of fO<sub>2</sub> in peridotite liquids, experimentally synthesised by aerodynamic laser levitation at 1 bar and 2173 K. We show that a magma ocean with Fe<sup>3+</sup>/∑Fe akin to that of contemporary upper mantle peridotite (0.037) would have had fO<sub>2</sub> 0.5 log units higher than the Fe-“FeO” equilibrium. At this relative fO<sub>2</sub>, a neutral CO<sub>2</sub>-H<sub>2</sub>O-dominated atmosphere of ~ 150 bar would have developed on the early Earth, taking into account the solubilities of the major volatiles, H, C, N and O in the magma ocean. Upon cooling, the Earth’s prebiotic atmosphere was likely comprised of CO<sub>2</sub>-N<sub>2</sub>, in proportions and at pressures akin to that on presently found on Venus.</p>


2016 ◽  
Vol 53 (11) ◽  
pp. 1103-1120 ◽  
Author(s):  
W.G. Ernst ◽  
Norman H. Sleep ◽  
Tatsuki Tsujimori

Intense devolatilization and chemical-density differentiation attended accretion of planetesimals on the primordial Earth. These processes gradually abated after cooling and solidification of an early magma ocean. By 4.3 or 4.2 Ga, water oceans were present, so surface temperatures had fallen far below low-pressure solidi of dry peridotite, basalt, and granite, ∼1300, ∼1120, and ∼950 °C, respectively. At less than half their T solidi, rocky materials existed as thin lithospheric slabs in the near-surface Hadean Earth. Stagnant-lid convection may have occurred initially but was at least episodically overwhelmed by subduction because effective, massive heat transfer necessitated vigorous mantle overturn in the early, hot planet. Bottom-up mantle convection, including voluminous plume ascent, efficiently rid the Earth of deep-seated heat. It declined over time as cooling and top-down lithospheric sinking increased. Thickening and both lateral extensional + contractional deformation typified the post-Hadean lithosphere. Stages of geologic evolution included (i) 4.5–4.4 Ga, magma ocean overturn involved ephemeral, surficial rocky platelets; (ii) 4.4–2.7 Ga, formation of oceanic and small continental plates were obliterated by return mantle flow prior to ∼4.0 Ga; continental material gradually accumulated as largely sub-sea, sialic crust-capped lithospheric collages; (iii) 2.7–1.0 Ga, progressive suturing of old shields + younger orogenic belts led to cratonal plates typified by emerging continental freeboard, increasing sedimentary differentiation, and episodic glaciation during transpolar drift; onset of temporally limited stagnant-lid mantle convection occurred beneath enlarging supercontinents; (iv) 1.0 Ga–present, laminar-flowing asthenospheric cells are now capped by giant, stately moving plates. Near-restriction of komatiitic lavas to the Archean, and appearance of multicycle sediments, ophiolite complexes ± alkaline igneous rocks, and high-pressure–ultrahigh-pressure (HP–UHP) metamorphic belts in progressively younger Proterozoic and Phanerozoic orogens reflect increasing negative buoyancy of cool oceanic lithosphere, but decreasing subductability of enlarging, more buoyant continental plates. Attending supercontinental assembly, density instabilities of thickening oceanic plates began to control overturn of suboceanic mantle as cold, top-down convection. Over time, the scales and dynamics of hot asthenospheric upwelling versus lithospheric foundering + mantle return flow (bottom-up plume-driven ascent versus top-down plate subduction) evolved gradually, reflecting planetary cooling. These evolving plate-tectonic processes have accompanied the Earth’s thermal history since ∼4.4 Ga.


2020 ◽  
Vol 221 (2) ◽  
pp. 1165-1181
Author(s):  
J Monteux ◽  
D Andrault ◽  
M Guitreau ◽  
H Samuel ◽  
S Demouchy

SUMMARY In its early evolution, the Earth mantle likely experienced several episodes of complete melting enhanced by giant impact heating, short-lived radionuclides heating and viscous dissipation during the metal/silicate separation. After a first stage of rapid and significant crystallization (Magma Ocean stage), the mantle cooling is slowed down due to the rheological transition, which occurs at a critical melt fraction of 40–50%. This transition first occurs in the lowermost mantle, before the mushy zone migrates toward the Earth's surface with further mantle cooling. Thick thermal boundary layers form above and below this reservoir. We have developed numerical models to monitor the thermal evolution of a cooling and crystallizing deep mushy mantle. For this purpose, we use a 1-D approach in spherical geometry accounting for turbulent convective heat transfer and integrating recent and solid experimental constraints from mineral physics. Our results show that the last stages of the mushy mantle solidification occur in two separate mantle layers. The lifetime and depth of each layer are strongly dependent on the considered viscosity model and in particular on the viscosity contrast between the solid upper and lower mantle. In any case, the full solidification should occur at the Hadean–Eoarchean boundary 500–800 Myr after Earth's formation. The persistence of molten reservoirs during the Hadean may favor the absence of early reliefs at that time and maintain isolation of the early crust from the underlying mantle dynamics.


Author(s):  
Bernard Bourdon ◽  
Mathieu Touboul ◽  
Guillaume Caro ◽  
Thorsten Kleine

We examine the implications of new 182 W and 142 Nd data for Mars and the Moon for the early evolution of the Earth. The similarity of 182 W in the terrestrial and lunar mantles and their apparently differing Hf/W ratios indicate that the Moon-forming giant impact most probably took place more than 60 Ma after the formation of calcium-aluminium-rich inclusions (4.568 Gyr). This is not inconsistent with the apparent U–Pb age of the Earth. The new 142 Nd data for Martian meteorites show that Mars probably has a super-chondritic Sm/Nd that could coincide with that of the Earth and the Moon. If this is interpreted by an early mantle differentiation event, this requires a buried enriched reservoir for the three objects. This is highly unlikely. For the Earth, we show, based on new mass-balance calculations for Nd isotopes, that the presence of a hidden reservoir is difficult to reconcile with the combined 142 Nd– 143 Nd systematics of the Earth's mantle. We argue that a likely possibility is that the missing component was lost during or prior to accretion. Furthermore, the 142 Nd data for the Moon that were used to argue for the solidification of the magma ocean at ca 200 Myr are reinterpreted. Cumulate overturn, magma mixing and melting following lunar magma ocean crystallization at 50–100 Myr could have yielded the 200 Myr model age.


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