scholarly journals Phosphorus fractions and its summer flux from sediments of deep reservoirs located at a phosphate-rock watershed, Central China

2017 ◽  
Vol 18 (2) ◽  
pp. 688-697 ◽  
Author(s):  
Yufei Bao ◽  
Yuchun Wang ◽  
Mingming Hu ◽  
Qiwen Wang
Keyword(s):  
Phosphate Rock ◽  
River System ◽  
Central China ◽  
Detailed Knowledge ◽  
Pollution Levels ◽  
Internal P Loading ◽  
Oxidation Reduction ◽  
Oxidation Reduction Potential ◽  
P Fraction ◽  
First Time

Abstract Huangbai River, including four enchained reservoirs, is located in a phosphate-rock watershed in Yichang City, Central China. Previous studies showed that pollution levels due to activities of phosphate mining (PM) were extremely high and the water quality of reservoirs was severely affected by sedimentation. Yet, detailed knowledge of the sediment is lacking at that high phosphorus (P) concentration basin. Therefore, the different P fractions and its diffusion fluxes at the water-sediment interface of four deep reservoirs have been investigated for the first time to understand the internal P loading. The results indicated that the concentrations of total P , ranging from 9,631.5 to 581.6 mg kg−1, exhibited an apparent spatial trend from the upstream to the downstream reservoirs, which corresponded with the activities of P mining in this basin. The P-fraction concentrations obtained from the sites were mainly ranked in this order: P associated with calcium (Ca-Pi) > organic P (Po) > P bound to aluminum (Al), ferrum (Fe) and manganese (Mn) oxides and hydroxides (Fe/Al-Pi). The orthophosphate diffusion fluxes ranged from −0.40 ± 0.09 to 0.95 ± 0.14 mg m−2 d−1 which were positively related to P fraction concentrations while negatively related to oxidation–reduction potential and dissolved oxygen values. These results implied the dynamics role of internal P loading. The principle component analysis suggested that PM activities and internal P loading were the most reactive factors in this river system.

scholarly journals Chemical indicators for pollution detection in terrestrial and aquatic ecosystems

2019 ◽  
Vol 43 (1) ◽  
Author(s):  
Alaa Zaghloul ◽  
Mohamed Saber ◽  
Camilia El-Dewany
Keyword(s):  
Oxygen Demand ◽  
Quality Criterion ◽  
Potential Health ◽  
Organic C ◽  
Pollution Levels ◽  
Chemical Indicators ◽  
Oxidation Reduction ◽  
Oxidation Reduction Potential ◽  
Reactive Carbon ◽  
Total Organic C

Abstract Background Pollution is objectionable changes in a given ecosystem trailing to potential health hazards. Assessment of pollution levels is continually recognized by several pollution indicators, biological, chemical, and/or physical. Chemical indicators always validate fair information about the evenness between ecosystem components. Results Chemical indicators include pH, quality criterion index, kinetics, oxidation-reduction potential, reactive carbon, total organic C, total residues, dissolved oxygen (DO), chemical oxygen demand (COD), biological oxygen demand (BOD), phosphate (P), nitrogen (N2), anhydrous ammonia (NH3), nitrate (NO3), and copper (Cu2+).

scholarly journals In situ measurements of oxidation–reduction potential and hydrogen peroxide concentration as tools for revealing LPMO inactivation during enzymatic saccharification of cellulose

2021 ◽  
Vol 14 (1) ◽  
Author(s):  
Adnan Kadić ◽  
Anikó Várnai ◽  
Vincent G. H. Eijsink ◽  
Svein Jarle Horn ◽  
Gunnar Lidén
Keyword(s):  
Reduction Potential ◽  
Enzymatic Saccharification ◽  
The State ◽  
Enzyme Inactivation ◽  
Ex Situ ◽  
Process Economics ◽  
Complete Inactivation ◽  
Oxidation Reduction ◽  
Oxidation Reduction Potential

Abstract Background Biochemical conversion of lignocellulosic biomass to simple sugars at commercial scale is hampered by the high cost of saccharifying enzymes. Lytic polysaccharide monooxygenases (LPMOs) may hold the key to overcome economic barriers. Recent studies have shown that controlled activation of LPMOs by a continuous H2O2 supply can boost saccharification yields, while overdosing H2O2 may lead to enzyme inactivation and reduce overall sugar yields. While following LPMO action by ex situ analysis of LPMO products confirms enzyme inactivation, currently no preventive measures are available to intervene before complete inactivation. Results Here, we carried out enzymatic saccharification of the model cellulose Avicel with an LPMO-containing enzyme preparation (Cellic CTec3) and H2O2 feed at 1 L bioreactor scale and followed the oxidation–reduction potential and H2O2 concentration in situ with corresponding electrode probes. The rate of oxidation of the reductant as well as the estimation of the amount of H2O2 consumed by LPMOs indicate that, in addition to oxidative depolymerization of cellulose, LPMOs consume H2O2 in a futile non-catalytic cycle, and that inactivation of LPMOs happens gradually and starts long before the accumulation of LPMO-generated oxidative products comes to a halt. Conclusion Our results indicate that, in this model system, the collapse of the LPMO-catalyzed reaction may be predicted by the rate of oxidation of the reductant, the accumulation of H2O2 in the reactor or, indirectly, by a clear increase in the oxidation–reduction potential. Being able to monitor the state of the LPMO activity in situ may help maximizing the benefit of LPMO action during saccharification. Overcoming enzyme inactivation could allow improving overall saccharification yields beyond the state of the art while lowering LPMO and, potentially, cellulase loads, both of which would have beneficial consequences on process economics.

scholarly journals The Negative Impact of Varicocele on Basic Semen Parameters, Sperm Nuclear DNA Dispersion and Oxidation-Reduction Potential in Semen

2021 ◽  
Vol 18 (11) ◽  
pp. 5977
Author(s):  
Kamil Gill ◽  
Michal Kups ◽  
Patryk Harasny ◽  
Tomasz Machalowski ◽  
Marta Grabowska ◽  
...  
Keyword(s):  
Reduction Potential ◽  
Nuclear Dna ◽  
Study Groups ◽  
Semen Parameters ◽  
Sperm Dna Fragmentation ◽  
Control Groups ◽  
Infertile Men ◽  
Oxidation Reduction ◽  
Oxidation Reduction Potential ◽  
Sperm Dna

Since varicocele is so common in infertile men, this study intends to analyse the relationships between varicocele and conventional semen characteristics, sperm nuclear DNA dispersion and oxidation-reduction potential (ORP) in semen. Varicocele-positive and varicocele-negative infertile men (study groups) showed significantly lower standard sperm parameters and higher sperm DNA fragmentation (SDF) and ORP in semen than healthy volunteers and subjects with proven fertility (control groups). A lower proportion of low SDF levels (0–15% SDF) and higher incidence of high SDF levels (>30% SDF), as well as a higher prevalence of high ORP values (>1.37 mV/106 sperm/mL), were found in the study groups vs. the control groups. Moreover, infertile men had significantly lower odds ratios (ORs) for low SDF levels and significantly higher ORs for high SDF levels and high ORP. SDF and ORP were negatively correlated with sperm number, morphology, motility and vitality. Furthermore, a significant positive correlation was found between SDF and ORP. The obtained results suggest that disorders of spermatogenesis may occur in varicocele-related infertility. These abnormalities are manifested not only by reduced standard semen parameters but also by decreased sperm DNA integrity and simultaneously increased oxidative stress in semen.

Derivation of Optimum Study Factors for Samples Contaminated with Cd Using Electric/Magnetic Field and ORP

2013 ◽  
Vol 813 ◽  
pp. 519-524
Author(s):  
Sang An Ha ◽  
Jei Pil Wang
Keyword(s):  
Magnetic Field ◽  
Heavy Metals ◽  
Removal Rate ◽  
Underground Water ◽  
Liquid Electrode ◽  
Oxidation Reduction ◽  
Oxidation Reduction Potential ◽  
Removal Of Heavy Metals ◽  
High Removal Rate ◽  
Membrane Treatment

A purpose of the present study is to derive optimum study factors for removal of heavy metals using combined alternating current electric/magnetic field and electric membranes for the area contaminated with heavy metals in soil or underground water. ORP (Oxidation Reduction Potential) analysis was conducted to determine an intensity of tendency for oxidation or reduction of the samples contaminated with heavy metals, and electrical membrane treatment was used with adjustment of concentrations and voltages of liquid electrode (Na2SO4) to derive a high removal rate. Removal constants were analyzed to be 0.0417, 0.119, 0.1594 when the voltages were 5V, 10V, 15V, respectively, and treatment efficiency was shown to increase as the liquid electrode concentration was increased. Keywords: heavy metals, electric/magnetic field, ORP, electrical membrane

scholarly journals The influence of oxidation-reduction state on the kinetic stability of pig kidney general acyl-CoA dehydrogenase and other flavoproteins

1984 ◽  
Vol 224 (2) ◽  
pp. 577-580 ◽  
Author(s):  
M Madden ◽  
S M Lau ◽  
C Thorpe
Keyword(s):  
Reduction Potential ◽  
Binding Protein ◽  
Sodium Dithionite ◽  
Egg White ◽  
Kinetic Stability ◽  
Pig Kidney ◽  
Data Support ◽  
Oxidation Reduction ◽  
Oxidation Reduction Potential ◽  
Electron Transferring Flavoprotein

Pig kidney general acyl-CoA dehydrogenase is markedly stabilized against loss of flavin and activity in 7.3 M-urea or at 60 degrees C upon reduction with sodium dithionite or octanoyl-CoA. Electron transferring flavoprotein is similarly stabilized, whereas egg white riboflavin-binding protein loses flavin more readily on reduction. These and other data support the anticipated correlation between the kinetic stability of the holoproteins and the oxidation-reduction potential of their bound flavins.

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