scholarly journals Amorphous materials based on perovskite ferroelectrics

2021 ◽  
Vol 5 (1) ◽  
Author(s):  
S.A. Gridnev ◽  
L.N. Korotkov

The methods of preparation, as well as the structure and most relevant physical properties of amorphous materials based on ferroelectrics with perovskite structure are reviewed. The theoretical basis for the possibility of ferroelectricity in non-crystalline solids is discussed. The structural relaxation in a glassy state and the crystallization processes leading to the formation of a ferroelectric phase are considered. The structure and physical properties of thin-film amorphous ferroelectrics that demonstrate noticeable differences from the properties of the same materials in bulk state are discussed separately

1988 ◽  
Vol 163 ◽  
pp. 175-179 ◽  
Author(s):  
K. Wasa ◽  
H. Adachi ◽  
K. Hirochi ◽  
K. Setsune ◽  
T. Kamada ◽  
...  

2009 ◽  
Vol 283-286 ◽  
pp. 533-538 ◽  
Author(s):  
Kazumasa Yamada ◽  
N. Shinagawa ◽  
M. Sogame ◽  
I.A. Figueroa ◽  
Hywel A. Davies ◽  
...  

The aim of this research is to clarify a quantitative evaluation in the structural relaxation processes focusing on the activation energy in Cu based amorphous alloys. The activation energy for structural relaxation process in a metal type amorphous CuHfTi ternary alloys, with cross sections of typically 0.03 mm x 2.0 mm, prepared by chill-block melt spinning has been investigated by Differential Scanning Calorimetry (DSC) with a cyclically heating technique. Activation energies for structural relaxation with a spatial quantity in amorphous materials have been discussed by use of a relaxed ratio function that depends on annealing temperature and time. In the present work, the distributions for the Activation Energy Spectrum (AES) were observed almost 152 kJmol-1 (1.58 eV). Another result has been also established that the “reversible” AES model energy distribution though the cyclically structure relaxation occurs even in amorphous Cu60Hf20Ti20 alloy.


Materials ◽  
2018 ◽  
Vol 11 (8) ◽  
pp. 1476 ◽  
Author(s):  
Dongliang Kuang ◽  
Zhou Ye ◽  
Lifeng Yang ◽  
Ning Liu ◽  
Zaihong Lu ◽  
...  

DBSA was used as a solubilizer together with conventional rejuvenator (CR) to produce a solubilized rejuvenator (SR), two kinds of aged bitumen involving TFOT aged bitumen and PAV aged bitumen were obtained by thin film oven test (TFOT) and pressurized aging vessel (PAV), respectively. Effects of CR and SR on the physical properties, chemical components, colloidal structure and micro-morphology of TFOT aged bitumen and PAV aged bitumen were investigated. Testing results of physical properties and chemical components indicated that CR and SR can replenish aged bitumen with necessary aromatics, TFOT aged bitumen that chemical component variation deteriorates its physical properties. With regard to PAV aged bitumen, of which the performance attenuation lies in chemical components variation and colloidal structure transformation, even if the content of CR reached up to 10 wt %, the regenerated bitumen cannot meet the regeneration requirement yet due to its definite influence on colloidal structure transformation, comparatively, sulfonic group in SR can react with the superficial atoms of asphaltenes to reform a solvation layer to facilitate the colloidal structure transformation of PAV aged bitumen, performance and beelike structure of regenerated PAV aged with bitumen with 10 wt % SR were approximated to that of virgin bitumen.


Metals ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 605 ◽  
Author(s):  
Vitaly Khonik ◽  
Nikolai Kobelev

The work is devoted to a brief overview of the Interstitialcy Theory (IT) as applied to different relaxation phenomena occurring in metallic glasses upon structural relaxation and crystallization. The basic hypotheses of the IT and their experimental verification are shortly considered. The main focus is given on the interpretation of recent experiments on the heat effects, volume changes and their link with the shear modulus relaxation. The issues related to the development of the IT and its relationship with other models on defects in metallic glasses are discussed.


2019 ◽  
Vol 21 (46) ◽  
pp. 25690-25699 ◽  
Author(s):  
Xiaowu Tang ◽  
Hyeok-jin Kwon ◽  
Heqing Ye ◽  
Jae Young Kim ◽  
Jaewoong Lee ◽  
...  

The addition of hardeners to the PEDOT:PSS composites enhances both electrical and physical properties to satisfy the requirements for electrode usages in organic electronic devices.


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