scholarly journals The periodic system of chemical elements solid model in the geological aspect

Author(s):  
Mikhail M. Labushev ◽  
◽  
Timofey M. Labushev ◽  

The topicality of the research comes from the need to obtain new knowledge about the manifestation of the periodic law in nature. Research aim is to associate the periodic system of chemical elements with the chemical composition and structure of natural objects. The research method suggests the creation of a solid model of the periodic system of chemical elements along with its comparison with ore formation objects as well as the manifestation of chemical elements isomorphism and some natural processes geochemistry. Research results. The solid version of the periodic table of the first 95 chemical elements together with a conventional zero element is proposed. Each volume cell characterizes a chemical element with an elementary crystal lattice of simple substance. Similar models can be composed of minerals and rocks associating with material substance of the earth's crust. 16 vertical groups in the model are arranged in a snake-like pattern. The model of the earth's crust with the “cubes” of chemical elements, minerals and mineral associations is proposed. The elements of adjacent spatial groups are naturally concentrated in combination, showing isomorphism while minerals enter the crystal lattice. The relative position of adjacent “cubes” follows the rule of translation in mutually perpendicular directions. The chemical elements of the first group can correspond spatially to volcanoes as well as mud volcanoes. The place of the zero chemical element is considered to be occupied by the elements of adjacent spatial groups. It is assumed that the faces of the “cube” of chemical elements are permeable areas through which chemical elements can be transferred. Summary. The confirmation of the model follows while considering ore formations, isomorphism of chemical elements in minerals and geochemistry of volcanic processes. 46 "Izvestiya vysshikh uchebnykh zavedenii. Gornyi zhurnal". No. 1. 2020 ISSN 0536-1028 Key words: chemical elements; solid model of periodic system; ore formations; isomorphism in crystals; geochemistry of volcanic processes.

Author(s):  
Guillermo Restrepo

The Periodic Table, Despite its near 150 years, is still a vital scientific construct. Two instances of this vitality are the recent formulation of a periodic table of protein complexes (Ahnert et al. 2015) and the announcement of four new chemical elements (Van Noorden 2016). “Interestingly, there is no formal definition of ‘Periodic Table’,” claims Karol (2017) in his chapter of the current volume. And even worse, the related concepts that come into play when referring to the periodic table (such as periodic law, chemical element, periodic system, and some others) overlap, leading to confusion. In this chapter we explore the meaning of the periodic table and of some of its related terms. In so doing we highlight a few common mistakes that arise from confusion of those terms and from misinterpretation of others. By exploring the periodic table, we analyze its mathematics and discuss a recent comment by Hoffmann (2015): “No one in my experience tries to prove [the periodic table] wrong, they just want to find some underlying reason why it is right.” We claim that if the periodic table were “wrong,” its structure would be variable; however the test of the time, including similarity studies, show that it is rather invariable. An approach to the structure of the periodic system we follow in this chapter is through similarity. In so doing we review seven works addressing the similarity of chemical elements accounting for different number of elements and using different properties, either chemical or physical ones. The concept of “chemical element” has raised the interest of several scholars such as Paneth (1962) and is still a matter of discussion given the double meaning it has (see, e.g., Scerri 2007, Earley 2009, Ruthenberg 2009, Ghibaudi et al. 2013, van Brakel 2014, Restrepo & Harré 2015), which is confusing, leading to misconceptions. The two meanings of the concept of chemical element are basic and simple substance. According to Paneth (1962), a basic substance belongs to the transcendental world and it is devoid of qualities, and therefore is not perceptible to our senses.


Author(s):  
Bernadette Bensaude-Vincent

The introduction of the modern concept of chemical element has often been credited to Lavoisier. I will argue that despite the significant impact of the definition of elements as non-decompound bodies in Lavoisier’s “Elements of Chemistry,” this claim is misleading for at least three reasons. First, elements were already defined as residues of analysis prior to Lavoisier. Second, Lavoisier did not totally give up the traditional view of elements as constituents of all bodies. Third, the modern definition of chemical element implies a clear distinction between simple bodies and elements that was later introduced by Dmitri Mendeleev. I will outline the role of this conceptual distinction in Mendeleev’s process of classification of elements and symmetrically emphasize how the periodic system contributed to stabilize his notion of element as an individual defined by its position in the system. Thus the concept of element appears as both a precondition and a product of the construction of the periodic system.


1965 ◽  
Vol S7-VII (1) ◽  
pp. 187-194
Author(s):  
Georges Machairas

Abstract The rocks of the earth's crust and upper mantle belong to three categories. The first includes those rocks that have achieved complete equilibrium. Rocks of the second category represent transitory equilibrium, their formation varying relative to the chemical elements available and the physical and dynamic conditions. Rocks of the third category consist of limestones, shales, and other detrital sediments. Their composition is completely controlled by that of the source rock. The global discontinuities including that at the surface, and the Mohorovicic and Lehmann-Gutenberg discontinuities are briefly discussed in terms of differences in densities of rocks of the various categories.


Animals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1663
Author(s):  
Nemi Malhotra ◽  
Hua-Shu Hsu ◽  
Sung-Tzu Liang ◽  
Marri Jmelou M. Roldan ◽  
Jiann-Shing Lee ◽  
...  

Rare earth elements (REEs) or “technology metals” were coined by the U.S. Department of Energy, a group of seventeen elements found in the Earth’s crust. These chemical elements are vital and irreplaceable to the world of technology owing to their unique physical, chemical, and light-emitting properties, all of which are beneficial in modern healthcare, telecommunication, and defense. Rare earth elements are relatively abundant in Earth’s crust, with critical qualities to the device performance. The reuse and recycling of rare earth elements through different technologies can minimize impacts on the environment; however, there is insufficient data about their biological, bioaccumulation, and health effects. The increasing usage of rare earth elements has raised concern about environmental toxicity, which may further cause harmful effects on human health. The study aims to review the toxicity analysis of these rare earth elements concerning aquatic biota, considering it to be the sensitive indicator of the environment. Based on the limited reports of REE effects, the review highlights the need for more detailed studies on the hormetic effects of REEs. Aquatic biota is a cheap, robust, and efficient platform to study REEs’ toxicity, mobility of REEs, and biomagnification in water bodies. REEs’ diverse effects on aquatic life forms have been observed due to the lack of safety limits and extensive use in the various sectors. In accordance with the available data, we have put in efforts to compile all the relevant research results in this paper related to the topic “toxicity effect of REEs on aquatic life”.


2020 ◽  
pp. 241-256
Author(s):  
Sarah N. Hijmans

In 1931, Paneth identified a dual meaning of the term “chemical element,” translated as “basic substance” and “simple substance.” Since then multiple philosophers of chemistry have also identified ambiguities surrounding this concept, and the IUPAC still holds a double definition today. This paper aims to help resolve this ambiguity through an analysis and reinterpretation of the two meanings of the term “element” proposed by Paneth. It is important to distinguish between elements as substances and elements as constituents, because the elementary substances disappear when elements enter into compounds, whereas the constituent subsists. The notion of simple substance fails to capture the stability of the element as a constituent of matter, and Paneth’s metaphysical idea of basic substance is contradictory with a concept of element that evolved thanks to scientific practice, not independent of it. Since these meanings are mutually exclusive, their combination within one term is problematic; yet, this paper will show that neither of them individually suffice to qualify the element. Therefore, based on a brief analysis of the history of chemistry, I will propose a way of rethinking Paneth’s distinction in order to understand the different aspects of this complex chemical concept. Though there is a certain duality to the notion of element in the sense that it can be characterized both as an abstract constituent and as a chemical substance, the term “element” does not have two distinct meanings; it refers to the element in all forms of chemical combination.


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