scholarly journals PENGARUH JENIS ASAM ALAMI TERHADAP PENURUNAN KADAR LOGAM BERAT TIMBAL DALAM DAGING IKAN TERI (Stelophorus indicus Sp) ASAL TELUK PALU

KOVALEN ◽  
2016 ◽  
Vol 2 (3) ◽  
Author(s):  
Yulita Nelin Sipa ◽  
Jamaluddin Jamaluddin ◽  
Ihwan Ihwan

Research on the effect of type natural acid against decline of content heavy metals plumbum in meat anchovy (Stelophorus indicus Sp) origin bay Palu. The purpose of this study was to determine the best type of acid used in dissolving levels of plumbum as heavy metals for 1 hour immersion and to determine the number of levels of heavy metals of lead that can be dissolved during immersion 1 hour. This study begins with a sample digestion using nitric acid, further qualitative test reagents dithizon 0.005% (positive), potassium iodide (positive) and sodium carbonate (postitif). Qualitative results test that showed a positive result then measured in metal content of plumbum  using atomic absorption spectrophotometer (AAS) at λ 283.3 nm. Then soaking using tamarind are 5%, acetic acid 10%, the filtrate pineapple 100%, starfruit 100% and lime 25% for 1 hour at room temperature, after measuring the metal content of plumbum with atomic absorption spectrophotometer (AAS) in λ 283.3. The results show levels of heavy metals plumbum before immersion average of 0.8 mg/kg, the average concentration of heavy metals plumbum after soaking tamarind 5% amounting to 0.787 mg/kg (1.64%), 10% acetic acid at 0.789 mg/kg (1.39%), pineapple filtrate 100% of 0.7882 mg/kg (1.49%), starfruit 100% 0.789 mg/kg (1.39%) and lime 25% of 0.7916 mg/kg (1.06%). Thus tamarind 5% is the best type of acid to reduce levels of plumbum metal in Palu bay anchovy origin.Keywords: Acid, Anchovy (Stelophorus indicus Sp), Content, Plumbum

2017 ◽  
Vol 17 (2) ◽  
pp. 131
Author(s):  
Emas Agus Prastyo Wibowo ◽  
Ika Sri Hardyanti ◽  
Isni Nurani ◽  
Dyan Septyaningsih Hardjono HP ◽  
Aden Dhana Rizkita

STUDI PENURUNAN KADAR LOGAM BESI (Fe) DAN LOGAM TEMBAGA (Cu) PADA AIR EMBUNG MENGGUNAKAN ADSORBEN NANOSILIKAABSTRAKPolusi limbah logam berat dalam air merupakan satu permasalahan lingkungan yang penting. Dalam mengatasi permasalahan tersebut dapat dilakukan purifikasi terhadap air tersebut. Metode yang dapat digunakan untuk purifikasi limbah sangat beragam salah satunya adalah absorpsi. Secara umum metode absorpsi telah banyak digunakan dalam purifikasi air limbah. Metode absorpsi dapat menurunkan kadar logam yang terlarut pada limbah. cair dengan cara menyerap logam-logam tersebut ke dalam permukaan absorbennya. Tujuan dilakukan penelitian ini adalah  untuk menurunkan konsentrasi logam besi (Fe) dan tembaga (Cu) menggunakan adsorben nanosilika. Penelitian ini menggunakan variabel bebas yaitu waktu pengadukan (20 menit, 40 menit, dan 60 menit). Hasil akhir filtrat air embung kemudian diukur absorbansinya menggunakan Spektrofotometer Serapan Atom. Berdasarkan hasil analisa menggunakan instrumen SSA diperoleh hasil bahwa tidak terjadi penurunan logam Fe maupun Cu. Dalam hal ini terjadi peningkatan konsentrasi dalam logam Fe maupun Cu, hal ini dikarenakan kurangnya waktu pengadukan dan pengaruh dari adsorben nanosilika.Kata Kunci: limbah, logam berat, nanosilika STUDY OF DECREASING METALS IRON (Fe) AND COPPER (Cu) ON EMBUNG WATER USE OF NANOSILICA ADSORBEN ABSTRACTHeavy waste pollution of heavy metals in the water is an important environment issue. To solve the problem, its can be purified the water. The methods that can be used for waste purification are very diverse, one of which is absorption. In general, the method of absorption has been widely used in wastewater purification. The absorption method can decrease dissolved metal content in the waste. liquid by absorbing the metals into the absorbent surface. Research has been conducted to reduce the concentration of iron (Fe) and copper (Cu) by using nanosilica adsorbent. This research used to independent variable that is stirring time (20 minutes, 40 minutes, and 60 minutes). The final result of filtrate embung water then measured its absorbance using Atomic Absorption Spectrophotometer (AAS). Based on the result of the analysis using SSA instrument, it is found that there is no decrease of Fe and Cu metals. There are several reasons for those problem such as due to lack of stirring time and the influence of nanosilica adsorbent.Keywords: Waste pollution, heavy metal, nanosilica


2019 ◽  
Vol 22 (1) ◽  
pp. 1
Author(s):  
Andini Komalasari ◽  
Budi Afriyansyah ◽  
Muhammad Ihsan ◽  
Mohammad Agung Nugraha

Bioaccumulation of Pb and Cu Heavy Metals to Penaeus merguiensis in the Waters of Inner Kelabat BayThe waters of Kelabat Bay has a wealth of marine resources that is quite important in supporting the economy of Bangka Regency and West Bangka Regency. The purpose of this research was to measure the concentration of heavy metals Pb and Cu (sea water, sediment, and Penaeus merguiensis) and measure the ability of Penaeus merguiensis in accumulating heavy metals Pb and Cu. Heavy metals Pb and Cu in Water, sediments and Penaeus merguiensis analyzed using Flame Atomic Absorption Spectrophotometer (Flame AAS). The results showed that concentration of heavy metals in water with an average range of Pb (0,1042-0,1748 mg/L) and Cu (0,000013-0,000021 mg/L). Average concentration of heavy metals in Pb sediments (7,15-7,73 mg/kg) and Cu (0,0016-0,00219 mg/kg ). Average concentration of Pb heavy metals in Penaeus merguiensis (1,34-1,54 mg/kg) and Cu (0,0003-0,00045 mg/kg). The average ability of Penaeus merguiensis in accumulating heavy metals Pb and Cu is 15,83 to water and 0,19 to sediment. The value of the Bioconcentration Factor is below 250 (FBK <250) so it falls into the low category. Penaeus merguiensis is more exposed to heavy metals dissolved in water than those released from sediment.Perairan Teluk Kelabat memiliki kekayaan sumber daya laut yang cukup penting dalam mendukung perekonomian Kabupaten Bangka dan Kabupaten Bangka Barat. Penelitian ini bertujuan untuk mengukur kandungan logam berat Pb dan Cu (air laut, sedimen, dan Penaeus merguiensis) dan mengukur kemampuan Penaeus merguiensis dalam mengakumulasi logam berat Pb dan Cu. Logam berat Pb dan Cu padaair, sedimen dan Penaeus merguiensisdianalisis menggunakan Flame Atomic Absorption Spectrophotometer (Flame AAS). Hasil penelitian menunjukkan bahwa konsentrasi logam berat dalam air dengan kisaran rata-rata Pb (0,1042-0,1748 mg/L) dan Cu (0,000013-0,000021 mg/L). Kisaran konsentrasi rata-rata logam berat dalam sedimen Pb (7,15-7,73 mg/kg) dan Cu (0,0016-0,00219 mg/kg). Kisaran konsentrasi rata-rata logam berat Pb di Penaeus merguiensis (1,34-1,54 mg/kg) dan Cu (0,0003-0,00045 mg/kg). Kemampuan rata-rata Penaeus merguiensis dalam mengakumulasi logam berat Pb dan Cu yaitu 15,83 terhadap air dan 0,19 terhadap sedimen. Nilai Faktor Biokonsentrasi tersebut di bawah 250 (FBK< 250) sehingga masuk dalam kategori rendah. Penaeus merguiensis lebih banyak terpapar logam berat yang terlarut dalam air daripada yang terlepas dari sedimen. 


2019 ◽  
Vol 22 (1) ◽  
pp. 1
Author(s):  
Andini Komalasari ◽  
Budi Afriyansyah ◽  
Muhammad Ihsan ◽  
Mohammad Agung Nugraha

Bioaccumulation of Pb and Cu Heavy Metals to Penaeus merguiensis in the Waters of Inner Kelabat BayThe waters of Kelabat Bay has a wealth of marine resources that is quite important in supporting the economy of Bangka Regency and West Bangka Regency. The purpose of this research was to measure the concentration of heavy metals Pb and Cu (sea water, sediment, and Penaeus merguiensis) and measure the ability of Penaeus merguiensis in accumulating heavy metals Pb and Cu. Heavy metals Pb and Cu in Water, sediments and Penaeus merguiensis analyzed using Flame Atomic Absorption Spectrophotometer (Flame AAS). The results showed that concentration of heavy metals in water with an average range of Pb (0,1042-0,1748 mg/L) and Cu (0,000013-0,000021 mg/L). Average concentration of heavy metals in Pb sediments (7,15-7,73 mg/kg) and Cu (0,0016-0,00219 mg/kg ). Average concentration of Pb heavy metals in Penaeus merguiensis (1,34-1,54 mg/kg) and Cu (0,0003-0,00045 mg/kg). The average ability of Penaeus merguiensis in accumulating heavy metals Pb and Cu is 15,83 to water and 0,19 to sediment. The value of the Bioconcentration Factor is below 250 (FBK <250) so it falls into the low category. Penaeus merguiensis is more exposed to heavy metals dissolved in water than those released from sediment.Perairan Teluk Kelabat memiliki kekayaan sumber daya laut yang cukup penting dalam mendukung perekonomian Kabupaten Bangka dan Kabupaten Bangka Barat. Penelitian ini bertujuan untuk mengukur kandungan logam berat Pb dan Cu (air laut, sedimen, dan Penaeus merguiensis) dan mengukur kemampuan Penaeus merguiensis dalam mengakumulasi logam berat Pb dan Cu. Logam berat Pb dan Cu padaair, sedimen dan Penaeus merguiensisdianalisis menggunakan Flame Atomic Absorption Spectrophotometer (Flame AAS). Hasil penelitian menunjukkan bahwa konsentrasi logam berat dalam air dengan kisaran rata-rata Pb (0,1042-0,1748 mg/L) dan Cu (0,000013-0,000021 mg/L). Kisaran konsentrasi rata-rata logam berat dalam sedimen Pb (7,15-7,73 mg/kg) dan Cu (0,0016-0,00219 mg/kg). Kisaran konsentrasi rata-rata logam berat Pb di Penaeus merguiensis (1,34-1,54 mg/kg) dan Cu (0,0003-0,00045 mg/kg). Kemampuan rata-rata Penaeus merguiensis dalam mengakumulasi logam berat Pb dan Cu yaitu 15,83 terhadap air dan 0,19 terhadap sedimen. Nilai Faktor Biokonsentrasi tersebut di bawah 250 (FBK< 250) sehingga masuk dalam kategori rendah. Penaeus merguiensis lebih banyak terpapar logam berat yang terlarut dalam air daripada yang terlepas dari sedimen. 


2018 ◽  
Vol 21 (2) ◽  
pp. 91
Author(s):  
Chrisna Adhi Suryono ◽  
Endang Sri Susilo ◽  
Aldo Rizqi Arinianzah ◽  
Wilis Ari Setyati ◽  
Irwani Irwani ◽  
...  

Contamination of Copper in Mugil dussumeri (Actinopterygii: Mugilidae, Forsskål, 1775) which was caught in Semarang waters, Indonesia The marine environment in Semarang waters are highly polluted by heavy metals such as copper (Cu).  On the other side, these areas have become producers of fishery commodities such as mullet fish Mugil dussumieri. The aims of this study was to determine the heavy metal content of Cu in mullet fish during wet monsoon (December 2017 and February 2018). Atomic Absorption Spectrophotometer were used to analysis of Cu concentration in marine water and fish meat.  The results show that the Cu content in marine water was not detected while in the meat of mullet fish during December 2017 and February 2018 were 0.66 ± 0.07 mg/kg and 0,604 ± 0.217 mg/kg, respectively. The results were still within the quality standard for maximum limit of Cu content allowed in seafood by FAO/WHO. Lingkungan perairan laut di sekitar Semarang berpeluang sangat tinggi untuk terpolusi logam berat tembaga.  Di lain sisi perairan ini menjadi daerah produksi perikanan seperti ikan belanak Mugil dussumieri. Tujuan dari penelitian ini adalah untuk mengetahui kandungan logam Cu dalam daging ikan belanak yang ditangkap selama musim penghujan (Desember 2017 dan Februari 2018). Untuk mengetahui konsentrasi Cu dalam air laut dan ikan belanak digunakan Atomic Absorption Spectrophotometer.  Hasil penelitian menunjukkan bahwa konsentrasi logam Cu selama bulan Desember 2017 adalah 0.66 ± 0.07/kg dan selama bulan Februari 0,604 ± 0.217 mg/kg, sedangkan konsentrasi Cu dalam air laut tidak terdeteksi.  Hasil penelitian dapat disimpulkan bahwa kandungan Cu dalam ikan belanak masih berada pada konsentrasi yang diperbolehkan oleh FAO/WHO.


ALCHEMY ◽  
2015 ◽  
Vol 4 (1) ◽  
Author(s):  
Eny Rahmawati ◽  
Diana Candra Dewi ◽  
Ahmad Ghanaim Fasya ◽  
Begum Fauziyah

<p class="BodyAbstract">Candy sold in the market could be containing a heavy metals like copper. In this study, candy was destructed with HNO3, HNO3/H2SO4 (3:1) dan HNO3/H2SO4/H2O2 (6:2:1) to know the best matter oxidixer for copper. Then, evaluated the levels of copper using Atomic Absorption Spectrophotometer (AAS). The one way anove result with F test showed that the best oxidizer for copper in candy is HNO3/H2SO4. The average concentration of Copper in candy coded A, B, C, D, and E were 1. 72 mg/Kg; 1.69 mg/Kg; 1.57 mg/Kg; 1.71 mg/Kg; and 1.69 mg/Kg respectively. The content of copper in candies were the under daily dietary recommended limit based on SNI regulation.</p><p class="BodyAbstract"> </p><p class="BodyAbstract"><em><strong>Key Words:</strong> Atomic Absorption Spectrophotometry, candy, matter oxidizer, time stability, wet destruction</em></p><p class="BodyAbstract"><em> </em></p>


2019 ◽  
Vol 5 (2) ◽  
pp. 224-230
Author(s):  
Lilis Sulistiawaty ◽  
Imas Solihat ◽  
Arie Pratama Putra

Cans are widely used as primary packaging in various food products. Ferrous (Fe) and zinc (Zn) metal as the constituent components in the manufacture of can packaging bodies can experience corrosion and dissolve in food so that it will affect food quality and finally affect to health. This study aimed to determine the content of Fe and Zn metal at different treatments (time) with 3% acetic acid and vegetable oil as food simulators on can packaging using Atomic Absorption Spectrophotometer (AAS). The results of the analysis showed that the range of Fe and Zn metal content in 3% acetic acid food simulants were respectively 0.15-27.46 mg/kg and 0.00060.007 mg/kg, while in vegetable oil simulants 3% Fe and metal content Zn were 0.6-2.46 mg/kg and 0.00040.0025 mg/kg with 80-100% recovery, respectively. Thus, food from can packaging should not be exposed to oxygen for a long time, especially when it has been opened because it will increase the leaching of Fe and Zn metals from the packaging into food.


2006 ◽  
Vol 61 (5-6) ◽  
pp. 357-362 ◽  
Author(s):  
Gürcan Güleryüz ◽  
Hülya Arslan ◽  
Belgin İzgi ◽  
Şeref Güçer

In this study, heavy metal content (Cu, Fe, Mn, Ni, Pb, Zn) was determined in soils and different organs of Verbascum olympicum Boiss. This species is endemic to Uludağ and spreads on destroyed areas such as: roadsides, developed building areas, ski lift stations and sheep folds. Soils and different organs (roots, stems, leaves and flowers) of plant samples were analyzed using an atomic absorption spectrophotometer for determining the element content. Heavy metal contents in soils and different organs in this species were highly correlated (P < 0.05). However, the contribution of plant organs to the accumulation capacity varied according to the metal. These results suggest that this species may be useful as a bioindicator for heavy metals.


Author(s):  
Muhammad Abbas ◽  
Zahida Parveen ◽  
Muhammad Iqbal ◽  
M Riazuddin ◽  
Sajid Iqbal ◽  
...  

A monitoring study was carried out with the aim to assess the level of toxic metals i.e., lead (Pb), cadmium (Cd), arsenic (As) and mercury (Hg) in different vegetables grown in Sindh province of Pakistan during 2007-2008. Two hundred ten samples of twenty one vegetables were collected from farmers' field of Sindh and exporters at Karachi. These samples were grouped into four categories viz., leafy, root and tuberous, cucurbits and fruity. The samples in duplicate were digested with nitric and perchloric acid mixture with 3:1 ratio. Cadmium and Pb were analyzed with Graphite Furnace Atomic Absorption Spectrophotometer and As and Hg on Atomic Absorption using Vapor and Hydride Generation Assembly. Average concentration of Cd, Pb, As and Hg in leafy vegetables was found 0.083 μgg-1, 0.05 μgg-1, 0.042 μgg-1 and 0.008 μgg-1 respectively, in roots and tuberous vegetables was 0.057 μgg-1, 0.03 μgg-1, 0.045 μgg-1 & 0.004 μgg-1 respectively, in cucurbit vegetables was 0.021 μgg-1, 0.051 μgg-1, 0.056 μgg-1 and 0.0089 μgg-1 respectively and in fruity vegetables was 0.035 μgg-1, 0.067 μgg-1, 0.054 μgg-1 and 0.007 μgg-1 respectively. In leafy vegetables, the concentration of cadmium, lead and mercury were found comparatively higher than other three groups of vegetables. However, concentration of heavy metals found in the samples of all four categories of vegetables, was within the permissible limits and safe to consume. Keywords: Atomic Absorption Spectroscopy; Heavy Metals; Vegetables; Graphite Furnace; Vapor Generation; Hydride GenerationDOI: 10.3126/kuset.v6i2.4013Kathmandu University Journal of Science, Engineering and Technology Vol.6. No II, November, 2010, pp.60-65


2021 ◽  
Vol 322 ◽  
pp. 01022
Author(s):  
Lisbet Sagala ◽  
Sulistiono ◽  
Djamar T.F.L. Batu

Banten Bay is an area affected by industrial, shipping, and domestic activities. These have the potential to produce wastes in the form of heavy metals and can accumulate in the body of aquatic organisms such as the splendid ponyfish Eubleekeria splendens (Cuvier, 1829). This study aimed to determine the accumulation of heavy metals Hg, Cd, Pb, and Cu in splendid ponyfish Eubleekeria splendens (Cuvier, 1829) meat in Banten Bay, Serang Regency, Banten Province. Sampling was carried out for three months, from August to October 2020. Analysis of heavy metal content was carried out using AAS (Atomic Absorption Spectrophotometer). The content of heavy metals Hg, Cd, Pb, and Cu in splendid ponyfish meat were <0.030 mg/kg, <0.001 mg/kg, <0.005 mg/kg, and 0.224-0.437 mg/kg. Bioaccumulation of heavy metals Hg, Cd, Pb, and Cu in small and big splendid ponyfish meat has a low accumulation rate. During the observation period, the heavy metal content of Hg, Cd, Pb, and Cu in small and big splendid ponyfish meat was not significantly different.


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