scholarly journals The Petrology and  Genesis of Silicic  Magmas in the  Kermadec Arc

2021 ◽  
Author(s):  
◽  
Simon James Barker
Keyword(s):  
Subduction Zone ◽  
Structural Changes ◽  
Mineral Chemistry ◽  
Silicic Magma ◽  
Small Scale ◽  
Mafic Enclaves ◽  
Compositional Range ◽  
Dominant Process ◽  
Wide Compositional Range ◽  
Silicic Magmas

<p>Recent work has shown that silicic volcanism can be abundant in intra-oceanic subduction settings, and is often associated with large explosive caldera-forming eruptions. Several major petrogenetic questions arise over the origin and eruption of large amounts of silicic magma at these relatively simple subduction settings. This study has investigated the geochemistry of pyroclasts collected from four volcanoes along the Kermadec arc, a young (<2 Myr) oceanic subduction zone in the southwest Pacific. Raoul, Macauley and a newly discovered volcano (here informally named 'New volcano') in the northern Kermadec arc, and Healy volcano in the southern Kermadec arc have all erupted dacitic to rhyolitic pumice within the last 10 kyr. For Raoul, New volcano and Healy, whole rock major element compositions fall with a limited compositional range. In contrast, pumice dredged from around Macauley caldera covers a wide compositional range indicating that there have been multiple silicic eruptions, not just the Sandy Bay Tephra exposed on Macauley Island. Distinctive crystal populations in both pumice samples and plutonic xenoliths suggest that many of the crystals did not grow in the evolved magmas, but were mixed in from other sources including gabbros and tonalites. Such open system mixing is ubiquitous in magmas from the four Kermadec volcanoes studied here. Silicic magmas, co-eruptive mafic enclaves and previously erupted basalts show sub-parallel REE patterns, and crystal composition and zonation suggests that mafic and silicic magmas have a strong genetic affiliation. Examination of whole rock, glass and mineral chemistry reveals that evolved magmas can be generated at each volcano through 60-75% crystal fractionation of a basaltic parent. These findings are not consistent with silicic magma generation via crustal anatexis, as previously suggested for the Kermadec arc. Although crystallisation is the dominant process driving melt evolution in the Kermadec volcanoes, the magmatic systems are open to contributions from both newly arriving melts and wholly crystalline plutonic bodies. Such processes occur in variable proportions between magma batches, and are largely reflected by small scale chemical variations between eruption units. Larger scale chemical trends reflect the position of the volcanoes along the arc, which in turn may reflect structural changes in the subduction zone and variations in sediment influx.</p>

scholarly journals The Petrology and  Genesis of Silicic  Magmas in the  Kermadec Arc

2021 ◽  
Author(s):  
◽  
Simon James Barker
Keyword(s):  
Subduction Zone ◽  
Structural Changes ◽  
Mineral Chemistry ◽  
Silicic Magma ◽  
Small Scale ◽  
Mafic Enclaves ◽  
Compositional Range ◽  
Dominant Process ◽  
Wide Compositional Range ◽  
Silicic Magmas

<p>Recent work has shown that silicic volcanism can be abundant in intra-oceanic subduction settings, and is often associated with large explosive caldera-forming eruptions. Several major petrogenetic questions arise over the origin and eruption of large amounts of silicic magma at these relatively simple subduction settings. This study has investigated the geochemistry of pyroclasts collected from four volcanoes along the Kermadec arc, a young (<2 Myr) oceanic subduction zone in the southwest Pacific. Raoul, Macauley and a newly discovered volcano (here informally named 'New volcano') in the northern Kermadec arc, and Healy volcano in the southern Kermadec arc have all erupted dacitic to rhyolitic pumice within the last 10 kyr. For Raoul, New volcano and Healy, whole rock major element compositions fall with a limited compositional range. In contrast, pumice dredged from around Macauley caldera covers a wide compositional range indicating that there have been multiple silicic eruptions, not just the Sandy Bay Tephra exposed on Macauley Island. Distinctive crystal populations in both pumice samples and plutonic xenoliths suggest that many of the crystals did not grow in the evolved magmas, but were mixed in from other sources including gabbros and tonalites. Such open system mixing is ubiquitous in magmas from the four Kermadec volcanoes studied here. Silicic magmas, co-eruptive mafic enclaves and previously erupted basalts show sub-parallel REE patterns, and crystal composition and zonation suggests that mafic and silicic magmas have a strong genetic affiliation. Examination of whole rock, glass and mineral chemistry reveals that evolved magmas can be generated at each volcano through 60-75% crystal fractionation of a basaltic parent. These findings are not consistent with silicic magma generation via crustal anatexis, as previously suggested for the Kermadec arc. Although crystallisation is the dominant process driving melt evolution in the Kermadec volcanoes, the magmatic systems are open to contributions from both newly arriving melts and wholly crystalline plutonic bodies. Such processes occur in variable proportions between magma batches, and are largely reflected by small scale chemical variations between eruption units. Larger scale chemical trends reflect the position of the volcanoes along the arc, which in turn may reflect structural changes in the subduction zone and variations in sediment influx.</p>

Structural changes in uterine tissues after uterine artery embolization in patients with leiomyoma complicated by uterine bleeding

GYNECOLOGY ◽  
2018 ◽  
Vol 20 (1) ◽  
pp. 78-82
Author(s):  
G P Titova ◽  
M M Damirov ◽  
L S Kokov ◽  
O N Oleynikova ◽  
G E Belozerov
Keyword(s):  
Uterine Artery Embolization ◽  
Uterine Artery ◽  
Structural Changes ◽  
Morphological Changes ◽  
Uterine Bleeding ◽  
Small Scale ◽  
Artery Embolization ◽  
Vessel Occlusion ◽  
Uterine Arteries ◽  
Uterine Tumors

Uterine leiomyoma (UL) is often complicated by the development of uterine bleeding. In urgent gynecology for the implementation of endovascular hemostasis, uterine artery embolization (UAE) is used. Performing UAE allows to stop and/or significantly reduce the intensity of bleeding and prepare a patient for surgical intervention. At the same time, the morphological changes that occur in uterine tissues in operated UL patients after performing the UAE are not studied. The aim was to study the peculiarities of pathomorphological changes in uterine tumors and tissues in operated UL patients complicated by uterine bleeding after performing UAE. Material and methods. The results of morphological changes appearing in tumors and tissues of the uterus in 39 operated UL patients, who were used for stopping uterine bleeding, were analyzed. Results. After applying different types of embolizing agents in macroscopic study of the uterus, signs of ischemia of its tissues were revealed, and the most pronounced disorders were detected in the UL nodes. Morphologically it was established that UAE microemboli resulted in vessel occlusion with increasing thrombosis in their distal sections. UAE was not accompanied by occlusal occlusion of the arteries and resulted in small-scale necrosis of the tumor with complete regeneration of the endometrium. Conclusions. The results of the morphological study showed that after the UAE was performed, the myomatous nodes underwent dystrophic, necrobiotic and necrotic changes. Depending on the nature of occlusion of the uterine arteries, various variants of necrosis (scale and completeness of the process) developed in the tumor tissue, which was aseptic in nature.

scholarly journals Numerical models of slab migration in continental collision zones

Solid Earth ◽  
2012 ◽  
Vol 3 (2) ◽  
pp. 293-306 ◽  
Author(s):  
V. Magni ◽  
J. van Hunen ◽  
F. Funiciello ◽  
C. Faccenna
Keyword(s):  
Subduction Zone ◽  
Plate Tectonics ◽  
Numerical Models ◽  
Continental Collision ◽  
Force Balance ◽  
Small Scale ◽  
Dip Angle ◽  
External Forces ◽  
Stress Dependent ◽  
Subduction System

Abstract. Continental collision is an intrinsic feature of plate tectonics. The closure of an oceanic basin leads to the onset of subduction of buoyant continental material, which slows down and eventually stops the subduction process. In natural cases, evidence of advancing margins has been recognized in continental collision zones such as India-Eurasia and Arabia-Eurasia. We perform a parametric study of the geometrical and rheological influence on subduction dynamics during the subduction of continental lithosphere. In our 2-D numerical models of a free subduction system with temperature and stress-dependent rheology, the trench and the overriding plate move self-consistently as a function of the dynamics of the system (i.e. no external forces are imposed). This setup enables to study how continental subduction influences the trench migration. We found that in all models the slab starts to advance once the continent enters the subduction zone and continues to migrate until few million years after the ultimate slab detachment. Our results support the idea that the advancing mode is favoured and, in part, provided by the intrinsic force balance of continental collision. We suggest that the advance is first induced by the locking of the subduction zone and the subsequent steepening of the slab, and next by the sinking of the deepest oceanic part of the slab, during stretching and break-off of the slab. These processes are responsible for the migration of the subduction zone by triggering small-scale convection cells in the mantle that, in turn, drag the plates. The amount of advance ranges from 40 to 220 km and depends on the dip angle of the slab before the onset of collision.

scholarly journals The Ocean’s Elevator: Evolution of the Air-Seawater Interface During a Small-Scale Algal Bloom

2020 ◽  
Author(s):  
Mickey Rogers ◽  
Jennifer Neal ◽  
Ankur Saha ◽  
Abdullah Algarni ◽  
Thomas Hill ◽  
...  
Keyword(s):  
Algal Blooms ◽  
Structural Changes ◽  
Organic Molecules ◽  
Algal Bloom ◽  
Small Scale ◽  
Surface Imaging ◽  
Brewster Angle Microscopy ◽  
Surface Active ◽  
Marine Algal ◽  
Late Stages

We explore in situ the surface properties of marine algal blooms of diatom monocultures by utilizing surface techniques of Brewster angle microscopy (BAM) imaging, vibrational sum frequency generation spectroscopy (SFG), and infrared reflection absorption spectroscopy (IRRAS). Over the course of the bloom, the marine algae produce surface-active biogenic molecules that temporally partition to the topmost interfacial layers and are selectively probed through surface imaging and spectroscopic measurements. BAM images show morphological structural changes and heterogeneity in the interfacial films with increasing density of surface-active biogenic molecules. Film thickness calculations quantified the average surface thickness over time. The image results reveal an ~5 nm thick surface region in the late stages of the bloom which correlates to typical sea surface nanolayer thicknesses. Our surface-specific SFG spectroscopy results show significant diminishing in the intensity of the dangling OH bond of surface water molecules consistent with organic molecules partitioning and replacing water at the air-seawater interface as the algal bloom progresses. Interestingly, we observe a new broad peak appear between 3500 cm<sup>-1</sup> to 3600 cm<sup>-1</sup> in the late stages of the bloom that is attributed to weak hydrogen bonding interactions of water to the surface-active biogenic matter. IRRAS confirms the presence of organic molecules at the surface as we observe increasing intensity of vibrational alkyl modes and the appearance of a proteinaceous amide band. Our work shows the often overlooked but vast potential of tracking changes in the interfacial regime of small-scale laboratory marine algal blooms. By coupling surface imaging and vibrational spectroscopies to complex, time-evolving, marine-relevant systems, we provide additional insight into unraveling the temporal complexity of sea spray aerosol compositions.

scholarly journals Pain and Excitement of Taking Technology to the Market

2004 ◽  
Vol 29 (4) ◽  
pp. 57-68 ◽  
Author(s):  
R Sunder
Keyword(s):  
Structural Changes ◽  
High Technology ◽  
Integrated System ◽  
Small Scale ◽  
Free Enterprise ◽  
Test Quality ◽  
Strength Performance ◽  
Playing Field ◽  
System Solution ◽  
Manufactured Products

With economic liberalization, the Indian industry has finally emerged from the shell of the license raj. It now sees investment in R&D as a means to survive and succeed in the long run. It has acquired an appetite for quality control and productivity in order to be competitive. To evaluate quality, manufactured products are tested for strength, performance, and durability in order to meet customer demands and, often, safety legislation. As a developer and manufacturer of technology used in testing, Bangalore Integrated System Solution (BiSS) has first-hand experience of the rapid changes in the market environment and what they mean for high technology manufactured products. As an entrepreneur who set up BiSS, the author experienced the challenges and tribulations of attempting to meet exacting requirements of test quality and performance, matching global standards. If the BiSS experience is any indication, the time and environment are right for scientists and technologists to consider the option of entrepreneurship. The institutional support for taking technology to the market is woefully wanting. Even so, potential rewards justify the risk of personal initiative to build entrepreneurial linkages with industry in seeking orders to develop and supply the technology-intensive hardware and software solutions. As manufacturing moves to India, the demand for local technology is on the rise as global players see the importance of local support to their endeavour. This opens a continuous stream of opportunity for local innovators. It carries the potential for future support in product development thereby adding value at the intellectual level. Finally, global players may see reason in seeking Indian technology to meet their requirements back home as well as for their projects in third countries. Today, cost drives decisions to move manufacturing to India. The same rationale can move development to India and, eventually, to outsource technology itself. For a country of India's size, strength, and stature, this is one more path to technological excellence tending to global leadership. For the scientist-entrepreneur, this is a unique opportunity to subject new concepts and technology to trial by fire at the hands of demanding customers in the industry. For the numerous national laboratories, such entrepreneurs can serve as useful partners in taking available technology to the market while at the same time providing direction to future marketable research and development. Thus, this paper concludes with the following observations: Globalization of the economy and the movement of manufacturing into India provide endless opportunity for entrepreneurship driven by high technology. Though the economy has seen significant structural changes over the past decade, obstacles still remain in the path of free enterprise. Government policy needs to be fine tuned in order to create a level playing field for the ‘small-scale innovator.’ Financial backing for innovative entrepreneurship is woefully inadequate in our country, perhaps, because the system carries an inherent skepticism about local capability. Similar doubts persist in large corporates that are unwilling to risk local procurement of high technology products. Scientists and technologists attempting to take their technology to the market are likely to experience professional enrichment by way of putting their concepts and assumptions to the acid test of a competitive and demanding marketplace.

Thermoelectric Properties of Ru2Si3-Based Chimney-Ladder Phases

2007 ◽  
Vol 561-565 ◽  
pp. 463-466 ◽  
Author(s):  
Kyosuke Kishida ◽  
Akira Ishida ◽  
Katsushi Tanaka ◽  
Haruyuki Inui
Keyword(s):  
Crystal Structures ◽  
Thermoelectric Properties ◽  
Electron Concentration ◽  
Valence Electron ◽  
Valence Electron Concentration ◽  
Compositional Range ◽  
Wide Compositional Range ◽  
P Type ◽  
Semiconducting Behavior

The variations of the crystal structures and thermoelectric properties of the Ru1-xRexSiy chimney-ladder phases were studied as a function of the Re concentration. A series of chimney-ladder phases with a compositional formula of Ru1-xRexSi1.539+0.178x are formed in a wide compositional range, 0.14 ≤ x ≤ 0.76. The composition of the chimney-ladder phase is systematically deviated from the idealized composition satisfying the valence electron concentration rule: VEC=14. Measurements of thermoelectric properties reveal that the chimney-ladder phases exhibit n-type semiconducting behavior at low Re concentrations and p-type semiconducting behavior at high Re concentrations, which are well consistent with the prediction based on the deviation of the composition of the chimney-ladder phase from the idealized composition.

scholarly journals Geochemical and Sr–Nd isotopic features of the Zaro volcanic complex: insights on the magmatic processes triggering a small-scale prehistoric eruption at Ischia island (south Italy)

2020 ◽  
Vol 109 (8) ◽  
pp. 2829-2849
Author(s):  
C. Pelullo ◽  
G. Cirillo ◽  
R. S. Iovine ◽  
I. Arienzo ◽  
M. Aulinas ◽  
...  
Keyword(s):  
Risk Mitigation ◽  
Mafic Magma ◽  
Small Scale ◽  
Volcanic Complex ◽  
Magmatic System ◽  
Mafic Enclaves ◽  
South Italy ◽  
Ischia Island ◽  
Magmatic Processes ◽  
Trace Element Contents

Abstract The prehistoric (< 7 ka) Zaro eruption at Ischia island (Southern Italy) produced a lava complex overlaying a pyroclastic deposit. Although being of low energy, the Zaro eruption might have caused casualties among the neolithic population that inhabited that area of Ischia, and damages to their settlements. A similar eruption at Ischia with its present-day population would turn into a disaster. Therefore, understanding the magmatic processes that triggered the Zaro eruption would be important for volcanic hazard assessment and risk mitigation, so as to improve a knowledge that can be applied to other active volcanic areas worldwide. The main Zaro lava body is trachyte and hosts abundant mafic and felsic enclaves. Here all juvenile facies have been fully characterized from petrographic, geochemical and isotopic viewpoints. The whole dataset (major and trace element contents; Sr–Nd isotopic composition) leads to rule out a genetic link by fractional crystallization among the variable facies. Thus, we suggest that the Zaro mafic enclaves could represent a deep-origin mafic magma that mingled/mixed with the main trachytic one residing in the Ischia shallow magmatic system. The intrusion of such a mafic magma into a shallow reservoir filled by partly crystallized, evolved magma could have destabilized the magmatic system presumably acting as a rapid eruption trigger. The resulting processes of convection, mixing and rejuvenation have possibly played an important role in pre- and syn-eruptive phases also in several eruptions of different sizes in the Neapolitan area and elsewhere in the world.

scholarly journals Post-rendezvous radar properties of comet 67P/CG from the Rosetta Mission: understanding future Earth-based radar observations and the dynamical evolution of comets

2019 ◽  
Vol 489 (2) ◽  
pp. 1667-1683 ◽  
Author(s):  
Essam Heggy ◽  
Elizabeth M Palmer ◽  
Alain Hérique ◽  
Wlodek Kofman ◽  
M Ramy El-Maarry
Keyword(s):  
Large Scale ◽  
Structural Changes ◽  
Dynamical Evolution ◽  
Textural Properties ◽  
Building Blocks ◽  
Cometary Nucleus ◽  
Small Scale ◽  
Small Bodies ◽  
Radar Observations ◽  
Comet 67P

ABSTRACT Radar observations provide crucial insights into the formation and dynamical evolution of comets. This ability is constrained by our knowledge of the dielectric and textural properties of these small-bodies. Using several observations by Rosetta as well as results from the Earth-based Arecibo radio telescope, we provide an updated and comprehensive dielectric and roughness description of Comet 67P/CG, which can provide new constraints on the radar properties of other nuclei. Furthermore, contrary to previous assumptions of cometary surfaces being dielectrically homogeneous and smooth, we find that cometary surfaces are dielectrically heterogeneous ( εr′≈1.6–3.2), and are rough at X- and S-band frequencies, which are widely used in characterization of small-bodies. We also investigate the lack of signal broadening in CONSERT observations through the comet head. Our results suggest that primordial building blocks in the subsurface are either absent, smaller than the radar wavelength, or have a weak dielectric contrast (Δ εr′). To constrain this ambiguity, we use optical albedo measurements by the OSIRIS camera of the freshly exposed subsurface after the Aswan cliff collapse. We find that the hypothetical subsurface blocks should have |Δ εr′|≳0.15, setting an upper limit of ∼ 1 m on the size of 67P/CG's primordial building blocks if they exist. Our analysis is consistent with a purely thermal origin for the ∼ 3 m surface bumps on pit walls and cliff-faces, hypothesized to be high-centred polygons formed from fracturing of the sintered shallow ice-bearing subsurface due to seasonal thermal expansion and contraction. Potential changes in 67P/CG's radar reflectivity at these at X- and S-bands can be associated with large-scale structural changes of the nucleus rather than small-scale textural ones. Monitoring changes in 67P/CG's radar properties during repeated close-approaches via Earth-based observations can constrain the dynamical evolution of its cometary nucleus.

The Advocate ophiolite mantle, Baie Verte, Newfoundland: regional correlations and evidence for metasomatismGeological Survey of Canada, Earth Sciences Sector, Contribution 20090211.

2010 ◽  
Vol 47 (3) ◽  
pp. 237-253 ◽  
Author(s):  
Jean H. Bédard ◽  
Monica Escayola
Keyword(s):  
Earth Sciences ◽  
Subduction Zone ◽  
Mineral Chemistry ◽  
Major Elements ◽  
Apparent Absence ◽  
Gold Exploration ◽  
Metasomatic Agent ◽  
Exploration Target ◽  
Chemical Signatures

Mantle rocks of the Advocate ophiolite near Flatwater Pond (Baie Verte, Newfoundland) are dominated by harzburgite tectonites, which are extensively converted to listvenite along the Baie Verte Road fault and represent a potential gold exploration target. Most Advocate harzburgites have forsteritic olivine (Fo90.5 to Fo93) and Cr-spinels, with Cr# (= 100Cr/(Cr + Al)) between 52 and 64 and Mg# (= 100Mg/(Mg + Fe2+)) between 56 and 68. These mineral chemical signatures, together with high whole-rock MgO (46%–48%), low Al2O3 (<1%), and TiO2 (<0.003%), imply the Advocate harzburgites are refractory residues after ca. 25%–35% melting. Cr-spinel compositions of Advocate mantle rocks overlap with Cr-spinels from the mantle rocks of the Point Rousse and Betts Cove ophiolites, with Mg# higher than those of Bay of Islands or Thetford Mines mantle Cr-spinels. Although refractory in terms of major elements and mineral chemistry, Advocate harzburgites contain high La–Ce–Pr–Pb–Nd–Sm–Zr contents suggestive of pervasive metasomatism. Similar geochemical signatures occur in all ophiolitic mantle rocks from the Baie Verte Peninsula examined so far. The enrichments are not consistent with supra-subduction zone syn-melting metasomatism as observed in other Appalachian ophiolites. The apparent absence of visible metasomatic channels in most outcrops suggests that metasomatism occurred before obduction by diffuse percolation, but the nature and origin of the metasomatic agent remain speculative. The similarities of mineral and whole-rock geochemistry imply that all mantle rocks from Baie Verte ophiolites are correlative and may represent remnants of a single obducted slab.

Mafic-silicic layered intrusions: the role of basaltic injections on magmatic processes and the evolution of silicic magma chambers

1996 ◽  
Vol 87 (1-2) ◽  
pp. 233-242 ◽  
Author(s):  
R. A. Wiebe
Keyword(s):  
Basaltic Magma ◽  
Mafic Magma ◽  
Silicic Magma ◽  
Granitic Magma ◽  
Magma Chambers ◽  
Mechanical Mixing ◽  
Diffusive Convection ◽  
Type Granite ◽  
Mafic Magmas ◽  
Silicic Magmas

ABSTRACT:Plutonic complexes with interlayered mafic and silicic rocks commonly contain layers (1–50 m thick) with a chilled gabbroic base that grades upwards to dioritic or silicic cumulates. Each chilled base records the infusion of new basaltic magma into the chamber. Some layers preserve a record of double-diffusive convection with hotter, denser mafic magma beneath silicic magma. Processes of hybridisation include mechanical mixing of crystals and selective exchange of H2O, alkalis and isotopes. These effects are convected away from the boundary into the interiors of both magmas. Fractional crystallisation aad replenishment of the mafic magma can also generate intermediate magma layers highly enriched in incompatible elements.Basaltic infusions into silicic magma chambers can significantly affect the thermal and chemical character of resident granitic magmas in shallow level chambers. In one Maine pluton, they converted resident I-type granitic magma into A-type granite and, in another, they produced a low-K (trondhjemitic) magma layer beneath normal granitic magma. If comparable interactions occur at deeper crustal levels, selective thermal, chemical and isotopic exchange should probably be even more effective. Because the mafic magmas crystallise first and relatively rapidly, silicic magmas that rise away from deep composite chambers may show little direct evidence (e.g. enclaves) of their prior involvement with mafic magma.

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