scholarly journals Metal-Organic Framework Glass Anode with an Exceptional Cycling-Induced Capacity Enhancement for Lithium Ion Batteries

2021 ◽  
Author(s):  
Chengwei Gao ◽  
Zhenjing Jiang ◽  
Peixing Wang ◽  
Lars Rosgaard Jensen ◽  
Yanfei Zhang ◽  
...  
Keyword(s):  
Pore Structure ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
High Performance ◽  
Storage Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
Great Promise ◽  
Electrochemical Performances ◽  
Metal Organic

<p>Metal organic frameworks (MOFs) hold great promise as high-energy anode materials for next-generation lithium ion batteries (LIBs) due to their tuneable pore structure and abundant reaction sites. However, since the pore structure of crystalline MOFs tends to collapse during lithium ion insertion and extraction, it has been a challenge to develop crystalline MOF-based anodes for high performance lithium ion batteries. Here we report a breakthrough in developing the high-performance MOF anodes. In detail, we have developed the first MOF glass anode, i.e., melt-quenched Cobalt-ZIF-62 glass anode with exceptional electrochemical performances. Compared with its crystalline counterpart, the Co-ZIF-62 glass anode exhibits significantly higher lithium storage capacity (306 mAh g<sup>-1</sup> after 1000 cycles at the current density of 2 A g<sup>-1</sup>), outstanding cycling stability and superior rate performance. Amazingly, the Li-ion storage capacity of the MOF glass anode continuously rises with increasing the number of charge-discharge cycles and even <i>tripled</i> after 1000 cycles. We revealed the possible origin of the unusual cycling-enhanced performances of the MOF glass anode. These superior performances make MOF glasses ideal candidates for anode materials for LIBs. </p>

scholarly journals Metal-Organic Framework Glass Anode with an Exceptional Cycling-Induced Capacity Enhancement for Lithium Ion Batteries

2021 ◽  
Author(s):  
Chengwei Gao ◽  
Zhenjing Jiang ◽  
Peixing Wang ◽  
Lars Rosgaard Jensen ◽  
Yanfei Zhang ◽  
...  
Keyword(s):  
Pore Structure ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
High Performance ◽  
Storage Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
Great Promise ◽  
Electrochemical Performances ◽  
Metal Organic

<p>Metal organic frameworks (MOFs) hold great promise as high-energy anode materials for next-generation lithium ion batteries (LIBs) due to their tuneable pore structure and abundant reaction sites. However, since the pore structure of crystalline MOFs tends to collapse during lithium ion insertion and extraction, it has been a challenge to develop crystalline MOF-based anodes for high performance lithium ion batteries. Here we report a breakthrough in developing the high-performance MOF anodes. In detail, we have developed the first MOF glass anode, i.e., melt-quenched Cobalt-ZIF-62 glass anode with exceptional electrochemical performances. Compared with its crystalline counterpart, the Co-ZIF-62 glass anode exhibits significantly higher lithium storage capacity (306 mAh g<sup>-1</sup> after 1000 cycles at the current density of 2 A g<sup>-1</sup>), outstanding cycling stability and superior rate performance. Amazingly, the Li-ion storage capacity of the MOF glass anode continuously rises with increasing the number of charge-discharge cycles and even <i>tripled</i> after 1000 cycles. We revealed the possible origin of the unusual cycling-enhanced performances of the MOF glass anode. These superior performances make MOF glasses ideal candidates for anode materials for LIBs. </p>

Building sponge-like robust architectures of CNT–graphene–Si composites with enhanced rate and cycling performance for lithium-ion batteries

2015 ◽  
Vol 3 (7) ◽  
pp. 3962-3967 ◽  
Author(s):  
Xiaolei Wang ◽  
Ge Li ◽  
Fathy M. Hassan ◽  
Matthew Li ◽  
Kun Feng ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Materials ◽  
High Performance ◽  
Rate Capability ◽  
Lithium Ion ◽  
Cycling Performance ◽  
Cycling Stability ◽  
Great Promise ◽  
Practical Applications ◽  
Excellent Cycling Stability

High-performance robust CNT–graphene–Si composites are designed as anode materials with enhanced rate capability and excellent cycling stability for lithium-ion batteries. Such an improvement is mainly attributed to the robust sponge-like architecture, which holds great promise in future practical applications.

Novel Fe4-based metal–organic cluster-derived iron oxides/S,N dual-doped carbon hybrids for high-performance lithium storage

Nanoscale ◽  
2021 ◽  
Author(s):  
Lei Hu ◽  
Qiushi Wang ◽  
Xiandong Zhu ◽  
Tao Meng ◽  
Binbin Huang ◽  
...  
Keyword(s):  
Iron Oxide ◽  
Lithium Ion Batteries ◽  
Iron Oxides ◽  
Iron Oxide Nanoparticles ◽  
Anode Materials ◽  
High Performance ◽  
Lithium Ion ◽  
Oxide Nanoparticles ◽  
Lithium Storage ◽  
Metal Organic

Iron oxide nanoparticles embedded in S,N dual-doped carbon through pyrolysis of novel Fe4-based metal–organic clusters are fabricated and utilized as potential anode materials for lithium ion batteries in both half- and full-cells.

Monodisperse tin nanoparticles and hollow tin oxide nanospheres as anode materials for high performance lithium ion batteries

2019 ◽  
Vol 6 (2) ◽  
pp. 473-476 ◽  
Author(s):  
Xixia Zhao ◽  
Wenhui Wang ◽  
Zhen Hou ◽  
Yikang Yu ◽  
Qian Di ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Tin Oxide ◽  
Anode Materials ◽  
High Performance ◽  
Lithium Ion ◽  
Electrochemical Performances ◽  
Tin Nanoparticles ◽  
Colloidal Method

Monodisperse Sn nanoparticles and hollow/amorphous SnOx nanospheres are prepared via a facile colloidal method, and they exhibit good electrochemical performances as anode materials in lithium ion batteries.

Facile synthesis of Fe-MOF/RGO and its application as a high performance anode in lithium-ion batteries

RSC Advances ◽  
2016 ◽  
Vol 6 (36) ◽  
pp. 30763-30768 ◽  
Author(s):  
Yan Jin ◽  
Chongchong Zhao ◽  
Zixu Sun ◽  
Yichao Lin ◽  
Liang Chen ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Lithium Ion Batteries ◽  
Reduced Graphene Oxide ◽  
Anode Materials ◽  
High Performance ◽  
Metal Organic Frameworks ◽  
Lithium Ion ◽  
Facile Synthesis ◽  
Reduced Graphene ◽  
Metal Organic

Metal organic frameworks (MOFs) and reduced graphene oxide (RGO) composite were used as anode materials in lithium-ion batteries (LIBs).

PROPORTIONAL EFFECT IN SbSi/N-DOPED GRAPHENE NANOCOMPOSITE PREPARATION FOR HIGH-PERFORMANCE LITHIUM-ION BATTERIES

2021 ◽  
pp. 2150105
Author(s):  
NARUEPHON MAHAMAI ◽  
THANAPHAT AUTTHAWONG ◽  
AISHUI YU ◽  
THAPANEE SARAKONSRI
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Materials ◽  
High Performance ◽  
Specific Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Morphological Identification ◽  
Synthesis Methods ◽  
Doped Graphene

Lithium-ion batteries (LIBs) have become commercialized technologies for the modern and future world, but commercial batteries using graphite still have a low specific capacity and are concerned with safety issues. Silicon (Si) and antimony (Sb) nanocomposites have the tendency to be synthesized as high-energy-density anode materials which can be a solution for the above-mentioned problems. This work reported the synthesis methods and characterization of Sb and Si composited with nitrogen-doped graphene (SbSi/NrGO) by facile chemical method and thermal treatment. Si was obtained by magnesiothermic reduction of SiO2 derived from rice husk, waste from the agricultural process. To study the phases, particle distributions, and morphologies, all prepared composites were characterized. In this experiment, the phase compositions were confirmed as [Formula: see text]-Si, [Formula: see text]-Si, SiC, Sb, and shifted peaks of expanded C which were caused by NrGO synthesis. Interestingly, a good distribution of Si and Sb particles on the NrGO surface was obtained in 15Sb15Si/NrGO composition. It could be due to appropriate Sb and Si contents on the NrGO surface area in composite materials. Morphological identification of synthesized products represented the Sb and Si particles in nanoscale dispersed on thin wrinkled-paper NrGO. These results suggested that the synthesis method in this paper is appropriate to prepare SbSi/NrGO nanocomposites to be used as high-performance anode materials in high-performance LIBs for advanced applications.

Metal–organic framework derived porous nanostructured Co3O4 as high-performance anode materials for lithium-ion batteries

2020 ◽  
Vol 56 (3) ◽  
pp. 2451-2463
Author(s):  
Yan-Hua Lu ◽  
Jin-Hui Li ◽  
Zhi-Feng Xu ◽  
Jia-Ming Liu ◽  
Sui-Jun Liu ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Materials ◽  
High Performance ◽  
Metal Organic Framework ◽  
Lithium Ion ◽  
Metal Organic ◽  
Organic Framework
Sign in / Sign up

Export Citation Format

Share Document