scholarly journals Simultaneously Synthesis and Sintering of Carbon Nanofiber Dispersed B4C Nanocomposites by Pulsed Electric-current Pressure Sintering and their Mechanical Properties

2008 ◽  
Vol 55 (8) ◽  
pp. 582-587
Author(s):  
Shingo Nakane ◽  
Yoshihiro Nakayama ◽  
Masaki Kato ◽  
Ken Hirota ◽  
Toshiyuki Nishimura ◽  
...  
2007 ◽  
Vol 534-536 ◽  
pp. 1153-1156 ◽  
Author(s):  
Koji Shimojima ◽  
Hiroyuki Hosokawa ◽  
Takeshi Nakajima ◽  
Masahiko Mizukami ◽  
Yoshiharu Yamamoto

In this paper, we show some experimental results of binder-free WC sintered by Pulsed Electric Current Sintering (PECS) also known as Field Assisted Sintering Technology (FAST). These binder-free WC have extremely high hardness and stiffness. However, these mechanical properties are dependent on the sintering condition, e.g., maximum temperature, applied pressure, etc. We show some relationship between mechanical properties and sintering condition to improve to sinter the binder-free WC.


2012 ◽  
Vol 527 ◽  
pp. 101-106 ◽  
Author(s):  
Erkka Kannisto ◽  
M. Erkin Cura ◽  
Erkki Levänen ◽  
Simo Pekka Hannula

To study the microstructure and mechanical properties of alumina nanocomposites, Al2O3/2.5 vol.% Ni and Al2O3/10 vol.% ZrO2 nanocomposites were consolidated by pulsed electric current sintering (PECS). Fracture toughness was found to increase by 13 % and 16 % respectively compared to reference alumina. Hardness increased slightly in Al2O3/Ni because of a fraction of nickel particles under the critical size (2 following the rule of mixtures. By investigating the results, causes of improved mechanical properties were critically evaluated.


2020 ◽  
Vol 985 ◽  
pp. 202-210
Author(s):  
Ken Hirota ◽  
Hironobu Hirahara ◽  
Kato Masaki ◽  
Toshiyuki Nishimura

Dense [boron carbide (B4C)]/[carbon nanomaterials] composites were synthesized and sintered simultaneously using pulsed electric-current pressure sintering (PECPS) at 2173 K for 6.0×102 s (10 min) under 50 MPa in a vacuum. The starting powders were amorphous B and C nanopowders and nanocarbons. The latter were acid-treated carbon nanofiber CNF and carbon nanotube CNT. The sintered composites were evaluated from the viewpoints of mechanical properties at high temperatures up to ~ 2023 K in inert atmosphere. Thus fabricated composites with 10vol%CNF maintained high bending strength σb around 750 MPa even at 1973 K; this temperature is 100 K higher than that of conventional B4C/CNF composites, and furthermore 600 MPa at 2023 K. These high σb at elevated temperatures might be explained by both the low content of catalytic Fe particles and the rough surface of CNF after the acid-treatment. On the other hand, B4C/CNT composites displayed 770 MPa at 1723 K. The stress-strain curves demonstrate that B4C/CNF composite deformed elastically until 1273 K and plastically up to 1973 K, however, the B4C/CNT composites displayed elastic deformation up to around 1873 K.


2020 ◽  
Vol 96 (4) ◽  
pp. 17-29
Author(s):  
A.G. Prigunova ◽  

The method of quenching-microstructural analysis, the so-called "stop-quenching", was used to study phase transformations during crystallization of the AK7 casting alloy of the Al-Si-Mg system. The alloy is smelted from scrap and waste, therefore it contains a large amount of impurities, including iron, copper. It was found that the formation of the structure of the AK7 alloy is carried out in the course of the following reactions: 1. Р → Аlα. 2. P → α-(Fe, Mn) 3Si2Al15 + Alα. 3. P → β-FeSiAl5 + Alα. 4. P + β-FeSiAl5 → α-(Fe, Mn, Cu)3Si2Al15. 5. P → β-FeSiAl5 + Si + Alα. 6. P → β-FeSiAl5 + α-(Fe, Mn, Cu)3Si2Al15 + Si + Alα. At the last stages of crystallization, eutectics are formed, which include phases with magnesium and copper: Mg2Si, π-FeMg3Si6Al8, W-Cu2Mg8Si6Al and θ-CuAl2. The transformation P → β + Si + Alα is realized both by the mechanism of cooperative growth of the β, Si, and Alα phases, and by the formation of double eutectics: P → Si + Alα and P → β + Alα, which grow simultaneously in the same temperature range from various centers of crystallization. The four-phase eutectic transformation P → β + α + Si + Alα is carried out according to the type of double or triple eutectic reactions: P → Si + Alα; P → α + Alα; P → β + Alα; β + Si + Alα. The main iron-containing phase in the AK7 alloy is the needle-shaped intermetallic compound β-FeSiAl5 - a stress concentrator, which leads to a decrease in mechanical properties. In this work, the neutralization of the harmful effect of iron was carried out by treating the melt with a unipolar pulsed electric current, under the influence of which the cluster structure of the melt changes. During crystallization, instead of β, a branched phase α is formed. The ratio of intermetallic compounds β and α depends on the processing modes. With optimal parameters of density and current frequency, at which the volume fraction of the branched phase α is the largest, the strength of the AK7 alloy increases by 32.1%, the hardness by 16.7%, and the relative elongation by 2.5 times, bringing its mechanical properties closer to the primary alloy AK7h. Keywords: aluminum-silicon alloys, phase transformations, iron-containing intermetallic compounds, growth forms, treatment of the melt with an electric current.


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