scholarly journals Estimating cation exchange capacity and clay content from agricultural soil testing data

2021 ◽  
Vol 30 (4) ◽  
Author(s):  
Mari Räty ◽  
Riikka Keskinen ◽  
Markku Yli-Halla ◽  
Juha Hyvönen ◽  
Helena Soinne

Clay content and the ability to reversibly retain cations affect many essential chemical and physical properties of soil, such as pH buffering and carbon sequestration. Cation exchange capacity (CEC) and base saturation are also commonly used as criteria in soil classification. However, determination of CEC and particle-size distribution is laborious and not included in routine soil testing. In this study, pedotransfer functions including soil test cations (STCat; Ca2+ + Mg2+ + K+), pH and soil organic carbon (SOC, %) as explanatory variables were developed for estimating CEC, titratable acidity (TA; H+ + Al3+) and clay content (clay, %). In addition, reference values for potential CEC and its components were determined for Finnish mineral and organic soils. The mean of potential CEC extracted by 1 M ammonium acetate at pH 7.0 ranged from 14 (range 6.4−25) in coarse soils to 33 (21−45) cmol(+) kg-1 in heavy clay soils, and from 42 (24−82) in mull soils to 77 (25−138) cmol(+) kg-1 in peat soils. The average CEC of clay and SOC were 27 and 160 cmol(+) kg-1, respectively. Titratable acidity occupied 53% and around 40% of the CEC sites in organic and mineral soils, respectively, evidencing that it is a prominent component of the potential CEC in these predominantly acidic soils. STCat, pH and SOC explained 96% of the variation in potential CEC. STCat and pH can be used in estimating the clay content especially for soils containing over 30% clay. In coarse textured soils, in contrast, SOC hampers the STCat based estimation of clay content.

2018 ◽  
Vol 39 (4) ◽  
pp. 1479
Author(s):  
Nara Núbia de Lima Cruz ◽  
Ronny Sobreira Barbosa ◽  
Marcio Cleto Soares de Moura ◽  
Daniel De Bortoli Teixeira ◽  
José Marques Júnior ◽  
...  

Global demands for an increased food production have prompted scientists to create technological innovations in various segments of the agricultural and environmental sectors. The use of diffuse reflectance spectroscopy in soil color determination to estimate its attributes is an example of these advances. Thus, the aim of this research was to identify the potential of the three parameters of the Munsell color system (Hue, Value, and Chroma) in estimating different chemical and particle size attributes by pedotransfer functions in a Typic Hapludox in the Cerrado of Piauí State, Brazil. This soil showed a yellowish color due to the goethite and low contents of bases and organic carbon. Among the calibrated pedotransfer functions, we observed that phosphorus, aluminum, hydrogen, potential acidity, potential cation exchange capacity, and base saturation could be estimated by Hue, while clay content by Value, and Chroma used to estimate hydrogen, potential acidity, and cation exchange capacity. We conclude that the parameter color could be used to estimate soil attributes.


1991 ◽  
Vol 116 (2) ◽  
pp. 275-279 ◽  
Author(s):  
E. P. Papanicolaou ◽  
C. G. Apostolakis ◽  
V. Skarlou ◽  
C. Nobeli ◽  
P. Kritidis

SUMMARYPlant:soil ratios (CRs) of 85Sr concentration were studied in wheat, lucerne, lettuce, radish, string bean (Phaseolus vulgaris), and cucumber grown in pots in eight Greek soil types in a glasshouse pot experiment in 1989.The CRs of the crops and of the plant parts studied differed according to soil type. They ranged from 0·034–1·39 for wheat grains to 7·6–36·5 for cucumber stems and leaves. The CRs of the edible parts were much lower than those of the other plant material.The correlation between CRs and clay content was negative and, in most cases, significant (P = 0·05–0·01) or highly significant (P < 0·01). The negative correlation improved (higher absolute value of r, lower variability) if clay plus silt content or cation exchange capacity was used instead of clay content.The correlation between CRs and soil properties was greatest for soil pH (r = –0·89) and decreased in the order: pH > total clay plus silt ≃ cation exchange capacity > total clay.


2017 ◽  
Vol 29 (2) ◽  
pp. 123-131
Author(s):  
Reshma Akter ◽  
Md Jamal Uddin ◽  
Md Faruque Hossain ◽  
Zakia Parveen

A study was carried out to evaluate the effects of brick manufacturing on phosphorus (P) and sulfur (S) concentrations in soil and plant collected from different distances of brick kilns in four AEZs of Bangladesh. Forty eight composite soil samples (0 - 15 cm depth) were collected from 48 points in 12 different sites at 0 m, 300 m, 800 m and 1500 m from brick kilns, where most (site 2, site 3, site 5, site 6, site 7, site 9 and site 10) of the brick kilns used coal for brick burning purposes. Plant samples (rice straw and different vegetables) were also collected from the respective fields except 0 m distances. Significantly (p ? 0.05) lower organic matter, cation exchange capacity, clay content and soil pH were found at 0 m distances compared to other distances. Highest concentration of total P in soil were recorded at 0 m distances and these concentrations decreased with increasing distances from the brick kilns in most of the sites; whereas available P is significantly lower at 0 m distances than that of other distances. Total and available concentration of S in soil followed the trend 0 m>300 m>800 m>1500 m. Maximum accumulation of P (69.15 mg kg-1) and S (0.14%) in plant was found at 800 m away from the brick kiln.Bangladesh J. Sci. Res. 29(2): 123-131, December-2016


1986 ◽  
Vol 58 (1) ◽  
pp. 1-7
Author(s):  
Raina Niskanen ◽  
Antti Jaakkola

The efficiency of the soil testing method used in Finland for predicting the effective cation-exchange capacity was studied in a material of 430 topsoil samples. The effective cation-exchange capacity was estimated 1) by summation of exchangeable Ca, Mg and acidity displaced by unbuffered 1 M KCI and 2) by summation of exchangeable Ca, Mg, K and Na displaced by neutral 1 M ammonium acetate and exchangeable acidity. In soil testing, Ca, Mg and K were extracted by acid ammonium acetate and soil pH measured in water-suspension. The estimates of the effective CEC were highly correlated and dependent on the clay and organic carbon content and pH(CaCl2) of the soil, the coefficient of multiple determination being over 80 %. Exchangeable Ca was the dominating cation. The proportion of Ca of the effective CEC was about 80 %. Acid ammonium acetate-extractable Ca together with pH(H2O) explained over 80 % of the variation in the effective CEC. For the whole material consisting of mineral soils with great variations in texture, organic carbon content and properties under evaluation, the regression equation predicting the effective CEC (KCI method) was CEC (mval/kg) = 309—56.8pH(H2O) + 0.085Ca(mg/l). Only 16 % of the estimates of the effective CEC calculated with this regression equation deviated more than 15 % from the measured values.


Solid Earth ◽  
2017 ◽  
Vol 8 (4) ◽  
pp. 827-843 ◽  
Author(s):  
Sunday Adenrele Adeniyi ◽  
Willem Petrus de Clercq ◽  
Adriaan van Niekerk

Abstract. Cocoa agroecosystems are a major land-use type in the tropical rainforest belt of West Africa, reportedly associated with several ecological changes, including soil degradation. This study aims to develop a composite soil degradation assessment index (CSDI) for determining the degradation level of cocoa soils under smallholder agroecosystems of southwestern Nigeria. Plots where natural forests have been converted to cocoa agroecosystems of ages 1–10, 11–40, and 41–80 years, respectively representing young cocoa plantations (YCPs), mature cocoa plantations (MCPs), and senescent cocoa plantations (SCPs), were identified to represent the biological cycle of the cocoa tree. Soil samples were collected at a depth of 0 to 20 cm in each plot and analysed in terms of their physical, chemical, and biological properties. Factor analysis of soil data revealed four major interacting soil degradation processes: decline in soil nutrients, loss of soil organic matter, increase in soil acidity, and the breakdown of soil textural characteristics over time. These processes were represented by eight soil properties (extractable zinc, silt, soil organic matter (SOM), cation exchange capacity (CEC), available phosphorus, total porosity, pH, and clay content). These soil properties were subjected to forward stepwise discriminant analysis (STEPDA), and the result showed that four soil properties (extractable zinc, cation exchange capacity, SOM, and clay content) are the most useful in separating the studied soils into YCP, MCP, and SCP. In this way, we have sufficiently eliminated redundancy in the final selection of soil degradation indicators. Based on these four soil parameters, a CSDI was developed and used to classify selected cocoa soils into three different classes of degradation. The results revealed that 65 % of the selected cocoa farms are moderately degraded, while 18 % have a high degradation status. The numerical value of the CSDI as an objective index of soil degradation under cocoa agroecosystems was statistically validated. The results of this study reveal that soil management should promote activities that help to increase organic matter and reduce Zn deficiency over the cocoa growth cycle. Finally, the newly developed CSDI can provide an early warning of soil degradation processes and help farmers and extension officers to implement rehabilitation practices on degraded cocoa soils.


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