scholarly journals Steroid estrogens in primary and tertiary wastewater treatment plants

2005 ◽  
Vol 52 (8) ◽  
pp. 273-278 ◽  
Author(s):  
O. Braga ◽  
G.A. Smythe ◽  
A.I. Schafer ◽  
A.J. Feitz

The concentrations of two natural estrogens (estrone (E1) and Estradiol (E2)) and one synthetic progestin (Ethinylestradiol (EE2)) were measured for different unit operations in an advanced sewage treatment plant and in a large coastal enhanced primary sewage treatment plant. The average influent concentration to both plants was similar: 55 and 53ng/L for E1 and 22 and 12ng/L for E2 for the advanced and enhanced primary STPs, respectively. The activated sludge process at the advanced STP removed up to 85% and 96% of E1 and E2, respectively. The enhanced primary sewage treatment plant was mostly ineffective at removing the steroids with only 14% of E1 and 5% of E2 being removed during the treatment process. EE2 was not been detected during the study period in the influent or effluent of either STP. The difference in the observed removal between the two plants is primarily linked to plant performance but the extent to which removal of steroid estrogens is due to bacterial metabolism (i.e. the advanced STP) rather than adsorption to the bacterial biomass remains unclear. The poor removal observed for the coastal enhanced primary STP may have implications for the receiving environment in terms of a greater potential for abnormal reproductive systems in marine animals, particularly if discharges are into large bays or harbours where flushing is limited.

2020 ◽  
Vol 15 (2) ◽  
pp. 142-151
Author(s):  
Peter Lukac ◽  
Lubos Jurik

Abstract:Phosphorus is a major substance that is needed especially for agricultural production or for the industry. At the same time it is an important component of wastewater. At present, the waste management priority is recycling and this requirement is also transferred to wastewater treatment plants. Substances in wastewater can be recovered and utilized. In Europe (in Germany and Austria already legally binding), access to phosphorus-containing sewage treatment is changing. This paper dealt with the issue of phosphorus on the sewage treatment plant in Nitra. There are several industrial areas in Nitra where record major producers in phosphorus production in sewage. The new wastewater treatment plant is built as a mechanicalbiological wastewater treatment plant with simultaneous nitrification and denitrification, sludge regeneration, an anaerobic zone for biological phosphorus removal at the beginning of the process and chemical phosphorus precipitation. The sludge management is anaerobic sludge stabilization with heating and mechanical dewatering of stabilized sludge and gas management. The aim of the work was to document the phosphorus balance in all parts of the wastewater treatment plant - from the inflow of raw water to the outflow of purified water and the production of excess sludge. Balancing quantities in the wastewater treatment plant treatment processes provide information where efficient phosphorus recovery could be possible. The mean daily value of P tot is approximately 122.3 kg/day of these two sources. The mean daily value of P tot is approximately 122.3 kg/day of these two sources. There are also two outflows - drainage of cleaned water to the recipient - the river Nitra - 9.9 kg Ptot/day and Ptot content in sewage sludge - about 120.3 kg Ptot/day - total 130.2 kg Ptot/day.


1998 ◽  
Vol 33 (2) ◽  
pp. 231-252 ◽  
Author(s):  
D.T. Bennie ◽  
C.A. Sullivan ◽  
H.-B. Lee ◽  
R.J. Maguire

Abstract Nonylphenol polyethoxylates and their refractory metabolites, including nonylphenol, are on the second Priority Substances List (PSL2) to determine if they are "toxic" as defined under the Canadian Environmental Protection Act. This study addresses the need for data on their occurrence in raw sewage, final effluents and sludge in Canada. Samples of raw sewage, final effluent and sludge were collected from 16 wastewater treatment plants across Canada in 1995 and 1996. These samples were analyzed for 4-nonylphenol (4-NP), nonylphenol ethoxylate (NP1EO), nonylphenol diethoxylate (NP2EO) and 4-4-tert-octylphenol (4-t-OP). Measurable quantities of these chemicals were found in almost all raw sewage and sludge samples. In the raw sewage, concentrations ranged from <0.005 to 21 μg/L for 4-t-OP, from 0.69 to 155 μg/L for 4-NP, from 2.9 to 43 μg/L for NP1EO and from 0.26 to 24 μg/L for NP2EO. Sludge concentrations (based on dry weight) ranged from <0.010 to 20 μg/g, from 8.4 to 850 μg/g, from 3.9 to 437 μg/g and from 1.5 to 297 μg/g for 4-t-OP, 4-NP, NP1EO and NP2EO, respectively. Of the final effluent samples, 60% contained detectable amounts of 4-t-OP and concentrations ranged from <0.005 to 0.37 μg/L. Almost all of the final effluent samples had detectable levels of 4-NP, NP1EO and NP2EO. The 4-NP concentrations varied from <0.020 to 13 μg/L, NP1EO was found in the range of 0.072 to 26 μg/L and NP2EO was found in the range of 0.099 to 21 μg/L.


2017 ◽  
Vol 35 (1) ◽  
pp. 141-148 ◽  
Author(s):  
Michał Marzec

AbstractThe reliability of removal of selected contaminants in three technological solutions of the household sewage treatment plants was analysed in this paper. The reliability of the sewage treatment plant with activated sludge, sprinkled biological deposit and hybrid reactor (activated sludge and immersed trickling filter) was analyzed. The analysis was performed using the Weibull method for basic indicators of impurities, BOD5, COD and total suspended solids. The technological reliability of the active sludge treatment plant was 70% for BOD5, 87% for COD and 66% for total suspended solids. In the sewage treatment plant with a biological deposit, the reliability values determined were: 30% (BOD5), 60% (COD) and 67% (total suspended solids). In a treatment plant with a hybrid reactor, 30% of the BOD5and COD limit values were exceeded, while 30% of the total suspended solids were exceeded. The reliability levels are significantly lower than the acceptable levels proposed in the literature, which means that the wastewater discharged from the analysed wastewater treatment plants often exceeds the limit values of indicators specified in currently valid in Poland Regulation of the Minister of Environment for object to 2000 population equivalent.


1973 ◽  
Vol 8 (1) ◽  
pp. 122-147
Author(s):  
J. D. O’Blenis ◽  
T.R. Warriner

Abstract The current widespread practice of disposal of water filtration plant wastes by direct discharge to receiving waters is coming under critical review by regulatory agencies. Among the alternatives for management of these wastes is the possibility of disposal to sanitary sewer systems. Since a recent nation-wide survey had established alum sludge as the most common waste generated by filtration plants, research was initiated to study the effects of water plant alum sludge on primary sewage treatment. A pilot primary sewage treatment plant was constructed and operated with a raw sewage feed of five litres per minute. A laboratory jar test program was conducted to supplement pilot plant operation. Sludges from two different water purification plants were tested along with alum and combinations of alum and water purification plant sludge for their effects on the removal of suspended solids, chemical oxygen demand (COD) and phosphates. The data showed jar testing to be a good indicator of pilot plant performance. Suspended solids, COD and phosphate removal efficiencies were improved by the addition of the sludges. The phosphate removal capacity of water treatment plant alum sludge was approximately the same as that reported for aluminum hydroxide, or about 1/7 to 1/9 of that determined for alum (as Aluminum). Recycling of the sludges improved phosphate removal performance.


1992 ◽  
Vol 25 (4-5) ◽  
pp. 51-58
Author(s):  
B. Teichgräber

The Emschergenossenschaft plans to improve the Emscher drainage system by separating sewage and clean water. 6 or 7 subcatchment areas will be created and served by separate wastewater treatment plants. The Bottrop WWTP has been planned for 1.3 million population equivalents. It is scheduled to start operation in 1995 and its costs are estimated as totalling 820 million DM in total. Biological treatment will be effected by a low-loaded, single-stage activated sludge system with cascade denitrification and modified UCT process.


1994 ◽  
Vol 30 (4) ◽  
pp. 25-34
Author(s):  
M. Ettala ◽  
E. Rossi

Seven operational mishaps were specified on the basis of a questionnaire on wastewater treatment plants, some of them large. In this study a process was developed for screening the chemical spill risks to municipal biological sewage treatment plant. Data on wastewater treatment processes, potential spill sources and chemical properties were combined to determine the threshold chemical quantities which may inhibit the removal of carbonaceous material, prevent nitrification and methanogenesis, cause sludge contamination or lead to the aeration capacity being exceeded. Two sewage treatment plants and eleven industrial sites were chosen for field studies. The influence of spill duration and maintenance activities on threshold quantities are discussed. A field survey lasting 1-2 hours at each site was long enough for the most relevant data to be obtained when the screening method developed was applied. Several chemical spill risks to the plants studied were specified. In addition, cases were identified in which failure of the pretreatment facilities for industrial wastewaters could cause severe mishaps at a biological wastewater treatment plant.


2021 ◽  
Vol 8 (1) ◽  
pp. 16-28
Author(s):  
Tareq Ahmed Ismaeel

The contamination in Tigress and Euphrates Rivers in Iraq has reached a high level for several reasons; one of these reasons is the discharged of sewage treatment plant (STP) effluent in the rivers, as well as other wastewater treatment plants. But the major problem is to taker discharge of wastewater to the river directly with no treatment! Many tankers in different places in all governorates in Iraq are utilized because of the absence of sewers which collecting the domestic discharge. Wastewater discharge in the rivers increases the pollution levels and especially when the river level decreases during summer seasons. In the last few years, the pollution was dramatically exacerbated. In this paper, an optimum Design for Decentralized Sewage Treatment Plant will be presented. Discharge of sewage tanks in the Tigris River has a severe negative impact on the environment; causing a deficiency in the dissolved oxygen in the water and increasing the limits of toxicity due to the accumulation of organic and inorganic substances. Pollution has become a serious issue that directly affects the aquatic life, agriculture, and people. The design unit has good specifications for effluent water discharge. TSS (Total Suspended Solid) decreased to less than 10 ppm, BOD (Biochemical Oxygen Demand) to less than 10 ppm, and COD (Chemical Oxygen Demand) to less than 50 ppm. The designed unit showed a good and easy operation and maintenance with less chemicals used.


Entecho ◽  
2019 ◽  
Vol 2 (1) ◽  
pp. 6-12
Author(s):  
Ivan Karpíšek ◽  
Jitka Zachová ◽  
Dana Vejmelková ◽  
Vladimír Sýkora

Aktivovaný kal na čistírnách odpadních vod je neustále vystavován nízkým koncentracím antimikrobiálních látek a dalších léčiv. To vyvolává otázku, jak mikroorganismy k těmto látkám na čistírně odpadních vod přistupují. Zda jsou schopny se v tomto prostředí na tyto látky adaptovat, degradovat je, případně je využít jako substrát. Nebo jestli jsou tyto látky aktivovaným kalem opomíjeny. Pro posouzení adaptace aktivovaného kalu byla využita metoda PCR pro sledování genů resistence a testy biologické rozložitelnosti. Pro testy byl využit aktivovaný kal z ČOV a kal adaptovaný v laboratorních SBR modelech při koncentracích antibiotik 500 ng∙l−1 a 500 μg∙l−1. Biologická rozložitelnost byla posuzována dle normy ČSN ISO 14593. Testované látky byly sledovány pomocí skupinového stanovení celkového anorganického uhlíku. Jako testované látky byly vybrány: benzylpenicilin, ampicilin, streptomycin, erythromycin, chloramfenikol, sulfamethoxazol a trimetoprim. Aktivovaný kal z čistírny odpadních vod neměl vyvinutou aktivitu k biodegradaci testovaných antibiotik. Je pravděpodobné, že vysoké zatížení snadno biologicky rozložitelným substrátem a krátké zdržení odpadní vody na ČOV, vede k tomu, že mikroorganismy aktivovaného kalu nejsou nuceny tyto látky aktivně utilizovat a brání se jim pouze tvorbou obranných mechanismů pomocí genů antibiotické resistence. Nízké koncentrace antibiotik v SBR modelech vytvářely selekční tlak na mikroorganismy a podněcovaly šíření genů antibiotické resistence. English Activated sludge in wastewater treatment plants is constantly exposed to low concentrations of antimicrobials and other drugs. This raises the question of how microorganisms approach to these substances in the sewage treatment plant. Whether they can adapt, degrade, or use antibiotics as a substrate in this environment or the activated sludge neglects these substances. To assess the adaptation of activated sludge, the PCR method for monitoring antibiotic resistance genes and biodegradability tests were used. These tests were carried out with activated sludge from WWTP and sludge adapted in laboratory SBR models at 500 ng∙l−1 and 500 μg∙l−1 of chosen antibiotics. Their biodegradability was assessed according to ČSN ISO 14593. The tested substances were monitored by group determination of total inorganic carbon. The chosen substances were: benzylpenicillin, ampicillin, streptomycin, erythromycin, chloramphenicol, sulfamethoxazole and trimethoprim. Activated sludge had no developed activity for biodegradation of tested antibiotics. It is likely that the high load of readily biodegradable substrate and the short retention of the wastewater at the WWTP lead to the activated sludge not being forced to actively utilize these substances and will only prevent from them by forming defence mechanisms using antibiotic resistance genes. Low concentrations of antibiotics in SBR models produced selective pressure on microorganisms and stimulated the spread of antibiotic resistance genes.


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