scholarly journals Axial dispersion of the liquid phase on a three-phase Karr reciprocating plate column

2004 ◽  
Vol 69 (7) ◽  
pp. 581-599 ◽  
Author(s):  
Ljubisa Nikolic ◽  
Vesna Nikolic ◽  
Vlada Veljkovic ◽  
Miodrag Lazic ◽  
Dejan Skala
Keyword(s):  
Liquid Phase ◽  
Gas Flow ◽  
Dispersion Coefficient ◽  
Solid Phase ◽  
Axial Dispersion ◽  
Two Phase ◽  
Three Phase ◽  
Phase Liquid ◽  
Similar Equation ◽  
Plate Column

The influence of the gas flow rate and vibration intensity in the presence of the solid phase (polypropylene spheres) on axial mixing of the liquid phase in a three phase (gas-liquid-solid) Karr reciprocating plate column (RPC) was investigated. Assuming that the dispersionmodel of liquid flow could be used for the real situation inside the column, the dispersion coefficient of the liquid phase was determined as a function of different operating parameters. For a two-phase liquid-solid RPC the following correlation was derived: DL = 1.26(Af)1.42 UL 0.51 ?S 0.23 and a similar equation could be applied with ? 30 % confidence for the calculation of axial dispersion in the case of a three-phase RPC: DL = 1.39(Af)0.47 UL0.42UG0.03 ?S -0.26.

Multiphase Reactions and Reactors

2001 ◽  
Author(s):  
L. K. Doraiswamy
Keyword(s):  
Liquid Phase ◽  
Solid Phase ◽  
Complete Classification ◽  
Catalytic Reactions ◽  
Two Phase ◽  
Multiphase Reactions ◽  
Liquid Phases ◽  
Three Phase ◽  
Solid Form

The first three chapters of this part dealt with two-phase reactions. Although catalysts are not generally present in these systems, they can be used in dissolved form in the liquid phase. This, however, does not increase the number of phases. On the other hand, there are innumerable instances of gas-liquid reactions in which the catalyst is present in solid form. A popular example of this is the slurry reactor so extensively employed in reactions such as hydrogenation and oxidation. There are also situations where the solid is a reactant or where a phasetransfer catalyst is immobilized on a solid support that gives rise to a third phase. A broad classification of three-phase reactions and reactors is presented in Table 17.1 (not all of which are considered here). This is not a complete classification, but it includes most of the important (and potentially important) types of reactions and reactors. The thrust of this chapter is on reactions and reactors involving a gas phase, a liquid phase, and a solid phase which can be either a catalyst (but not a phasetransfer catalyst) or a reactant, with greater emphasis on the former. The book by Ramachandran and Chaudhari (1983) on three-phase catalytic reactions is particularly valuable. Other books and reviews include those of Shah (1979), Chaudhari and Ramachandran (1980), Villermaux (1981), Shah et al. (1982), Hofmann (1983), Crine and L’Homme (1983), Doraiswamy and Sharma (1984), Tarmy et al. (1984), Shah and Deckwer (1985), Chaudhari and Shah (1986), Kohler (1986), Chaudhari et al. (1986), Hanika and Stanek (1986), Joshi et al. (1988), Concordia (1990), Mills et al. (1992), Beenackers and Van Swaaij (1993), and Mills and Chaudhari (1997). Doraiswamy and Sharma (1984) also present a discussion of gas-liquid-solid noncatalytic reactions in which the solid is a reactant. In Chapter 7 we saw how Langmuir-Hinshelwood-Hougen-Watson (LHHW) models are normally used to describe the kinetics of gas-solid (catalytic) or liquid-solid (catalytic) reactions, and in Chapters 14 to 16 we saw how mass transfer between gas and liquid phases can significantly alter the rates and regimes of these two-phase reactions.

scholarly journals Hydrodynamics of gas-agitated liquid-liquid extraction columns

2012 ◽  
pp. 199-216 ◽  
Author(s):  
Milan Sovilj
Keyword(s):  
Packed Column ◽  
Perforated Plate ◽  
Continuous Phase ◽  
Extraction Column ◽  
Two Phase ◽  
Spray Column ◽  
L System ◽  
Three Phase ◽  
Phase Liquid ◽  
Plate Column

Although the non-agitated extraction columns (spray column, packed column, perforated plate column, sieve plate column, etc) can handle high flow rates and are simple and cheap, there have been relatively few applications of these columns because they suffer from serious backmixing of the continuous phase. It was shown that the backmixing is reduced when the spray column is operated with dense packing of drops. Another way of increasing the efficiency of a non-agitated extraction column is to introduce an inert gas (air, nitrogen, oxygen) as a mixing agent in the two-phase liquid-liquid (L-L) system. This method of energy introduction increases the turbulence within the new three-phase gas-liquid-liquid (G-L-L) system, which causes an improved dispersion of droplets, and, consequently, a higher dispersed phase holdup and therefore a great mass transfer area. The present study reports the hydrodynamics in the non-agitated extraction columns, as well as the axial dispersion for the two- and three-phase systems.

scholarly journals The Results of Numerical Simulation of Two-Phase Liquid-Gas Flow with Constant and Real Thermodynamics Properties of the Liquid in a Shock-Jet Nozzle

2019 ◽  
pp. 51-60
Author(s):  
A.D. Khlopov ◽  
M.S. Frantsuzov
Keyword(s):  
Liquid Phase ◽  
Thermophysical Properties ◽  
Gas Flow ◽  
Volume Fraction ◽  
Temperature Dependent ◽  
Two Phase ◽  
Dispersion Process ◽  
Commercial Software Package ◽  
Phase Liquid ◽  
Jet Nozzle

In this paper, the outflow of liquid in the coflowing airstream from a shock-jet nozzle is examined using a commercial software package with varying initial and boundary conditions. Gas-dynamic characteristics and distribution fields for pressure, velocity, temperature and volume fraction of the two-phase flow are obtained. The influence of thermophysical properties of the liquid on the process of jet dispersion is determined. The results of simulation of the liquid outflow from the shock-jet nozzle at constant and real (temperature dependent) thermophysical properties of the liquid phase are compared. The qualitative and quantitative influence of the input pressure in the nozzle on the jet dispersion process is determined. As a result of a series of calculations, the minimum required characteristics of temporal and spatial resolution for the correct solution of the problem are identified. It is established that the volume content of the liquid phase is higher with real thermophysical properties compared to the constant ones.

SYNTHESIS OF HYDROGEN IN ACOUSTOPLASMA DISCHARGE IN A LIQUID-PHASE STREAM

2019 ◽  
pp. 42-48 ◽  
Author(s):  
N. A. Bulychev
Keyword(s):  
Liquid Phase ◽  
Organic Compounds ◽  
Electrode Materials ◽  
Solid Phase ◽  
Plasma Discharge ◽  
Raw Material ◽  
Two Phase ◽  
Reduced Pressure ◽  
External Power Source ◽  
Phase Medium

In this paper, the plasma discharge in a high-pressure fluid stream in order to produce gaseous hydrogen was studied. Methods and equipment have been developed for the excitation of a plasma discharge in a stream of liquid medium. The fluid flow under excessive pressure is directed to a hydrodynamic emitter located at the reactor inlet where a supersonic two-phase vapor-liquid flow under reduced pressure is formed in the liquid due to the pressure drop and decrease in the flow enthalpy. Electrodes are located in the reactor where an electric field is created using an external power source (the strength of the field exceeds the breakdown threshold of this two-phase medium) leading to theinitiation of a low-temperature glow quasi-stationary plasma discharge.A theoretical estimation of the parameters of this type of discharge has been carried out. It is shown that the lowtemperature plasma initiated under the flow conditions of a liquid-phase medium in the discharge gap between the electrodes can effectively decompose the hydrogen-containing molecules of organic compounds in a liquid with the formation of gaseous products where the content of hydrogen is more than 90%. In the process simulation, theoretical calculations of the voltage and discharge current were also made which are in good agreement with the experimental data. The reaction unit used in the experiments was of a volume of 50 ml and reaction capacity appeared to be about 1.5 liters of hydrogen per minute when using a mixture of oxygen-containing organic compounds as a raw material. During their decomposition in plasma, solid-phase products are also formed in insignificant amounts: carbon nanoparticles and oxide nanoparticles of discharge electrode materials.

The influence of the Stokes and Archimedes forces on the stability of a two-phase flow

2003 ◽  
Vol 3 ◽  
pp. 266-270
Author(s):  
B.H. Khudjuyerov ◽  
I.A. Chuliev
Keyword(s):  
Spectral Method ◽  
Stability Region ◽  
Gas Flow ◽  
Two Phase Flow ◽  
Solid Phase ◽  
Stability Characteristic ◽  
Phase Flow ◽  
Two Phase ◽  
The Stability

The problem of the stability of a two-phase flow is considered. The solution of the stability equations is performed by the spectral method using polynomials of Chebyshev. A decrease in the stability region gas flow with the addition of particles of the solid phase. The analysis influence on the stability characteristic of Stokes and Archimedes forces.

Axial dispersion in the liquid phase in a horizontal two-phase tube reactor

1991 ◽  
Vol 56 (6) ◽  
pp. 1249-1252
Author(s):  
Marie Fialová ◽  
Ctirad Verner ◽  
Lothar Ebner
Keyword(s):  
Liquid Phase ◽  
Flow Regimes ◽  
Basic Flow ◽  
Axial Dispersion ◽  
Two Phase ◽  
Tube Reactor

The characteristics of axial dispersion in the liquid phase were measured for two basic flow regimes in a horizontal two-phase tube reactor. The data obtained indicate that in some flow regions, axial dispersion can be quite significant.

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