scholarly journals Effect of Phosphating Temperature on Surface Properties of Manganese Phosphate Coating on HSLA Steel

2020 ◽  
Vol 22 (1) ◽  
pp. 55-61
Author(s):  
Jana Pastorkova ◽  
Martina Jackova ◽  
Filip Pastorek ◽  
Zuzana Florkova ◽  
Juliana Drabikova
Keyword(s):  
Surface Properties ◽  
Electrochemical Impedance ◽  
Hsla Steel ◽  
Electrochemical Corrosion ◽  
High Strength ◽  
Phosphate Coating ◽  
Nacl Solution ◽  
Optimal Temperature ◽  
Manganese Phosphate ◽  
Photo Documentation

A phosphating process modified for a high-strength low-alloy (HSLA) steel was performed at various temperatures and influence on the surface properties of the Domex steel covered by manganese phosphate (MnP) was investigated by electrochemical corrosion tests supported by a photo documentation performed by the SEM. Corrosion measurements were performed in 0.1M NaCl solution at 22±2 °C using electrochemical impedance spectroscopy and potentio-dynamic polarisation in order to obtain thermodynamic and kinetic corrosion characteristics and individual elements of equivalent circuits. It is that a temperature of the phosphating process has a very significant effect on protection properties of the created manganese phosphate coating on the Domex steel and needs to be strictly monitored. According to results of corrosion testing and surface morphology observations, the optimal temperature for the phosphating process on the tested Domex steel was chosen.

scholarly journals Effect of combined surface treatment on quality and electrochemical corrosion properties of manganese phosphate on hsla steel domex 700

2018 ◽  
Vol 62 (2) ◽  
pp. 45-53 ◽  
Author(s):  
Kamil Borko ◽  
F. Pastorek ◽  
Jacková M. Neslušan ◽  
S. Fintová ◽  
B. Hadzima
Keyword(s):  
Corrosion Resistance ◽  
Surface Treatment ◽  
Electrochemical Impedance ◽  
Hsla Steel ◽  
Electrochemical Corrosion ◽  
High Strength Steels ◽  
High Strength ◽  
Corrosion Properties ◽  
Manganese Phosphate ◽  
Pre Treatment

Abstract The actual industrial trend is focused on weight reduction of constructions while preserving strength properties. For this purpose, conventional steel are replaced by high strength steels.. The aim of this study was to evaluate the effects of mechanical surface pre-treatment on corrosion resistance of high strength low alloy steel Domex 700 before and after surface treatment by manganese phosphating. Tested environment was 0,1M NaCl solution. Evaluation of mechanical pre-treatment and phosphating effects on corrosion resistance was realized by electrochemical measurements: potentiodynamic polarization measurements (Tafel analysis) and electrochemical impedance spectroscopy (equivalent circuits). From resulsts it is possible to conclude, that creation of manganese phosphate layer on ground and shot peened steel surface significantly increases the corrosion resistance of Domex 700 steel.

scholarly journals Effect of Surface Pretreatment on Quality and Electrochemical Corrosion Properties of Manganese Phosphate on S355J2 HSLA Steel

Coatings ◽  
2016 ◽  
Vol 6 (4) ◽  
pp. 46 ◽  
Author(s):  
Filip Pastorek ◽  
Kamil Borko ◽  
Stanislava Fintová ◽  
Daniel Kajánek ◽  
Branislav Hadzima
Keyword(s):  
Hsla Steel ◽  
Electrochemical Corrosion ◽  
Corrosion Properties ◽  
Surface Pretreatment ◽  
Manganese Phosphate ◽  
Effect Of Surface

scholarly journals The Influence of Glass Flake and Micaceous Iron Oxide on Electrochemical Corrosion Performance of Waterborne Silicate Coatings in 3.5% NaCl Solution

Coatings ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 833 ◽  
Author(s):  
Xu Zhao ◽  
Yuhong Qi ◽  
Zhanping Zhang ◽  
Kejiao Li
Keyword(s):  
Electrochemical Impedance ◽  
Composite Coatings ◽  
Impact Resistance ◽  
Electrochemical Corrosion ◽  
Nacl Solution ◽  
Corrosion Performance ◽  
Pencil Hardness ◽  
Anticorrosive Pigments ◽  
Comprehensive Comparison ◽  
Glass Flake

Waterborne silicate composite coatings were prepared to replace existing solvent-based coatings for ships. A series of complex coatings were prepared by adding anticorrosive pigments to the silicate resin. Adhesion, pencil hardness, and impact resistance were investigated, and corrosion performance in 3.5% NaCl solution was measured by electrochemical impedance spectroscopy (EIS). The results show that adhesion and impact resistance are high, and that pencil hardness can reach 4H. The curing mechanism for the coatings were investigated by Fourier-transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The mechanism of curing reaction in the studied waterborne silicate paint was found to be different from that reported in the literature. When the coatings were immersed in 3.5% NaCl solution for 8 h, there is only one time constant in the Bode plot, and coating capacitance (Qc) gradually increases while coating resistance (Rc) gradually decreases. Glass flake composite coatings have better corrosion resistance by comprehensive comparison of Qc and Rc.

scholarly journals Effect of surface treatment by sandblasting on the quality and electrochemical corrosion properties of a C-1020 carbon steel used by an Algerian oil company

2019 ◽  
Vol 272 ◽  
pp. 01001
Author(s):  
Nadia HAMMOUDA ◽  
Kamel BELMOKRE
Keyword(s):  
Carbon Steel ◽  
Electrochemical Impedance ◽  
Electrochemical Corrosion ◽  
Surface Preparation ◽  
Nacl Solution ◽  
Corrosion Properties ◽  
Good Surface ◽  
Oil Company ◽  
Mechanical Surface ◽  
Effect Of Surface

The purpose of the different operations under the term surface preparation is to get a clean surface able to be coated. It is essential to adapt this preparation in terms of the metallurgical nature of the substrate, cleanliness, its shape and roughness. Surface preparations especially the operations of sandblasting, polishing, or grinding prove of capital importance. It allows to modify the superficial properties of these materials, after these treatments the surface becomes very active. This paper evaluates the mechanical surface treatments effect by sandblasting (Sa 1.5 and Sa 2.5) on the electrochemical corrosion characteristics of C-1020 carbon steel in 3% NaCl solution electrolyte simulating aggressive sea atmosphere. Investigations are conducted using stationary (free potential "E-t, polarization curves "E-i", the Tafel rights and the Rp) and nonstationary electrochemical tools such as electrochemical impedance. The results obtained allowed us to highlight that sandblasted carbon steel degrades with immersion time because of the roughness of the surface. These results were confirmed by the plot of the electrochemical impedance diagrams, confirming that the process governing kinetics is under charge transfer control. Good protection against corrosion cannot be obtained only with a good surface preparation of the adapted steel.

Electrochemical Behaviors of Die-Cast Mg-4Al-0.4Mn-Xpr (x=0, 1, 4) Alloys in NaCl Solution

2013 ◽  
Vol 690-693 ◽  
pp. 82-88
Author(s):  
Xiao Dong Niu ◽  
Wei Sun ◽  
Xin Qiu ◽  
Jian Meng ◽  
Jian An
Keyword(s):  
Electrochemical Impedance ◽  
Electrochemical Corrosion ◽  
Open Circuit ◽  
Nacl Solution ◽  
Electrochemical Behaviors ◽  
Β Phase ◽  
Die Cast ◽  
Corrosion Behaviors ◽  
Potential Test

The microstructures and electrochemical corrosion behaviors of die-cast Mg-4Al-0.4Mn-xPr (x=0, 1, 4 wt.%) alloys have been investigated. Electrochemical behaviors of all alloys are described by open circuit potential test, potentiodynamic polarization test and electrochemical impedance spectroscope in 3.5 wt.% NaCl solution. The results show that the α-Mg grain is refined and the continuous net β phase appears gradually with increasing the content of Pr in the Mg-4Al-0.4Mn alloys. Moreover, the β phase plays a role of galvanic cathode in AM40 alloy and corrosion barrier in Pr-containing alloys, respectively. Electrochemical measurements show that Pr can improve corrosion resistance of Mg-4Al-0.4Mn alloy in the 3.5 wt.% NaCl solution, and corrosion rate decreases with increasing Pr content.

Study on Corrosion Behaviors of Epoxy Aluminum Coating Immersed in 3.5%NaCl Solution

2014 ◽  
Vol 912-914 ◽  
pp. 338-341 ◽  
Author(s):  
Rui Yan ◽  
Ting Liang ◽  
Hong Chun Ren ◽  
Jin Gu ◽  
Zhuang Zhou Ji
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Osmotic Pressure ◽  
Electrochemical Impedance ◽  
Electrochemical Corrosion ◽  
Aluminum Coating ◽  
Nacl Solution ◽  
Metal Interface ◽  
Electrochemical Corrosion Behavior ◽  
Corrosion Behaviors

Electrochemical corrosion behavior of epoxy aluminum coating immersed in 3.5%NaCl solution was investigated using electrochemical impedance spectroscopy (EIS). SEM was also used to analyze the surface images of coating, and the failure mechanism was discussed as well. The experimental results showed that corrosive species can penetrate into coatings and reach the coating/substrate interface promptly, causing the decrease of electro-resistance and the beginning of electrochemical corrosion at the coatings/metal interface. The coating was compact and continuous at beginning, while the blisters and cavities appeared after corrosion, which were formed osmotic pressure created by corrosion species penetration.

scholarly journals Corrosion and Corrosion Inhibition of High Strength Low Alloy Steel in 2.0 M Sulfuric Acid Solutions by 3-Amino-1,2,3-triazole as a Corrosion Inhibitor

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
El-Sayed M. Sherif ◽  
Adel Taha Abbas ◽  
D. Gopi ◽  
A. M. El-Shamy
Keyword(s):  
Sulfuric Acid ◽  
Corrosion Inhibition ◽  
Polarization Resistance ◽  
Immersion Time ◽  
Electrochemical Impedance ◽  
Hsla Steel ◽  
Electrochemical Techniques ◽  
High Strength ◽  
X Ray ◽  
Sulfuric Acid Solutions

The corrosion and corrosion inhibition of high strength low alloy (HSLA) steel after 10 min and 60 min immersion in 2.0 M H2SO4solution by 3-amino-1,2,4-triazole (ATA) were reported. Several electrochemical techniques along with scanning electron microscopy (SEM) and energy dispersive X-ray (EDS) were employed. Electrochemical impedance spectroscopy indicated that the increase of immersion time from 10 min to 60 min significantly decreased both the solution and polarization resistance for the steel in the sulfuric acid solution. The increase of immersion time increased the anodic, cathodic, and corrosion currents, while it decreased the polarization resistance as indicated by the potentiodynamic polarization measurements. The addition of 1.0 mM ATA remarkably decreased the corrosion of the steel and this effect was found to increase with increasing its concentration to 5.0 mM. SEM and EDS investigations confirmed that the inhibition of the HSLA steel in the 2.0 M H2SO4solutions is achieved via the adsorption of the ATA molecules onto the steel protecting its surface from being dissolved easily.

Corrosion behavior of high strength low alloy HSLA steel in 35 wt% NaCl solution containing diethylenetriamine DETA as corrosion inhibitor

2018 ◽  
Author(s):  
Abdul Shakoor ◽  
Khuram Shahzad ◽  
Mostafa H. R Sliem ◽  
Fareeha Ubaid ◽  
Himyan M Akbar ◽  
...  
Keyword(s):  
Corrosion Inhibitor ◽  
Corrosion Behavior ◽  
Hsla Steel ◽  
High Strength ◽  
Nacl Solution

scholarly journals Electrochemical Corrosion Behavior of Ni-Fe-Co-P Alloy Coating Containing Nano-CeO2 Particles in NaCl Solution

Materials ◽  
2019 ◽  
Vol 12 (16) ◽  
pp. 2614 ◽  
Author(s):  
Xiuqing Fu ◽  
Wenke Ma ◽  
Shuanglu Duan ◽  
Qingqing Wang ◽  
Jinran Lin
Keyword(s):  
Composite Coating ◽  
Corrosion Behavior ◽  
Electrochemical Impedance ◽  
Electrochemical Corrosion ◽  
Alloy Coating ◽  
Charge Transfer Resistance ◽  
Corrosion Mechanism ◽  
Nacl Solution ◽  
Transfer Resistance ◽  
Electrochemical Corrosion Behavior

In order to study the effect of nano-CeO2 particles doping on the electrochemical corrosion behavior of pure Ni-Fe-Co-P alloy coating, Ni-Fe-Co-P-CeO2 composite coating is prepared on the surface of 45 steel by scanning electrodeposition. The morphology, composition, and phase structure of the composite coating are analyzed by means of scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). The corrosion behavior of the coatings with different concentrations of nano-CeO2 particles in 50 g/L NaCl solution is studied by Tafel polarization curve and electrochemical impedance spectroscopy. The corrosion mechanism is discussed. The experimental results show that the obtained Ni-Fe-Co-P-CeO2 composite coating is amorphous, and the addition of nano-CeO2 particles increases the mass fraction of P. With the increase of the concentration of nano-CeO2 particles in the plating solution, the surface flatness of the coating increases. The surface of Ni-Fe-Co-P-1 g/L CeO2 composite coating is uniform and dense, and its self-corrosion potential is the most positive; the corrosion current and corrosion rate are the smallest, and the charge transfer resistance is the largest, showing the best corrosion resistance.

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