Ultra-low dioxane in ethoxy sulphate products

Author(s):  
Ilio Sebastiani ◽  
◽  
Antonio Milicia ◽  
Icilio Adami

The progressive reduction of the permitted content of 1,4-dioxane in ethoxy sulphates presents an increased challenge for surfactant producers. This article discusses technical solutions that can be put in place based on the chemistry of the 1,4-dioxane molecule and its formation mechanism during surfactant production. Desmet Ballestra’s “ultra-low dioxane technology” is discussed in detail, with emphasis on the technical features, advantages, and achievable quality. Technologies for 1,4-dioxane degradation and disposal into water effluent streams are also illustrated.

2021 ◽  
Vol 12 (1) ◽  
pp. 18-29
Author(s):  
A. M Petrov ◽  
A. N Popov

In the presented article, the team of authors considers the existing methods and the main modern technical solutions that are currently implemented in different countries in the diagnosis of heat supply networks. There is a selection of the main directions in the development and design of heat supply networks, which have already been implemented or supported by scientific teams from different countries. Various methods and technical features of diagnostics are reviewed, strengths and weaknesses of the presented solutions are highlighted. The reviewed works were subjected to detailed analysis, which revealed the presence of a high interest of the scientific and industrial community in the integration and improvement of existing digital technologies in the development of heat supply systems, which would be closely related to forecasting and modeling processes in this industry. The team of authors highlights the main vectors for the development of this sector, citing an example of a significant increase in the degree of digitalization of final products, which makes it possible to use data analytics to obtain effective technical solutions regarding heat supply networks. Separately, the positive experience of different countries in this industry is noted when using neural networks not only in the design of heat supply networks, but also as a target industry as a whole. Assumptions are put forward about the need for a detailed analysis of the existing foreign and domestic experience, as well as scientific developments in this area, in order to determine the most suitable technical solutions on the territory of the Russian Federation, which will take into account the climatic characteristics of the country and be based on methods of large data analysis, computer vision and simulation. modeling.


Author(s):  
A. B. Biryukov ◽  
S. M. Saf’yants ◽  
P. A. Gnitiev ◽  
V. A. Shatovich

There are a number of technical solutions to utilize the waste gases of electric arc furnaces (EAF) for scrap preheating thus returning back the heat into the technological process. The waste gases can be utilized also for steam or hot water production. The preliminary scrap heating before charging it into EAF is more perspective. Technical features of various types scrap heaters considered, including conveyer and shaft scrap heating technologies with continuous (Contiarc, Consteel, Comelt, BBC-Brusa) and periodic charging (Fuchs Systemtechnik, COSS, backet). It was shown that application of scrap heaters for EAF ensures saving of electric energy, increase of metal yield, decrease of dust and gases level in the shop, decrease of negative impact on environment. The disadvantages include frequent and costly repairs of the facilities, impossibility to control some factors having effect on the process of scrap heating. It was shown that when designing new EAFs with a charge exceeding 100 t, horizontal facilities are more preferrable, while for EAFs of small volumes shaft heaters suit better. At EAF modernizing it is recommended to use shaft heaters and back­et-thermos, since it is easier to construct a vertical furnace than a horizontal one with minimal length of 100 m. It was noted that hor­izontal heaters operate better in terms of technology, since ensure continuous charging by scrap, but at that occupy a considerable space in the shop. When comparing vertical heaters and backet by all the characteristics including heat-engineering and designingones, vertical shaft heaters prevail.


2015 ◽  
Vol 1 (1) ◽  
Author(s):  
Carlo Veca

AbstractPottery technology, although largely neglected in studies of the Sicilian Early Bronze Age (Castelluccio culture, 2200-1450 BC), represents a strategic field of research for focusing on main steps of manufacturing of Castelluccian vessels. In this perspective, the evidence from the archaeological deposit of Colle della Croce (Scicli, Ragusa) has allowed us to emphasise some new technical features that can be observed in the production within other cultural districts. The most significant phase of the study was the autoptic examination of materials and surfaces that led to the definition of this production as medium and coarse ware, with the use of different kinds of technical solutions in relation to different uses and functions. The manufacturing techniques, especially when surface treatment is clearly recognizable on fragmentary specimens, can be conditioned by several factors, such as the shape type and the function of the vessel. Features such as working plans and supporting systems were observed quite frequently, as well as polishing techniques and joints slots for the handles that could be interpreted as ‘workshop standards’ rather than simply local traditions.


Author(s):  
Margherita Micheletti Cremasco ◽  
Federica Caffaro ◽  
Ambra Giustetto ◽  
Lucia Vigoroso ◽  
Giuseppe Paletto ◽  
...  

Objective:To identify the critical behaviors that may hinder the correct use of foldable rollover protective structures (FROPS) on tractors and to explore the influence of user factors and FROPS technical characteristics.Background:FROPS are effective in preventing fatal injuries in rollover accidents if they are in the upright position. However, many farmers leave FROPS folded down.Method:Twenty farmers and sixteen models of tractors were involved in the study. Operators were observed while raising the FROPS, and the observed behaviors were correlated with user factors and FROPS technical features.Results:In the initial rotation of the FROPS, higher lowered roll-bar to ground distance and FROPS pivot-pin to ground distance required more awkward and unbalanced postures ( p = .02 and p = .01, respectively). When rotating the FROPS in upright position, smaller stature of the participants and higher FROPS pivot-pin to ground distance were significantly correlated with using the tractor’s rear 3-point lower links as a supporting surface ( p = .01 and p = .02, respectively).Conclusion:FROPS might be revised considering users’ comfort in use and anthropometric variability, to improve reachability, avoid risky behaviors, and enhance FROPS operation.Application:Technical solutions to enhance FROPS accessibility may be developed, particularly by providing safe surfaces to support operators and highlighting the grasping points. Further best practices and information on correct gestures to handle the FROPS should be included in the tractor manual.


2020 ◽  
Vol 55 (2) ◽  
pp. 117-122
Author(s):  
F. Malchair ◽  
C. Maccia

Radiation protection and dose optimisation in computerized tomography (CT) for pediatric patients are of utmost importance because of the potential risk of cancer induction by exposure to ionizing radiation. A review of available technical features in modern CT machines aiming at reducing and/or optimizing patient dose was performed. Practical advices to operators were listed according to dose-related technical solutions studied to decrease the doses and to practically implement dose optimisation.


Author(s):  
A. W. Fetter ◽  
C. C. Capen

Atrophic rhinitis in swine is a disease of uncertain etiology in which infectious agents, hereditary predisposition, and metabolic disturbances have been reported to be of primary etiologic importance. It shares many similarities, both clinically and pathologically, with ozena in man. The disease is characterized by deformity and reduction in volume of the nasal turbinates. The fundamental cause for the localized lesion of bone in the nasal turbinates has not been established. Reduced osteogenesis, increased resorption related to inflammation of the nasal mucous membrane, and excessive resorption due to osteocytic osteolysis stimulated by hyperparathyroidism have been suggested as possible pathogenetic mechanisms.The objectives of this investigation were to evaluate ultrastructurally bone cells in the nasal turbinates of pigs with experimentally induced atrophic rhinitis, and to compare these findings to those in control pigs of the same age and pigs with the naturally occurring disease, in order to define the fundamental lesion responsible for the progressive reduction in volume of the osseous core.


Author(s):  
K.-H. Herrmann ◽  
W. D. Rau ◽  
R. Sikeler

Quantitative recording of electron patterns and their rapid conversion into digital information is an outstanding goal which the photoplate fails to solve satisfactorily. For a long time, LLL-TV cameras have been used for EM adjustment but due to their inferior pixel number they were never a real alternative to the photoplate. This situation has changed with the availability of scientific grade slow-scan charged coupled devices (CCD) with pixel numbers exceeding 106, photometric accuracy and, by Peltier cooling, both excellent storage and noise figures previously inaccessible in image detection technology. Again the electron image is converted into a photon image fed to the CCD by some light optical transfer link. Subsequently, some technical solutions are discussed using the detection quantum efficiency (DQE), resolution, pixel number and exposure range as figures of merit.A key quantity is the number of electron-hole pairs released in the CCD sensor by a single primary electron (PE) which can be estimated from the energy deposit ΔE in the scintillator,


Author(s):  
S. P. Eron’ko ◽  
M. Yu. Tkachev ◽  
E. V. Oshovskaya ◽  
B. I. Starodubtsev ◽  
S. V. Mechik

Effective application of slag-forming mixtures (SFM), being fed into continuous castingg machine (CCM) moulds, depends on their even distribution on the melt surface. Manual feeding of the SFM which is widely usedd does not provide this condition, resulting in the necessity to actualize the work to elaborate systems of SFM mechanized feedingg into moulds of various types CCM. A concept of the designing of a system of SFM feeding into CCM moulds presented with the ratte strictly correspondent to the casting speed and providing formation of an even layer of fine material of given thickness on the whoole surface of liquid steel. The proposed methods of designing of the SFM mechanized feeding systems based on three-dimensional computer simulation with the subsequent verification of the correctness of the adopted technical solutions on field samples. Informattion is presented on the design features of the adjusted facilities intended for continuous supply of finely granulated and powder mixtuures on metal mirror in moulds at the production of high-quality billets, blooms and slabs. Variants of mechanical and pneumo-mechaanical SFM supply elaborated. At the mechanical supply the fine material from the feeding hopper is moved at a adjusted distance bby a rigid horizontally located screw. At the pneumo-mechanical supply the metered doze of the granular mixture is delivered by a sshort vertical screw, the lower part of which is located in the mixing chamber attached from below to the hopper and equipped with ann ejector serving for pneumatic supply of the SFM in a stream of transporting gas. It was proposed to use flexible spiral screws in the ffuture facilities of mechanical SFM feeding. It will enable to eliminate the restrictions stipulated by the lack of free surface for locatiion of the facility in the working zone of the tundish, as well as to decrease significantly the mass of its movable part and to decreaase the necessary power of the carriage moving mechanism driver. The novelty of the proposed technical solutions is protected by thhree patents. The reduction of 10–15% in the consumption of slag-forming mixtures during the transition from manual to mechanizeed feeding confirmed. The resulting economic effect from the implementation of technical development enables to recoup the costs inncurred within 8–10 months.


Author(s):  
I. I. Lube ◽  
N. V. Trutnev ◽  
S. V. Tumashev ◽  
A. V. Krasikov ◽  
A. G. Ul’yanov ◽  
...  

At production of pipes of type 13Cr grade steel used at development of oil and gas deposits in areas with aggressive environment, intensive wear of instrument takes place, first of all, piercing mill mandrels. Factors, influencing the resistivity of the piercing mandrels considered, including chemical composition of the material, the mandrel is made of and its design. Based on industrial experience it was shown, that chrome content in the mandrel material practically does not affect on the increase of its resistivity, since the formed thin protective oxides having high melting temperature, are quickly failed and practically are not restored in the process of piercing. To increase the resistivity of piercing mandrels at production of casing tubes of type 13Cr grade steel, a work was accomplished to select a new material for their manufacturing. The chemical composition of steel presented, which was traditionally used for piercing mandrels manufacturing, as well as a steel grade proposed to increase their resistivity. First, molybdenum content was increased, which increases the characteristics of steel strength and ductility at high temperatures and results in grain refining. Second, tungsten content was also increased, which forms carbides in the steel resulting in an increase of its hardness and “red resistivity”, as well as in preventing grains growth during heating. Third, cobalt content was also increased, which increases heat resistivity and shock loads resistivity. The three elements increase enabled to increase the mandrels resistivity by two times. Results of mandrel test of steel 20ХН2МВ3КБ presented, the mandrel having corrugation on the working cone surface, which enabled to reach the resistivity growth to 12 passes without significant change of instrument cost. Microstructure of mandrels made of steels 20Х2Н4МФА and 20ХН2МВ3КБ shown. Application of the centering pin of special design was tested, which provided forming of a rounding edge on the front billet ends, eliminated undercut of mandrel external surface in the process of secondary billet grip and increase the service life of the piercing mill mandrels. At production of seamless pipes of martensite class type 13Cr stainless steels having L80 group of strength, an increase of piercing mandrel resistivity was reached by more than four times, which together with other technical solutions enabled to increase the hourly productivity of the hot rolling section of Volzhsky pipe plant ТПА 159-426 line by more than two times.


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