Phosphorus recovery from wastewater through struvite formation in fluidized bed reactors: a sustainable approach

2008 ◽  
Vol 57 (2) ◽  
pp. 175-181 ◽  
Author(s):  
M. I. H. Bhuiyan ◽  
D. S. Mavinic ◽  
F. A. Koch

Recovery of phosphate as struvite (MgNH4PO4·6H2O), before it forms and accumulates on wastewater treatment equipment, solves wastewater treatment problems and also provides environmentally sustainable, renewable nutrient source for the agriculture sector. A pilot-scale fluidized bed reactor was used to recover phosphate through crystallization of struvite, from anaerobic digester centrate at the Lulu Island Wastewater Treatment Plant, Richmond, British Columbia, Canada. The desired degree of phosphate removal was achieved by maintaining operating pH (8.0–8.2), and recycle ratio 5–9, to control the supersaturation conditions inside the reactor. The performance of the system was found to be optimal when in-reactor supersaturation ratio was 2–6. Among several other operating parameters, apparent upflow velocity and magnesium to phosphate molar ratio were also found important to maintain system performance, both in terms of efficiency of phosphate removal and recovery as struvite pellets. A narrow window of upflow velocity (400–410 cm/min) was found to be effective in removing 75–85% phosphate. TOC level inside the rector was found to affect the performance to some extent. The precipitation potential of struvite could be successfully predicted using a thermodynamic solubility product value of 10−13.36 and its temperature dependence in PHREEQC.

1994 ◽  
Vol 30 (3) ◽  
pp. 119-128
Author(s):  
Elemér Dobolyi ◽  
Imre Takács

An existing rendering plant wastewater treatment facility has to be upgraded to meet the newly set British and more stringent EC effluent standards. After detailed analysis it turned out, that the existing treatment plant cannot be upgraded, a new plant has to be built. The rendering plant processes slaughterhouse wastes. The wastewater contains easily biodegradable organic substances, mainly organic acids, organic bonded nitrogen and ammonia. According to the new effluent standards the main task, besides the organic removal was the complete removal of nitrogen. The aim of this study was to find out the best available technology and the basic wastewater design data. For this purpose, on site pilot scale experiments were carried out. In several test runs the influent BOD and T K N have varied of between 1400-5500 and 460-1120 mg/l, respectively. Based on the experimental results, single-sludge nitrification-denitrification technology was selected for the full scale treatment plant. The plant was extended by chemical phosphate removal applying the post-precipitation method. In addition to the experimental schedule, a mathematical model of the plant was developed for two purposes.– to verify the applicability of the general activated sludge model under high concentration influent conditions, and– to generalize experimental results and provide a tool to predict plant performance under full scale conditions. On the basis of successful pilot plant experiments and model calibration, full scale plant design parameters were determined and presented. The full scale plant is under construction.


2020 ◽  
Vol 15 (2) ◽  
pp. 142-151
Author(s):  
Peter Lukac ◽  
Lubos Jurik

Abstract:Phosphorus is a major substance that is needed especially for agricultural production or for the industry. At the same time it is an important component of wastewater. At present, the waste management priority is recycling and this requirement is also transferred to wastewater treatment plants. Substances in wastewater can be recovered and utilized. In Europe (in Germany and Austria already legally binding), access to phosphorus-containing sewage treatment is changing. This paper dealt with the issue of phosphorus on the sewage treatment plant in Nitra. There are several industrial areas in Nitra where record major producers in phosphorus production in sewage. The new wastewater treatment plant is built as a mechanicalbiological wastewater treatment plant with simultaneous nitrification and denitrification, sludge regeneration, an anaerobic zone for biological phosphorus removal at the beginning of the process and chemical phosphorus precipitation. The sludge management is anaerobic sludge stabilization with heating and mechanical dewatering of stabilized sludge and gas management. The aim of the work was to document the phosphorus balance in all parts of the wastewater treatment plant - from the inflow of raw water to the outflow of purified water and the production of excess sludge. Balancing quantities in the wastewater treatment plant treatment processes provide information where efficient phosphorus recovery could be possible. The mean daily value of P tot is approximately 122.3 kg/day of these two sources. The mean daily value of P tot is approximately 122.3 kg/day of these two sources. There are also two outflows - drainage of cleaned water to the recipient - the river Nitra - 9.9 kg Ptot/day and Ptot content in sewage sludge - about 120.3 kg Ptot/day - total 130.2 kg Ptot/day.


1992 ◽  
Vol 25 (4-5) ◽  
pp. 203-209 ◽  
Author(s):  
R. Kayser ◽  
G. Stobbe ◽  
M. Werner

At Wolfsburg for a load of 100,000 p.e., the step-feed activated sludge process for nitrogen removal is successfully in operation. Due to the high denitrification potential (BOD:TKN = 5:1) the effluent total nitrogen content can be kept below 10 mg l−1 N; furthermore by some enhanced biological phosphate removal about 80% phosphorus may be removed without any chemicals.


2010 ◽  
Vol 62 (8) ◽  
pp. 1965-1965
Author(s):  
S. Park ◽  
J. Lee ◽  
J. Park ◽  
I. Byun ◽  
T. Park ◽  
...  

Publisher‘s note. We regret that the published version of this article erroneously denoted the first author as corresponding author; in fact the formal corresponding author of this paper is Professor Taeho Lee, whose address is repeated below.


2017 ◽  
Vol 77 (1) ◽  
pp. 70-78 ◽  
Author(s):  
Yanjun Mao ◽  
Xie Quan ◽  
Huimin Zhao ◽  
Yaobin Zhang ◽  
Shuo Chen ◽  
...  

Abstract The activated sludge (AS) process is widely applied in dyestuff wastewater treatment plants (WWTPs); however, the nitrogen removal efficiency is relatively low and the effluent does not meet the indirect discharge standards before being discharged into the industrial park's WWTP. Hence it is necessary to upgrade the WWTP with more advanced technologies. Moving bed biofilm processes with suspended carriers in an aerobic tank are promising methods due to enhanced nitrification and denitrification. Herein, a pilot-scale integrated free-floating biofilm and activated sludge (IFFAS) process was employed to investigate the feasibility of enhancing nitrogen removal efficiency at different hydraulic retention times (HRTs). The results showed that the effluent chemical oxygen demand (COD), ammonium nitrate (NH4+-N) and total nitrogen (TN) concentrations of the IFFAS process were significantly lower than those of the AS process, and could meet the indirect discharge standards. PCR-DGGE and FISH results indicated that more nitrifiers and denitrifiers co-existed in the IFFAS system, promoting simultaneous nitrification and denitrification. Based on the pilot results, the IFFAS process was used to upgrade the full-scale AS process, and the effluent COD, NH4+-N and TN of the IFFAS process were 91–291 mg/L, 10.6–28.7 mg/L and 18.9–48.6 mg/L, stably meeting the indirect discharge standards and demonstrating the advantages of IFFAS in dyestuff wastewater treatment.


2002 ◽  
Vol 46 (4-5) ◽  
pp. 435-440 ◽  
Author(s):  
E. Levlin ◽  
M. Löwén ◽  
K. Stark ◽  
B. Hultman

Expected requirements of phosphorus recovery, restrictions on sludge disposal on landfill, and difficulties in obtaining consensus on sludge use on agricultural land has led to several development works in Sweden to change sludge management methods. Especially sludge fractionation has gained interest including following steps to recover products and separate transfer of toxic substances into a small stream. Commercial systems are offered based on technology by Cambi/KREPRO and BioCon and other companies and many other methods are under development. Iron salts are widely used in Sweden as precipitation agents for phosphorus removal and this technology has some disadvantages for phosphorus recovery compared with the use of biological phosphorus removal. The amount of chemicals needed for a KREPRO or a BioCon system was calculated for a treatment plant which has an addition of iron salt resulting in 1,900 mole Fe per tonne DS. The result was compared with the chemical consumption of recovery systems installed at plants with lower use of iron for precipitation. The chemical consumption in equivalents per tonne DS was found to be 5,000 + 6,000 * (molar ratio iron to phosphorus).


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