Thermally prepared Ti/RhOx electrodes: II H2 evolution in acid solution
Keyword(s):
Ti/RhOx electrodes were prepared at 400-600?C by thermal decomposition of Rh chloride. Oxide layers were studied by SEM, cyclic voltammetry and steady-state E-j curves In 0.5 mol dm-3 H2SO4 solution. Voltammetric charge exhibits a maximum at 430?C with fresh electrodes which shifts to 470?C after use for H2 evolution. H2 discharge first produces a decrease in voltammetric charge, then an activation with final settlement to a constant behaviour for "aged" electrodes. H2 evolution on stable RhOx surfaces takes place with 40 mV Tafel slope and a reaction order of 2.5. The fractional reaction order indicates that the surface response to pH is that typical of oxides even for "aged" electrodes. A reaction mechanism is proposed.
2012 ◽
Vol 476-478
◽
pp. 1322-1326
1976 ◽
Vol 251
(7)
◽
pp. 2023-2029
Keyword(s):
1978 ◽
Vol 253
(5)
◽
pp. 1451-1457
◽
Keyword(s):
1970 ◽
Vol 13
(1)
◽
pp. 1-10
◽
2018 ◽
Vol 198
◽
pp. 455-465
◽
1977 ◽
Vol 2
(3)
◽
pp. 171-177
◽
2013 ◽
Vol 49
(2)
◽
pp. 275-283
◽
Keyword(s):
2018 ◽
Vol 15
(2)
◽
pp. 258-282
◽