Low temperature anaerobic biotreatment of priority pollutants

2008 ◽  
Vol 57 (4) ◽  
pp. 499-503 ◽  
Author(s):  
R. M. McKeown ◽  
G. Collins ◽  
F. A. Chinalia ◽  
T. Mahony ◽  
V. O'Flaherty

The effect of low operating temperature and pollutant concentration on the performance of five anaerobic hybrid reactors was investigated. Stable and efficient long-term (>400 days) treatment of a cold (6–13°C), volatile fatty acid (VFA)-based, wastewater was achieved at applied organic loading rates (OLRs) of 5 kg chemical oxygen demand (COD) m−3 d−1 with COD removal efficiencies c. 84% at 6°C (sludge loading rate (SLR) 1.04–1.46 kg COD kg [VSS]−1 d−1). VFA-based wastewaters, containing up to 14 g pentachlorophenol (PCP) m−3 d−1 or 155 g toluene m−3 d−1 were successfully treated at applied OLRs of 5–7 kg COD m−3 d−1. Despite transient declines in reactor performance in response to increasing toxicant loading rates, stable operation (COD removal efficiencies > 90%) and satisfactory toxicant removal efficiencies (>88%) were demonstrated by the systems.

1983 ◽  
Vol 15 (8-9) ◽  
pp. 359-368 ◽  
Author(s):  
L van den Berg ◽  
K J Kennedy

Cheese whey and a dilute waste from a cheese factory with a Chemical Oxygen Demand of 66,000 and 4,000 mg (COD)/L respectively, were treated at high loading rates in 0.7 to 1.2 L downflow anaerobic stationary fixed film reactors and an upflow sludge bed reactor. In downflow stationary fixed film reactors treating cheese whey, COD removal efficiencies of 97% were achieved at a loading rate of 5 kg COD/m3/day and 92% at a maximum loading rate of 22 kg COD/m3/day. With dairy plant waste, loading rates of up to 15 kg COD/m3/day were possible with COD removal efficiencies averaging 75%, decreasing slightly with increasing loading rates. In an upflow sludge bed reactor the COD removal efficiency of dairy plant waste, decreased from 87% at 5 kg COD/m3/day to 73% at 15 kg COD/m3/day. A stationary fixed film reactor treating a skim milk powder waste (4,000 ppm) could only be operated at up to 10 kg COD/m3/day with a treatment efficiency of 72%. Methane was produced from all wastes at rates corresponding to 0.32 m3 CH4 (0°C, 1 atm) per kg COD removed. Results show that stationary fixed film reactors are capable of treating dairy wastes at high loading rates and high COD removal efficiencies.


2005 ◽  
Vol 51 (6-7) ◽  
pp. 421-430 ◽  
Author(s):  
E. Melin ◽  
T. Leiknes ◽  
H. Helness ◽  
V. Rasmussen ◽  
H. Ødegaard

The effect of moving bed biofilm reactor (MBBR) loading rate on membrane fouling rate was studied in two parallel units combining MBBR and membrane reactor. Hollow fiber membranes with molecular weight cut-off of 30 kD were used. The HRTs of the MBBRs varied from 45 min to 4 h and the COD loading rates ranged from 4.1 to 26.6 g COD m−2 d−1. The trans-membrane pressure (TMP) was very sensitive to fluxes for the used membranes and the experiments were carried out at relatively low fluxes (3.3–5.6 l m−2 h−1). Beside the test with the highest flux, there were no consistent differences in fouling rate between the low- and high-rate reactors. Also, the removal efficiencies were quite similar in both systems. The average COD removal efficiencies in the total process were 87% at 3–4 h HRT and 83% at 0.75–1 h HRT. At high loading rates, there was a shift in particle size distribution towards smaller particles in the MBBR effluents. However, 79–81% of the COD was in particles that were separated by membranes, explaining the relatively small differences in the removal efficiencies at different loading rates. The COD fractionation also indicated that the choice of membrane pore size within the range of 30 kD to 0.1 μm has very small effect on the COD removal in the MBBR/membrane process, especially with low-rate MBBRs.


2011 ◽  
Vol 64 (4) ◽  
pp. 923-929 ◽  
Author(s):  
Nidal Mahmoud ◽  
Jules B. van Lier

The possibility of enhancing the process performance of the UASB-septic tank for treating strong sewage in Palestine by means of inoculating the reactor with well adapted anaerobic sludge and/or adding a packing media to the upper part of the reactor, creating an anaerobic hybrid (AH)-septic tank, was investigated. To achieve these objectives, two community onsite UASB-septic tank and AH-septic tank were operated in parallel at 2 days HRT for around 8 months overlapping the cold and hot periods of the year in Palestine. The achieved removal efficiencies of CODtot in the UASB-septic tank and AH-septic tank during the first months of operation, coinciding with the cold period and the subsequent hot period, were respectively 50(±15)% and 48(±15)% and 66(±8)% and 55(±8)%. This shows that the UASB-septic tank performed significantly better (p < 0.05) than the AH-septic tank after rather long periods of operation. The difference in the CODtot removal efficiency was mainly due to the better CODss removal efficiencies in the UASB-septic tank. The removal efficiencies over the last 50 days of operation for CODtot, CODsus, CODcol and CODdis were 70, 72, 77 and 55% and 53, 54, 78 and 45% for the UASB-septic tank and AH-septic tank, respectively. Comparing the here achieved COD removal efficiencies with previously reported efficiencies of UASB-septic tanks operated in Palestine shows that the reactor performance in terms of COD removal and conversion, during the first 8 months of operation, has improved substantially by being started with well adapted anaerobic sludge, simulating and predicting long-term performance. Adding packing media did not lead to an improvement.


Author(s):  
Ahmad Zuhairi Abdullah ◽  
Mohamad Hakimi Ibrahim ◽  
Mohd. Omar Ab. Kadir

Kertas kerja ini membincangkan tentang kecekapan penuras cucur dalam merawat supernatan kumbahan kilang kelapa sawit (POME). Supernatan POME diperoleh menerusi dua jenis perawatan. Dalam perawatan 1, pengendapan graviti digunakan untuk menyingkir pepejal boleh mendak. Perawatan 2 digunakan untuk menyingkir pepejal boleh mendak dan gumpalan partikal dengan menggunakan 350 ppm alum. Influen dialurkan secara titisan pada biojisim yang terlekat pada penyokong pepejal rawak PVC setinggi 1 m. Penuras cucur berupaya menyingkir lebih daripada 90.0% dari keperluan oksigen biologi (BOD) dan keperluan oksigen kimia (COD) di bawah 1 m3/m2–hari. Pada 2.53 m3/m2–hari, influen dengan Perawatan 1 menghasilkan kecekapan penyingkiran COD sebanyak 40.3%, berbanding 83.1% bila Perawatan 2 digunakan. Perkara ini berlaku berikutan penyingkiran bahan organik tak boleh resap semasa Perawatan 2. Kecekapan penyingkiran menurun dengan meningkatnya bebanan hidraulik kerana wujudnya kelemahan dalam hidrolisis bahan tak boleh resap kepada substratum larut. Dengan edaran semula (α=1), penyingkiran BOD dan COD yang lebih tinggi dicapai di bawah 7 m3/m2–hari. Pencapaian ini disebabkan oleh bebanan organik yang lebih rendah serta pergedaran semula enzim dan biojisim yang aktif kepada sistem. Perawatan 2 menghasilkan enap cemar yang lebih tinggi kerana penukaran substratum boleh larut kepada biojisim tak boleh larut. Hidrolisis bahan organik tak boleh resap didapati berlaku secara aktif pada bahagian atas penuras cucur sementara bahagian bawahnya cenderung mengoksidakan substratum organik. Kata kunci: POME, turas cucur, bahan organik bolehresap, penggumpalan, alir semula This paper discusses the efficiency of a trickling filter to treat Palm Oil Mill Effluent (POME) supernatants. POME supernatants were obtained via two treatments. In Treatment 1, gravity sedimentation was used to remove settleable solids. In Treatment 2, both settleable solids and colloidal particles were removed using 350 ppm of alum. The influents were allowed to trickle over biomass attached to 1 m high random PVC solid support. Below 1 m3/m2–day, the filter demonstrated Biological Oxygen Demand (BOD) and Chemical Oxygen Demand (COD) removal efficiencies of more than 90.0%. At 2.53 m3/m2–day, the influent with Treatment 1 gave a COD removal efficiency of 40.3%, but increased to 83.1% when the influent with Treatment 2 was used. This was ascribed to the removal of non–diffusible organics during Treatment 2. The removal efficiencies decreased with an increase in hydraulic loading due to limitations in the hydrolysis of non–diffusibles into soluble substrates. With recirculation (α=1), higher BOD and COD removals were achieved below 7.0 m3/m2–day, attributed to lower organic loading and the recycling of active enzyme and biomass to the system. The influent with Treatment 2 demonstrated higher sludge production due to higher conversion of soluble substrates into insoluble biomass. Hydrolysis of non–diffusible organics mainly took place at upper reaches of the filter column while lower reaches were involved in oxidizing the organic subtrates. Key words: POME, trickling filter, diffusible organic, coagulation, recirculation


2016 ◽  
Vol 75 (1) ◽  
pp. 57-68 ◽  
Author(s):  
Takahiro Watari ◽  
Trung Cuong Mai ◽  
Daisuke Tanikawa ◽  
Yuga Hirakata ◽  
Masashi Hatamoto ◽  
...  

Conventional aerated tank technology is widely applied for post treatment of natural rubber processing wastewater in Southeast Asia; however, a long hydraulic retention time (HRT) is required and the effluent standards are exceeded. In this study, a downflow hanging sponge (DHS) reactor was installed as post treatment of anaerobic tank effluent in a natural rubber factory in South Vietnam and the process performance was evaluated. The DHS reactor demonstrated removal efficiencies of 64.2 ± 7.5% and 55.3 ± 19.2% for total chemical oxygen demand (COD) and total nitrogen, respectively, with an organic loading rate of 0.97 ± 0.03 kg-COD m−3 day−1 and a nitrogen loading rate of 0.57 ± 0.21 kg-N m−3 day−1. 16S rRNA gene sequencing analysis of the sludge retained in the DHS also corresponded to the result of reactor performance, and both nitrifying and denitrifying bacteria were detected in the sponge carrier. In addition, anammox bacteria was found in the retained sludge. The DHS reactor reduced the HRT of 30 days to 4.8 h compared with the existing algal tank. This result indicates that the DHS reactor could be an appropriate post treatment for the existing anaerobic tank for natural rubber processing wastewater treatment.


2004 ◽  
Vol 49 (5-6) ◽  
pp. 281-288 ◽  
Author(s):  
S.J. Kim ◽  
P.Y. Yang

A two-stage entrapped mixed microbial cell (2SEMMC) process which separates nitrification and denitrification phases by the installation of the anoxic and oxic EMMC reactors packed with EMMC carriers was operated with 6, 4, 3, and 2 hours of hydraulic retention time (HRT) using simulated domestic wastewater. The activated sludge was immobilized using cellulose acetate for the EMMC carriers. Similar soluble chemical oxygen demand (SCOD) removal efficiencies of 90-97% were observed for all HRTs (SCOD loading rate of 0.84-2.30 g/L/d) applied. In order to achieve more than 80 % of TN removal efficiency, the HRT should be maintained higher than 4 hours (less than 0.24 g/L/d of TN loading rate). Denitrification was a rate-limiting step which controlled overall TN removal efficiency at TN loading rate of 0.15-0.31 g/L/d although nitrification efficiencies achieved 97-99 %. The effluent TSS of less than 25 mg/L in the 2SEMMC process was maintained at the SCOD loading rate of less than 1.23 g/L/d with back-washing intervals of 5 and 10 days in the anoxic and oxic EMMC reactors, respectively. The minimum HRT of 4 hours is required for high removal efficiencies of organics (average 95.6 %) and nitrogen (average 80.5 %) in the 2SEMMC process with 3 times of recirculation ratio.


2012 ◽  
Vol 9 ◽  
pp. 57-62
Author(s):  
Fiza Sarwar ◽  
Wajeeha Malik ◽  
Muhammad Salman Ahmed ◽  
Harja Shahid

Abstract: This study was designed using actual effluent from the sugary mills in an Up-flow Anaerobic Sludge Blanket (UASB) Reactor to evaluate treatability performance. The reactor was started-up in step-wise loading rates beginning from 0.05kg carbon oxygen demand (COD)/m3-day to 3.50kg-COD/m3-day. The hydraulic retention time (HRT) was slowly decreased from 96 hrs to eight hrs. It was observed that the removal efficiency of COD of more than 73% can be easily achieved at an HRT of more than 16 hours corresponding to an average organic loading rate (OLR) of 3.0kg-COD/m3-day, at neutral pH and constant temperature of 29°C. The average VFAs (volatile fatty acids) and biogas production was observed as 560mg/L and 1.6L/g-CODrem-d, respectively. The average methane composition was estimated as 62%. The results of this study suggest that the treatment of sugar mills effluent with the anaerobic technology seems to be more reliable, effective and economical.DOI: http://dx.doi.org/10.3126/hn.v9i0.7075 Hydro Nepal Vol.9 July 2011 57-62


2008 ◽  
Vol 57 (7) ◽  
pp. 1047-1052 ◽  
Author(s):  
U. Durán ◽  
O. Monroy ◽  
J. Gómez ◽  
F. Ramírez

The biological elimination of polymeric resins compounds (PRC) such as acrylic acid and their esters, vinyl acetate and styrene under methanogenic and oxygen-limited methanogenesis conditions was evaluated. Two UASB reactors (A and B) were used and the removal of the organic matter was studied in four stages. Reactor A was used as methanogenic control during the study. Initially both reactors were operated under methanogenic conditions. From the second stage reactor B was fed with 0.6 and 1 mg/L·d of oxygen (O2). Reactor A had diminution in chemical oxygen demand (COD) removal efficiency from 75±4% to 37±5%, by the increase of PRC loading rate from 750 to 1125 mg COD/L·d. In this reactor there was no styrene elimination. In reactor B the COD removal efficiency was between 73±5% and 80±2%, even with the addition of O2 and increase of the PRC loading rate, owing to oxygen being used in the partial oxidation of these compounds. In this reactor the yields were modified from 0.56 to 0.40 for CH4 and from 0.31 to 0.60 for CO2. The O2 in low concentrations increased 40.7% the consumption rates of acrylic acid, methyl acrylate and vinyl acetate, allowing styrene consumption with a rate of 0.103 g/L·d. Batch cultures demonstrated that under methanogenic and oxygen-limited methanogenesis conditions, the glucose was not used as an electron acceptor in the elimination of PRC.


2011 ◽  
Vol 2011 ◽  
pp. 1-6 ◽  
Author(s):  
Lawrence Yoo ◽  
Hansang Kim ◽  
Andrew Shin ◽  
Vijay Gupta ◽  
Joseph L. Demer

This paper characterized bovine extraocular muscles (EOMs) using creep, which represents long-term stretching induced by a constant force. After preliminary optimization of testing conditions, 20 fresh EOM samples were subjected to four different loading rates of 1.67, 3.33, 8.33, and 16.67%/s, after which creep was observed for 1,500 s. A published quasilinear viscoelastic (QLV) relaxation function was transformed to a creep function that was compared with data. Repeatable creep was observed for each loading rate and was similar among all six anatomical EOMs. The mean creep coefficient after 1,500 seconds for a wide range of initial loading rates was at1.37±0.03(standard deviation, SD). The creep function derived from the relaxation-based QLV model agreed with observed creep to within 2.7% following 16.67%/s ramp loading. Measured creep agrees closely with a derived QLV model of EOM relaxation, validating a previous QLV model for characterization of EOM biomechanics.


2015 ◽  
Vol 72 (11) ◽  
pp. 2034-2044 ◽  
Author(s):  
Rosa Elena Yaya Beas ◽  
Katarzyna Kujawa-Roeleveld ◽  
Jules B. van Lier ◽  
Grietje Zeeman

This research was conducted to study the faecal coliforms removal capacity of downflow hanging sponge (DHS) reactors as a post-treatment for an upflow anaerobic sludge blanket (UASB) reactor. Three long-term continuous laboratory-scale DHS reactors, i.e. a reactor with cube type sponges without recirculation, a similar one with recirculation and a reactor with curtain type sponges, were studied. The porosities of the applied medium were 91%, 87% and 47% respectively. The organic loading rates were 0.86 kgCOD m−3 d−1, 0.53 kgCOD m−3 d−1 and 0.24 kgCOD m−3 d−1 correspondingly at hydraulic loading rates of 1.92 m3 m−2 d−1, 2.97 m3 m−2 d−1 and 1.32 m3 m−2 d−1, respectively (COD: chemical oxygen demand). The corresponding averages for faecal coliform removal were 99.997%, 99.919% and 92.121% respectively. The 1989 WHO guidelines standards, in terms of faecal coliform content for unrestricted irrigation (category A), was achieved with the effluent of the cube type DHS (G1) without recirculation. Restricted irrigation, category B and C, is assigned to the effluent of the cube type with recirculation and the curtain type, respectively. Particularly for organic compounds, the effluent of evaluated DHS reactors complies with USEPA standards for irrigation of so called non-food crops like pasture for milking animals, fodder, fibre, and seed crops.


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