scholarly journals Solid contact Zn2+ -selective electrode with low detection limit and stable and reversible potential

2014 ◽  
Vol 12 (3) ◽  
pp. 354-364 ◽  
Author(s):  
Cecylia Wardak
Keyword(s):  
Ionic Liquid ◽  
Detection Limit ◽  
Response Time ◽  
Tap Water ◽  
Direct Determination ◽  
Fast Response ◽  
Indicator Electrode ◽  
Solid Contact ◽  
Internal Reference ◽  
Fast Response Time

AbstractA new solid contact Zn2+ polyvinylchloride membrane sensor with 2-(2-Hydroxy-1-naphthylazo)-1,3,4 -thiadiazole as an ionophore has been prepared. For the electrode construction, ionic liquids, alkylmethylimidazolium chlorides are used as transducer media and as a lipophilic ionic membrane component. The addition of ionic liquid to the membrane phase was found to reduce membrane resistance and determine the potential of an internal reference Ag/AgCl electrode. The electrode with the membrane composition: ionophore: PVC: o-NPOE: ionic liquid in the percentage ratio of (wt.) 1:30:66:3, respectively, exhibited the best performance, having a slope of 29.8 mV decade−1 in the concentration range 3×10−7–1×10−1 M. The detection limit is 6.9×10−8 M. It has a fast response time of 5–7 s and exhibits stable and reproducible potential. It has a fast response time of 5–7 s and exhibits stable and reproducible potential, which does not depend on pH in the range 3.8–8.0. The proposed sensor shows a good and satisfactory selectivity towards Zn2+ ion in comparison with other cations including alkali, alkaline earth, transition and heavy metal ions. It was successfully applied for direct determination of zinc ions in tap water and as an indicator electrode in potentiometric titration of Zn2+ ions with EDTA.

scholarly journals Ionic-Liquid Doping Enables High Transconductance, Fast Response Time, and High Ion Sensitivity in Organic Electrochemical Transistors

2018 ◽  
Vol 31 (2) ◽  
pp. 1805544 ◽  
Author(s):  
Xihu Wu ◽  
Abhijith Surendran ◽  
Jieun Ko ◽  
Oliver Filonik ◽  
Eva M. Herzig ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Response Time ◽  
Fast Response ◽  
Fast Response Time ◽  
High Transconductance ◽  
Organic Electrochemical Transistors

Highly sensitive potentiometric sensors for thorium ions detection using morpholine derivative self-assembled on silver nanoparticles

RSC Advances ◽  
2016 ◽  
Vol 6 (81) ◽  
pp. 77854-77862 ◽  
Author(s):  
Zeinab F. Akl ◽  
Tamer Awad Ali
Keyword(s):  
Silver Nanoparticles ◽  
Detection Limit ◽  
Response Time ◽  
Water Samples ◽  
High Selectivity ◽  
Fast Response ◽  
Potentiometric Sensors ◽  
Fast Response Time ◽  
Highly Sensitive ◽  
Morpholine Derivative

Potentiometric screen-printed electrodes were constructed for Th(iv) determination in water samples. The optimized electrodes exhibited fast response time, wide linear range, low detection limit and high selectivity towards Th(iv) ions.

scholarly journals Highly active and porous single-crystal In2O3 nanosheet for NOx gas sensor with excellent response at room temperature

RSC Advances ◽  
2017 ◽  
Vol 7 (53) ◽  
pp. 33419-33425 ◽  
Author(s):  
Li Sun ◽  
Wencheng Fang ◽  
Ying Yang ◽  
Hui Yu ◽  
Tingting Wang ◽  
...  
Keyword(s):  
Detection Limit ◽  
Response Time ◽  
Single Crystal ◽  
Gas Sensor ◽  
Room Temperature ◽  
Fast Response ◽  
Fast Response Time ◽  
Excellent Response ◽  
Highly Active ◽  
Nox Gas Sensor

Porous single-crystal In2O3 nanosheet was well-designed and prepared through calcination after liquid reflux, then exhibited a distinguished response, fast response time to NOx with good selectivity and low detection limit at room temperature.

scholarly journals Cobalt(II) ion-selective electrode with solid contact

2008 ◽  
Vol 6 (4) ◽  
pp. 607-612 ◽  
Author(s):  
Cecylia Wardak
Keyword(s):  
Detection Limit ◽  
Response Time ◽  
Potentiometric Titration ◽  
Indicator Electrode ◽  
Solid Contact ◽  
Selective Electrode ◽  
Cobalt Ions ◽  
Real Samples ◽  
Nernstian Slope

AbstractA new all plastic sensor for Co2+ ions based on 2-amino-5 (hydroxynaphtyloazo-1′)-1,3,4 thiadiazole (ATIDAN) as ionophore was prepared. The electrode exhibits a low detection limit of 1.5 × 10−6 mol L−1 and almost theoretical Nernstian slope in the activity range 4.0 × 10−6–1 × 10−1 mol L−1 of cobalt ions. The response time of the sensor is less than 10 s and it can be used over a period of 6 months without any measurable divergence in potential. The proposed sensor shows a fairly good selectivity for Co(II) over other metal ions. The electrode was successfully applied for determination of Co2+ in real samples and as an indicator electrode in potentiometric titration of Co2+ ions with EDTA.

scholarly journals High-performance non-enzymatic glucose detection: using a conductive Ni-MOF as an electrocatalyst

2020 ◽  
Vol 8 (25) ◽  
pp. 5411-5415 ◽  
Author(s):  
Yanxia Qiao ◽  
Qian Liu ◽  
Siyu Lu ◽  
Guang Chen ◽  
Shuyan Gao ◽  
...  
Keyword(s):  
Detection Limit ◽  
Response Time ◽  
Blood Serum ◽  
High Performance ◽  
Glucose Sensor ◽  
High Sensitivity ◽  
Fast Response ◽  
Glucose Detection ◽  
Serum Samples ◽  
Fast Response Time

A glucose sensor based on a conductive Ni-MOF as an electrocatalyst exhibits a fast response time, low detection limit, and high sensitivity, and it can also be applied for the detection of glucose in blood serum samples.

scholarly journals Dual-Cation Electrolytes Crosslinked with MXene for High-Performance Electrochromic Devices

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 874
Author(s):  
Soyoung Bae ◽  
Youngno Kim ◽  
Jeong Min Kim ◽  
Jung Hyun Kim
Keyword(s):  
Ionic Conductivity ◽  
Response Time ◽  
Indium Tin Oxide ◽  
High Performance ◽  
Fast Response ◽  
High Ionic Conductivity ◽  
Electrochromic Device ◽  
Fast Response Time ◽  
Coloration Efficiency ◽  
Conduction Pathway

MXene, a 2D material, is used as a filler to manufacture polymer electrolytes with high ionic conductivity because of its unique sheet shape, large specific surface area and high aspect ratio. Because MXene has numerous -OH groups on its surface, it can cause dehydration and condensation reactions with poly(4-styrenesulfonic acid) (PSSA) and consequently create pathways for the conduction of cations. The movement of Grotthuss-type hydrogen ions along the cation-conduction pathway is promoted and a high ionic conductivity can be obtained. In addition, when electrolytes composed of a conventional acid or metal salt alone is applied to an electrochromic device (ECD), it does not bring out fast response time, high coloration efficiency and transmittance contrast simultaneously. Therefore, dual-cation electrolytes are designed for high-performance ECDs. Bis(trifluoromethylsulfonyl)amine lithium salt (LiTFSI) was used as a source of lithium ions and PSSA crosslinked with MXene was used as a source of protons. Dual-Cation electrolytes crosslinked with MXene was applied to an indium tin oxide-free, all-solution-processable ECD. The effect of applying the electrolyte to the device was verified in terms of response time, coloration efficiency and transmittance contrast. The ECD with a size of 5 × 5 cm2 showed a high transmittance contrast of 66.7%, fast response time (8 s/15 s) and high coloration efficiency of 340.6 cm2/C.

scholarly journals Isothiocyanato-Tolanes Based High Birefringence and Fast Response Time Mixtures for Photonic Applications

2006 ◽  
Vol 453 (1) ◽  
pp. 215-226 ◽  
Author(s):  
Sebastian Gauza ◽  
Chien-Hui Wen ◽  
Yang Zhao ◽  
Shin-Tson Wu ◽  
Anna Ziółek ◽  
...  
Keyword(s):  
Response Time ◽  
Fast Response ◽  
Fast Response Time ◽  
High Birefringence

Development of High-Efficiency Zn2SiO4:Mn Thin Films for Flat Panel Cathodoluminescent Displays

1997 ◽  
Vol 471 ◽  
Author(s):  
J. Liu ◽  
D. C. Morton ◽  
M. R. Miller ◽  
Y. Li ◽  
E. W. Forsythe ◽  
...  
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Electrical Conductivity ◽  
Response Time ◽  
Decay Time ◽  
High Efficiency ◽  
Fast Response ◽  
Flat Panel ◽  
Powder Phosphor ◽  
Fast Response Time

ABSTRACTZn2SiO4:Mn thin films were deposited and studied as thin film phosphors for flat panel cathodoluminescent displays. Crystallized films with improved electrical conductivity were obtained after conventional and rapid thermal annealings in a N2 environment at 850Xy11100 °C for 0.25 to 60 minutes. A maximum cathodoluminescent efficiency of 1.3 Lm/W was achieved under dc excitation at 1500 volts. The luminescent emission from these thin films was peaked around 525 nm. The decay time of these films was controlled in the range of 2 to 10 ms by varying the deposition and annealing parameters. The fast response time of these thin films overcomes the long decay limitation of the Zn2SiO4:Mn powder phosphor in practical display applications.

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