scholarly journals Synthesis New Pyridinium Salts as Corrosion Inhibitors for Mild Steel in 1 M H2SO4

2021 ◽  
Vol 24 (2) ◽  
pp. 14-20
Author(s):  
Rania Kareem Hameed ◽  
◽  
Mehdi Salih Shihab ◽  
Keyword(s):  
Weight Loss ◽  
Free Energy ◽  
Corrosion Rate ◽  
Mild Steel ◽  
Corrosion Inhibitors ◽  
Organic Molecules ◽  
Inhibition Efficiency ◽  
Pyridinium Salts ◽  
Inhibitor Concentration ◽  
Pyridinium Bromide

Some new pyridinium salts, namely 4-(4-Chloro-benzylidene-hydrazinocarbonyl)-1-phenyl-pyridinium bromide, C1; 4-(4-Chloro-benzylidene-hydrazinocarbonyl)-1-butyl-pyridinium bromide, C2; 4-(4-Chloro-benzylidene-hydrazinocarbonyl)-1-phencyl-pyridinium bromide, C3; were synthesized and Corrosion inhibitors for mild steel were tested in a 1M H2SO4aqueous solution at 20ºC for 24 hours using weight loss measurements. The findings revealed that the inhibition efficiency of all pyridinium bromide derivatives converges at the maximum concentration. An increase in inhibitor concentration is associated with a decrease in corrosion rate, an increase in inhibition efficiencies, and an increase in surface degree of coverage. The physisorption effects for (C1, C2, and C3) were revealed by the free energy values of adsorption, which provided useful information for predicting the interaction between the metal surface and organic molecules as corrosion inhibitors.

scholarly journals Study New Pyridine Derivatives as Corrosion Inhibitors for Mild Steel in an Acidic Media

2021 ◽  
Vol 24 (3) ◽  
pp. 1-8
Author(s):  
Rania Kareem Hameed ◽  
◽  
Mehdi Salih Shihab ◽  
Keyword(s):  
Mild Steel ◽  
Corrosion Inhibitors ◽  
Organic Molecules ◽  
Surface Coverage ◽  
Inhibition Efficiency ◽  
Pyridinium Salts ◽  
Pyridine Derivatives ◽  
Acidic Media ◽  
Free Energy Of Adsorption ◽  
Pyridinium Bromide

Some new pyridinium salts, namely4-(4-bromo-benzylidene-hydrazinocarbonyl)-1-phenyl-pyridinium bromide, A1; 4-(4-bromo-benzylidene-hydrazinocarbonyl)-1-butyl-pyridinium bromide, A2; 4-(4-bromo-benzylidene-hydrazinocarbonyl)-1-phencyl-pyridinium bromide, A3; were synthesized and studied as corrosion inhibitors for mild steel in 1M H2SO4aqueous solution at 20°C by weight loss measuring for 24 hrs. The results showed that the inhibition efficiency of all pyridinium bromide derivatives had a significant in value with the highest concentration. An increase in the inhibitor concentration is accompanied by a decrease in the corrosion rate, an increase in the retarding efficiency and an increase in the degree of surface coverage. The values of the free energy of adsorption revealed the effects of spontaneously reaction of (A1, A2, and A3) and gave useful information to predict the interaction between the metal surface and the organic molecules as corrosion inhibitors.

scholarly journals Ethanolamines as Corrosion Inhibitors for Zinc in (HNO3+H2SO4) Binary Acid Mixture

2010 ◽  
Vol 7 (2) ◽  
pp. 665-668 ◽  
Author(s):  
R. T. Vashi ◽  
H. M. Bhajiwala ◽  
S. A. Desai
Keyword(s):  
Corrosion Rate ◽  
Acid Concentration ◽  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Corrosion Behaviour ◽  
Acid Mixture ◽  
Inhibitor Concentration

This work deals with the study of corrosion behaviour for zinc in (HNO3+ H2SO4) binary acid mixture containing ethanolamines. Corrosion rate increases with concentration of acid and temperature. At constant acid concentration, the inhibition efficiency of ethanolamines increases with the inhibitor concentration. Value of ΔGa increases and inhibition decreases with temperature. The mode of inhibition action appears to be chemisorption.

scholarly journals Inhibition of Brass Corrosion in Acid Medium Using Thiazoles

2013 ◽  
Vol 14 ◽  
pp. 87-102
Author(s):  
K.K. Taha ◽  
Musa E. Mohamed ◽  
S.A. Khalil ◽  
S.A. Talab
Keyword(s):  
Weight Loss ◽  
Thermal Properties ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Corrosion Rate ◽  
Heat Exchangers ◽  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Zinc Dissolution

Brass as an alloy composed mainly of copper is great industrial uses such as heat exchangers and similar other facility due to its good thermal properties. Due to the presence of the considerable ratio of zinc the alloy suffers from zinc dissolution or dezincification. Dezincification rate increases with the increase in the ratio of zinc in the alloy. In this study benzothiazole (BTH) and its substituent’s 2-methylbenzothiazole (MeBTH), 2-aminobenzothiazole (ABTH), 2-mercaptobenzothiazole (MBTH) and 2-phenylbenzothiazole (PhBTH) have been used as corrosion inhibitors for α-brass in stirred 0.1 M HClO4. The methods of investigation include weight loss, Tafel and linear polarizations and electrochemical impedance spectroscopy. The order of inhibition efficiency (%E) was calculated and the values obtained has indicated the sequence of inhibition efficiency was found to be BTH < MeBTH < ABTH < PhBTH < MBTH. The calculated values of thermodynamic parameters support this order. The inhibitors were found to suppress the corrosion rate by the formation of films which were identified by IR, SEM and EDAX techniques.

POLYVINYLPYROLLIDONE AND POLYACRYLAMIDE AS CORROSION INHIBITORS FOR MILD STEEL IN ACIDIC MEDIUM

2008 ◽  
Vol 15 (03) ◽  
pp. 277-286 ◽  
Author(s):  
S. A. UMOREN ◽  
I. B. OBOT
Keyword(s):  
Adsorption Isotherm ◽  
Corrosion Rate ◽  
Mild Steel ◽  
Acidic Medium ◽  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Adsorption Process ◽  
Physical Adsorption ◽  
Activation Parameters ◽  
Temkin Adsorption Isotherm

The corrosion inhibition of mild steel in 1 M H 2 SO 4 in the presence of polyvinylpyrollidone (PVP) and polyacrylamide (PA) as inhibitors at 30–60°C was studied using gravimetric and gasometric techniques. The inhibition efficiency (1%) increased with increase in concentration of the inhibitors. Increase in temperature increased the corrosion rate in the absence and presence of inhibitors but decreased the inhibition efficiency. Both PVP and PA were found to obey Temkin adsorption isotherm and Kinetic-Thermodynamic Model of El-Awady at all the concentrations and temperatures studied. Phenomenon of physical adsorption is proposed from the activation parameters obtained. Thermodynamic parameters reveal that the adsorption process is spontaneous. PVP was found to be a better inhibitor than PA.

scholarly journals Synergistic effect of ZnO nanoparticles with organic compound as corrosion inhibition

2020 ◽  
Author(s):  
Buraq T Sh AL-Mosawi ◽  
Mohammed M Sabri ◽  
Muhanad A Ahmed
Keyword(s):  
Weight Loss ◽  
Mild Steel ◽  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Corrosion Process ◽  
Zno Nps ◽  
Weight Loss Method ◽  
Steel Surfaces ◽  
Loss Method ◽  
Isatin Derivative

Abstract In chemical manufactures, the corrosion inhibitors were added in order to reduce the corrosion of mild steel. Chemical molecules are often used on mild steel surfaces as portion of the latest finishing steps before painting and/or storage. Here, this work elucidated the utilization of an isatin derivative, namely, 3-((3-acetylphenyl)imino)indolin-2-one synergistic with zinc oxide nanoparticles for improving the impedance of mild steel (MS) against corrosion in 1.0 M hydrochloric acid using the weight loss method and scanning electron microscopy (SEM). Weight loss measurements demonstrated that the best 3-((3-acetylphenyl)imino)indolin-2-one concentration was 0.5 mM and the inhibition efficiency was 83% whereas the inhibition efficiency was 92% with addition of ZnO NPs. 3-((3-Acetylphenyl)imino)indolin-2-one retards the corrosion process at 300 K and demonstrates low inhibition efficiencies at 310, 320 and 330 K.

scholarly journals Investigating the Inhibitive Characteristics of Moringa Oleifera on the Corrosion of Mild Steel

2021 ◽  
Vol 9 (9) ◽  
pp. 595-602
Author(s):  
Okpaga D. M
Keyword(s):  
Weight Loss ◽  
Corrosion Rate ◽  
Mild Steel ◽  
Immersion Time ◽  
Moringa Oleifera ◽  
Inhibition Efficiency ◽  
Sodium Hydroxide Solution ◽  
Total Surface Area ◽  
Corrosion Rates ◽  
Very High

Abstract: This work deals with the inhibitive characteristics of Moringa oleifera fruits and leaves extracts in Hydrochloric Acid solution and Sodium Hydroxide solution respectively on the corrosion of mild steel. This was carried out using weight loss and polarization techniques. The effects of immersion time, the effect of acid and alkaline concentration on the corrosion behavior of mild steel in 1.0M HCl and 1.0 NaOH with addiction of extracts were deduced. The fruits which were dried and grounded to powder of 10g and the leaves which range from 25cm3 to 100cm3 were used for this study. The corrosion rate was very high in the absence of inhibitors (Moringa oleifera fruits and the leaves extracts). The mild steel was cut into coupon averaging a total surface area of 4.262cm2 . The sample was weighed and immersed into a beaker containing 1.0M NaOH with different volumes of moringa leaves and 1.0M HCl with 10g dried concentrated powdered moringa fruits with coupons removed every 7 days for weight loss measurements till 4 weeks. The corrosion rates were found to be decreased by 83% in 1.0M HCl and 78% in 1.0M NaOH respectively, values of inhibition efficiency (ࣁ (%were calculated from weight loss. The results obtained showed that the Moringa oleifera fruits and leaves extracts could serve as effective inhibitors on the corrosion of mild steel in HCl and NaOH respectively. Keywords: Moringa oleifera, Corrosion rate, Weight loss, Mild steel, Inhibitor.

scholarly journals Synergistic effect on inhibiton efficiency of coconut husk fibre essence in controlling corrosion of mild steel in neutral medium

2015 ◽  
Vol 49 (3) ◽  
pp. 185-188
Author(s):  
A Sankar ◽  
S Ananth Kumar ◽  
S Rameshkumar
Keyword(s):  
Weight Loss ◽  
Mild Steel ◽  
Steel Surface ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Neutral Medium ◽  
Well Water ◽  
Inhibitor Concentration ◽  
Coconut Husk ◽  
Tank Water

The corrosion inhibition nature of coconut husk essence for the corrosion of mild steel in tank water (neutral medium) was investigated using weight loss, electrochemical impedance and Potentiodynamic Polarization methods. The results revealed that coconut husk essence acts as a corrosion inhibitor in well water. The inhibition efficiency increased with an increase in inhibitor concentration. The inhibition is attributed to adsorption of the inhibitor on the steel surface. DOI: http://dx.doi.org/10.3329/bjsir.v49i3.22133 Bangladesh J. Sci. Ind. Res. 49(3), 185-188, 2014

scholarly journals Anti-Corrosive Behavior of the Seed Extract of Amomum sabulatum

2021 ◽  
Vol 309 ◽  
pp. 01026
Author(s):  
Neha Daksh ◽  
Akhil Saxena ◽  
Jayahari Lade ◽  
Nakul Gupta
Keyword(s):  
Weight Loss ◽  
Electron Microscope ◽  
Corrosion Rate ◽  
Scanning Electron Microscope ◽  
Mild Steel ◽  
Plant Extract ◽  
Inhibition Efficiency ◽  
Protective Layer ◽  
Seed Extract ◽  
Scanning Electron

An aqueous extract of Amomum sabulatum seeds was evaluated for anticorrosive effects on mild steel in the presence of HCl. Weight loss measurements were taken to determine the corrosion rate and inhibition efficiency at various concentrations. With the increasing concentrations of plant extract, the results showed an improvement in inhibition efficiency and a decrease in corrosion rate. In the presence of 1500 ppm concentration of plant extract, it has an inhibition efficiency of 82.08 % at 303 K. The scanning electron microscope was used to examine the surface, which proves that while the extract was there, a protective layer formed on the metal surface.

scholarly journals Corrosion Inhibition of Mild-Steel in 0.5 M HCl using some prepared 1,2,3-Triazoles Derivatives

2019 ◽  
Vol 9 (4) ◽  
pp. 290-304 ◽  
Author(s):  
Hawraa Kareem Dhaif ◽  
Ekhlas Q . Jasim ◽  
Zena A. Muhajjar ◽  
Ashwaq A. Shanta
Keyword(s):  
Activation Energy ◽  
Weight Loss ◽  
Corrosion Rate ◽  
Mild Steel ◽  
Langmuir Isotherm ◽  
Mixed Type ◽  
Inhibition Efficiency ◽  
Temperature Impact ◽  
The Impact ◽  
Hcl Solution

The Weight loss was employed to investigate the impact of triazole on mild-steel dissolution in 0.5 M HCl solution. The inhibitor’s inhibition efficiency was seen to increase with concentration yielding (81.61%,82.61%,88.29%,91.64%,94.32%) of (T9, T8, T6, T4, T1) at concentration 1×10-4 M HCl, at a temperature of 25°C for 240 min. At a temperature range from 25–45°C, we studied the temperature impact on the corrosion behavior, wherein the results demonstrated decrease in inhibition efficiency with rising in temperature to achieve (61.7%, 52.26%, 63.1%, 72.11%, 75.77 %) of (T9, T8, T6, T4 and T1) at a concentration of 1×10-4 M, at a temperature 45°C for 240 min. A study was also performed regarding the impact of temperature on the corrosion rate in the presence and absence of triazole. The activation energy and Kinetic parameters were calculated and discussed. Polarization curves revealed that the studied inhibitors represent a mixed – type inhibitors. Adsorption of inhibitors was found to obey Langmuir isotherm and was isotherm physisorption type.

Adsorption and corrosion inhibition characteristics of two medicinal molecules

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Hydrochloric Acid ◽  
Corrosion Rate ◽  
Mild Steel ◽  
Corrosion Inhibition ◽  
Half Life ◽  
Thermodynamic Data ◽  
Inhibition Efficiency ◽  
Gravimetric Method ◽  
Corrosive Environment ◽  
Corrosion Inhibition Efficiency

The corrosion inhibition characteristics of two medicinal molecules phenylalanine and rutin on mild steel in 1.0M Hydrochloric acid were evaluated using gravimetric method. Corrosion inhibition efficiency of 83.78 and 90.40 % was obtained respectively after seven days. However, phenylalanine showed weak accumulative higher corrosion inhibition efficiency. The presence of both molecules in the corrosive environment reduced the corrosion rate constant and increased the material half-life. Thermodynamic data calculated suggests a spontaneous adsorption of the molecules on the mild steel’s surface.

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