scholarly journals Hydrogeochemistry and lead contamination of groundwater in the north part of Esfahan province, Iran

2018 ◽  
Vol 16 (4) ◽  
pp. 622-634 ◽  
Author(s):  
Kaveh Pazand ◽  
Davoud Khosravi ◽  
Mohammad Reza Ghaderi ◽  
Mohammad Reza Rezvanianzadeh

Abstract Geochemical and hydrogeochemical studies were conducted to assess the origin and geochemical mechanisms driving lead enrichment in groundwaters of semi-arid regions in Central Iran. In this study, 149 water samples were analyzed using inductively coupled plasma mass spectrometry (ICP-MS). Concentrations of Pb and As in about 68% and 27% of the samples, respectively, exceeded WHO guidelines. Analyzing the results of ICP-MS of parental rocks and aquifer sediments shows that unweathered volcanic rocks were the primary source for lead mobilizing to groundwaters.

Author(s):  
Bayanova Т.B. ◽  
Drogobuzhskaya S.V. ◽  
Subbotin V.V. ◽  
Serov P.А. ◽  
Steshenko Е.N. ◽  
...  

Baddeleyite is a significant mineral successfully applied in the U-Pb geochronology for the precise dating of mafic rocks from layered intrusions with the platinum group element (PGE) and Cu-Ni mineralization. The Fennoscandian Shield hosts several layered Pt-Pd, Co-Cr-Ni, and Ti-V occurrences in the Northern (Karelian) and Southern (Karelian-Finnish) belts. The aim of this study is to estimate the content and distribution of rare earth elements (REE) in baddeleyite and to calculate temperatures (Т, ̊С) of the U-Pb system closure and baddeleyite crystallization compared to zircon from Cu-Ni and Pt-Pd deposits in the north-eastern Fennoscandian Shield. For the first time, baddeleyite crystals from Cu-Ni (Monchepluton) and Pt-Pd (Monchetundra) reefs of the Monchegorsk ore area have been studied in situ by the laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) to measure the U-Pb age of formation and the REE content.


Minerals ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1032
Author(s):  
Pei Zan ◽  
Shouyu Chen ◽  
Jinduo Chen ◽  
Shengli Li

This study discussed the pertrological classification, geochronology, petrogenesis and tectonic evolution of early Paleozoic granites from the Xingshuping gold deposit in the East Qinling orogenic belt. In order to achieve this target, we carried out an integrated study of zircon U–Pb age, whole-rock major and trace elements, as well as Sr–Nd–Hf isotope compositions for the Xingshuping granites (part of the Wuduoshan pluton) from the Erlangping unit. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U–Pb dating constrains the emplacement age of the Xingshuping granites at 446.2 ± 1.2 Ma. The rocks at Xingshuping can be divided into two types: mainly biotite granite and monzonitic granite. The biotite granites are typical adakitic rocks, while the monzonitic granites show characteristics similar to normal arc volcanic rocks. The geochemical compositions reveal that they were derived from a clay-rich, plagioclase-rich and biotite-rich psammitic lower continental crust source, with contributions of mantle-derived magmas. The distinction is that the biotite granites were primarily derived from partial melting in a syn-collision extension setting, whereas the monzonitic granite went through a fractional crystallization process in an intraplate anorogenic setting.


2021 ◽  
Author(s):  
Johannes Rembe ◽  
Renjie Zhou ◽  
Edward R. Sobel ◽  
Jonas Kley ◽  
Chen Jie ◽  
...  

Abstract. The North Pamir, part of the western syntax of the India-Asia collision zone, preserves remnants of a poorly investigated Paleozoic intra-oceanic subduction zone. To constrain the age of this ancient ocean floor, we analyzed calcite phases in vesicular basalt and basaltic volcanic breccia with U-Pb geochronology using laser-ablation inductively-coupled-plasma mass-spectrometry (LA-ICP-MS). Calcite dating yielded Mississippian ages, mostly overlapping each other within errors. REE + Y data reveal that the basaltic host rock of the calcite and oxidizing seawater are major sources of trace elements during calcite precipitation. U-Pb ages seem to be independent of REE + Y concentrations. Our results demonstrate the potential of calcite dating to constrain the age of ancient ocean floors and provide a test of the hypothesis that a continuous early Paleozoic Kunlun Terrane extended from northern Tibet into the North Pamir.


2011 ◽  
Vol 48 (1) ◽  
pp. 45-61 ◽  
Author(s):  
M. A. Ramos-Arias ◽  
J. D. Keppie

High-grade and high-pressure rocks in Acatlán Complex (southern Mexico) are inferred to have been emplaced either during the convergence and collision between Laurentia and Gondwana or during subduction on the western margin of Pangea. In the Ixcamilpa area, such rocks occur in a synformal nappe and are subdivided into (1) the Neoproterozoic–Ordovician Piaxtla Suite (metapsammite, meta-pelite, and amphibolite) that passes structurally upwards from blueschist through eclogite to amphibolite facies; intruded by (2) Cambro-Ordovician megacrystic granitoids; both of which were thrust westwards over (3) the Carboniferous Zumpango Unit consisting of clastic and meta-volcanic rocks. Laser ablation – inductively coupled plasma – mass spectrometry (LA–ICP–MS) U–Pb zircon geochronology yielded age population peaks at (i) 435–490 Ma, probably derived from Acatlán granitoids; (ii) 500–700 Ma, likely derived from the Yucatan Peninsula and Brasiliano orogens; (iii) 800–900 Ma, with provenance in the Goiás arc of eastern Amazonia; and (iv) 950–1300 Ma, sourced either from Oaxaquia, Amazonia, or Laurentia: the younger ca. 310–360 Ma ages are limited to the Zumpango Unit and likely have a local provenance. The overall similarity of the Piaxtla rocks in the Ixcamilpa area and those in the Piaxtla-Mimilulco median belt suggests that Ixcamilpa nappe roots in the median belt, which is interpreted as an extrusion zone within the Acatlán Complex. Since neither high-pressure belt represents a closed ocean, deposition of the Neoproterozoic–Ordovician rocks is inferred to have taken place on the southern margin of Rheic Ocean adjacent to Oaxaquia–Amazonia, whereas the Carboniferous rocks were deposited on the western margin of Pangea synchronous with extrusion of the high-pressure rocks.


2019 ◽  
Vol 132 (5-6) ◽  
pp. 1031-1045
Author(s):  
Shuang Yan ◽  
Renjie Zhou ◽  
He-Cai Niu ◽  
Yue-xing Feng ◽  
Ai Duc Nguyen ◽  
...  

Abstract Volcanic-hosted iron deposits of the eastern Awulale metallogenetic belt in Central Asia possess a reserve of over 1.2 billion tons of iron ores and constitute one of the most important basements for high-grade iron resources in China. Skarns are widespread in these deposits and closely associated with iron mineralization. The ages of these skarns are unclear, and their genesis remains debated, preventing further investigation into their metallogenic processes. We focused on garnets in nine ore-bearing skarns from three large-scale iron deposits (Chagangnuoer, Dunde, and Beizhan) in the eastern Awulale belt. U-Pb dating was conducted on these garnets using our in-house reference material, the Taochong garnet (TC-13, Pb-Pb isochron age: 126.2 ± 2.3 Ma, initial 207Pb/206Pb ratio: 0.845 ± 0.022). Laser-ablation–multicollector–inductively coupled plasma–mass spectrometry (LA-MC-ICP-MS) was employed in the garnet U-Pb dating, and high-precision U-Pb ages (0.3%–1.6%) were obtained, highlighting the advantages of LA-MC-ICP-MS in dating low-U minerals. The garnet U-Pb ages of the nine skarn samples fall into three groups, i.e., 329.0 ± 5.1–326 ± 3.3 Ma (two samples), 316.3 ± 2.9–311.2 ± 2.4 Ma (six samples), and 295.6 ± 1.0 Ma (one sample), implying three episodes of skarn alteration in the volcanic-hosted iron mineralization system. The first and second episodes of skarns formed as a result of contact metasomatism between coeval volcanic rocks and limestone, and they have economically important iron mineralization. The third was likely caused by a local postcollision granitic intrusion, but its metallogenic potential deserves further assessment.


2019 ◽  
Author(s):  
Ingo Strenge ◽  
Carsten Engelhard

<p>The article demonstrates the importance of using a suitable approach to compensate for dead time relate count losses (a certain measurement artefact) whenever short, but potentially strong transient signals are to be analysed using inductively coupled plasma mass spectrometry (ICP-MS). Findings strongly support the theory that inadequate time resolution, and therefore insufficient compensation for these count losses, is one of the main reasons for size underestimation observed when analysing inorganic nanoparticles using ICP-MS, a topic still controversially discussed.</p>


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