Population Dynamics of Phenol Degrading Microorganisms in Activated Sludge Process under the Stress of Phenolic Wastewater

1991 ◽  
Vol 23 (4-6) ◽  
pp. 1001-1010 ◽  
Author(s):  
M. Okada ◽  
T. Nakamura ◽  
H. Ito ◽  
A. Murakami

The process to gain and lose phenol degrading activity of activated sludge under different stress of phenol was studied by three types of operations, i.e. continuous flow reactor, aerobic SBR, and anaerobic/aerobic SBR under two types of loads, i.e. elevating and constant loads. The higher activity and tolerance under the higher concentration of phenol was gained in activated sludge of aerobic SBR under the constant high load. The higher phenolic stress, i.e. mixed liquor concentration of phenol, at the beginning of batch cycles seemed to increase the activity. Constant and low phenolic stress in continuous flow reactors and elevating load in SBR, however, could not build up tolerance and the higher degrading activity under the higher concentration of phenol. SBR operations which are able to give appropriate phenolic stress on activated sludge, even under the same daily loading of phenol as continuous flow reactor, would be preferable to build up and maintain the activity and to ensure stable operation of wastewater treatment even under shock loading. The degrading activity of activated sludge may be gained mainly by the increase in the ability of bacteria to degrade and tolerate phenol and not by the increase in population.

2017 ◽  
Vol 13 ◽  
pp. 120-126 ◽  
Author(s):  
Christian H Hornung ◽  
Miguel Á Álvarez-Diéguez ◽  
Thomas M Kohl ◽  
John Tsanaktsidis

This work describes the Diels–Alder reaction of the naturally occurring substituted butadiene, myrcene, with a range of different naturally occurring and synthetic dienophiles. The synthesis of the Diels–Alder adduct from myrcene and acrylic acid, containing surfactant properties, was scaled-up in a plate-type continuous-flow reactor with a volume of 105 mL to a throughput of 2.79 kg of the final product per day. This continuous-flow approach provides a facile alternative scale-up route to conventional batch processing, and it helps to intensify the synthesis protocol by applying higher reaction temperatures and shorter reaction times.


Energies ◽  
2020 ◽  
Vol 13 (4) ◽  
pp. 1002 ◽  
Author(s):  
Maïté Audemar ◽  
Yantao Wang ◽  
Deyang Zhao ◽  
Sébastien Royer ◽  
François Jérôme ◽  
...  

Furfural is a platform molecule obtained from hemicellulose. Among the products that can be produced from furfural, furfuryl alcohol is one of the most extensively studied. It is synthesized at an industrial scale in the presence of CuCr catalyst, but this process suffers from an environmental negative impact. Here, we demonstrate that a non-noble metal catalyst (Co/SiO2) was active (100% conversion of furfural) and selective (100% selectivity to furfuryl alcohol) in the hydrogenation of furfural to furfuryl alcohol at 150 °C under 20 bar of hydrogen. This catalyst was recyclable up to 3 cycles, and then the activity decreased. Thus, a comparison between batch and continuous flow reactors shows that changing the reactor type helps to increase the stability of the catalyst and the space-time yield. This study shows that using a continuous flow reactor can be a solution to the catalyst suffering from a lack of stability in the batch process.


1994 ◽  
Vol 30 (3) ◽  
pp. 183-192 ◽  
Author(s):  
Ferhan Çeçen

This study examines the effect of powdered activated carbon (PAC) addition to activated sludge in the treatment of pulp bleaching effluents which contain a large amount of nonbiodegradable matter. The effect of PAC addition has been studied in both batch and continuous-flow reactors. Isotherms were developed for PAC and biomass adsorption. It was shown that substrate removal by air stripping and biosorption was negligible. The change in substrate concentration occurred mainly by biodegradation. The biological removal data obtained in batch and continuous-flow reactors were fitted to kinetic models. Both batch and continuous-flow experiments revealed that there remained a high amount of nonbiodegradable substrate as expressed by residual COD and Color436. Carbon addition to activated sludge resulted in a high decrease in substrate concentration, particularly for color. However, the results indicated that there was no noticable biological enhancement with PAC addition. The combined PAC and activated sludge process seemed to be a combination of adsorption and biodegradation.


1987 ◽  
Vol 19 (3-4) ◽  
pp. 505-516 ◽  
Author(s):  
André van Niekerk ◽  
David Jenkins ◽  
M. G. Richard

The removal of substrates from wastewaters by activated sludge is commonly expressed in terms of a collective substrate parameter such as COD, BOD5 or TOC. Several different linear and non-linear rate expressions are employed to describe complex substrate removal in the literature. The indiscriminate application of batch substrate uptake rates to the analysis or design of continuous-flow reactors can introduce errors. These potential errors have particular significance in the design of aerobic selectors used to control low F/M bulking.


Proceedings ◽  
2019 ◽  
Vol 2 (13) ◽  
pp. 994
Author(s):  
Philipp Sulzer ◽  
René Lebl ◽  
Torsten Mayr

In this contribution we present an optical oxygen sensor that can easily be integrated into continuous flow reactors. The sensors are pressure resistant to up to 8 bars and are able to continuously measure oxygen for several hours in organic solvents. The dynamic range was evaluated up to 42 mmol/L O2 and several calibrations showed the sensors to perform linearly according to Stern-Volmer, which allows convenient two-point calibrations. By using state-of-the-art HPLC connectors and materials the sensor can be implemented at virtually every point of a standard flow reactor. Readout is conducted via a 4-channel USB phase fluorimeter.


2005 ◽  
Vol 129 (1) ◽  
pp. 111-118 ◽  
Author(s):  
Laurence W. Gill ◽  
Orlaith A. McLoughlin

The main UV dose-related kinetic parameters influencing solar disinfection have been investigated for the design of a continuous flow reactor suitable for a village-scale water treatment system. The sensitivities of different pathogenic microorganisms under solar light in batch processes have been compared in order to define their relative disinfection kinetics with E. coli used as a baseline organism. Dose inactivation kinetics have been calculated for small scale disinfection systems operating under different conditions such as reflector type, flow rate, process type, photocatalytic enhancement, and temperature enhancement using E. coli K-12 as a model bacterium. Solar disinfection was shown to be successful in all experiments with a slight improvement in the disinfection kinetic found when a fixed TiO2 photocatalyst was placed in the reactor. There was also evidence that the photocatalytic mechanism prevented regrowth in the post-irradiation environment. A definite synergistic solar UV∕temperature effect was noticed at a temperature of 45°C. The disinfection kinetics for E. coli in continuous flow reactors have been investigated with respect to various reflector shapes and flow regimes by carrying out a series of experiments under natural sunlight. Finally, photocatalytic and temperature enhancements to the continuous flow process have been evaluated.


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