scholarly journals Mineralogy and petrology of the Salitre I phoscorite-carbonatite-alkaline complex, Brazil

Keyword(s):  
Author(s):  
Jens Konnerup-Madsen

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Konnerup-Madsen, J. (2001). A review of the composition and evolution of hydrocarbon gases during solidification of the Ilímaussaq alkaline complex, South Greenland. Geology of Greenland Survey Bulletin, 190, 159-166. https://doi.org/10.34194/ggub.v190.5187 _______________ Fluid inclusions in minerals from agpaitic nepheline syenites and hydrothermal veins in the Ilímaussaq complex and in similar agpaitic complexes on the Kola Peninsula, Russia, are dominated by hydrocarbon gases (predominantly methane) and hydrogen. Such volatile compositions differ considerably from those of most other igneous rocks and their formation and entrapment in minerals reflects low oxygen fugacities and a wide range of crystallisation temperatures extending to a low-temperature solidus. Their composition reflects initial low carbon contents and high water contents of the magma resulting in the exsolution of a waterrich CO2–H2O dominated vapour phase. Fractionation of chlorides into the vapour phase results in high salinities and the subsequent development of a heterogeneous vapour phase with a highly saline aqueous-rich fraction and a methane-dominated fraction, with preferential entrapment of the latter, possibly due to different wetting characteristics. The light stable isotope compositions support an abiogenic origin for the hydrocarbons in agpaitic nepheline syenite complexes.


Author(s):  
Ole V. Petersen ◽  
Alexander P. Khomyakov ◽  
Henning Sørensen

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Petersen, O. V., Khomyakov, A. P., & Henning. (2001). Natrophosphate from the Ilímaussaq alkaline complex, South Greenland. Geology of Greenland Survey Bulletin, 190, 139-141. https://doi.org/10.34194/ggub.v190.5184 _______________ The rare mineral natrophosphate has been identified for the first time in the Ilímaussaq alkaline complex in a drill core from the Kvanefjeld area. It occurs sparsely in zoned veinlets with cores of natrophosphate and borders of fibrous trona. The natrophosphate is more or less smoky, transparent and unaltered. The refractive index n = 1.448 ± 0.005 is low compared to that given for the material from the type locality, Khibina alkaline complex, Kola Peninsula; the unit cell parameter a = 27.76 ± 0.05 Å is in excellent agreement with that given for the material from the type locality. The veins occur in hyper-agpaitic naujakasite lujavrite; villiaumite is an associated mineral. Only a few water-soluble minerals have so far been found in the Ilímaussaq alkaline complex compared to the wealth of such minerals in the Khibina and Lovozero alkaline complexes. This is possibly at least partly due to lack of necessary precautions during sampling.


2014 ◽  
Vol 61 ◽  
pp. 175-191 ◽  
Author(s):  
Dmitry Konopelko ◽  
Georgy Biske ◽  
Reimar Seltmann ◽  
Sergey V. Petrov ◽  
Elena Lepekhina

Lithos ◽  
2021 ◽  
pp. 106330
Author(s):  
Vincenza Guarino ◽  
Michele Lustrino ◽  
Alberto Zanetti ◽  
Colombo C.G. Tassinari ◽  
Excelso Ruberti ◽  
...  

2020 ◽  
Vol 12 (1) ◽  
pp. 85-116 ◽  
Author(s):  
Kirtikumar Randive ◽  
Tushar Meshram

AbstractCarbonatites are carbonate-rich rocks of igneous origin. They form the magmas of their own that are generated in the deep mantle by low degrees of partial melting of carbonated peridotite or eclogite source rocks. They are known to occur since the Archaean times till recent, the activity showing gradual increase from older to younger times. They are commonly associated with alkaline rocks and be genetically related with them. They often induce metasomatic alteration in the country rocks forming an aureole of fenitization around them. They are host for economically important mineral deposits including rare metals and REE. They are commonly associated with the continental rifts, but are also common in the orogenic belts; but not known to occur in the intra-plate regions. The carbonatites are known to occur all over the globe, majority of the occurrences located in Africa, Fenno-Scandinavia, Karelian-Kola, Mongolia, China, Australia, South America and India. In the Indian Subcontinent carbonatites occur in India, Pakistan, Afghanistan and Sri Lanka; but so far not known to occur in Nepal, Bhutan, Bangladesh and Myanmar. This paper takes an overview of the carbonatite occurrences in the Indian Subcontinent in the light of recent data. The localities being discussed in detail cover a considerable time range (>2400 Ma to <0.6 Ma) from India (Hogenakal, Newania, Sevathur, Sung Valley, Sarnu-Dandali and Mundwara, and Amba Dongar), Pakistan (Permian Koga and Tertiary Pehsawar Plain Alkaline Complex which includes Loe Shilman, Sillai Patti, Jambil and Jawar), Afghanistan (Khanneshin) and Sri Lanka (Eppawala). This review provide the comprehensive information about geochemical characteristics and evolution of carbonatites in Indian Subcontinent with respect to space and time.


1995 ◽  
Vol 32 (3) ◽  
pp. 273-280 ◽  
Author(s):  
S. L. Kamo ◽  
T. E. Krogh ◽  
P. S. Kumarapeli

U–Pb baddeleyite and zircon ages for three diabase dykes from widely spaced localities within the Grenville dyke swarm indicate a single age of emplacement at [Formula: see text] Ma. The 700 km long Grenville dyke swarm, located in the southeastern part of the Canadian Shield, was emplaced syntectonically with the development of the Ottawa graben. This graben may represent a plume-generated lapetan failed arm that developed at the onset of the breakup of Laurentia. Other precisely dated lapetan rift-related units, such as the Callander Alkaline Complex and the Tibbit Hill Formation volcanic rocks, indicate a protracted 36 Ma period of rifting and magmatism prior to volcanism along this segment of the lapetan margin. The age of the Grenville dykes is the youngest in a progression of precisely dated mafic magmatic events from the 723 Ma Franklin dykes and sills to the 615 Ma Long Range dykes, along the northern and northeastern margins of Laurentia, respectively. Thus, the age for these dykes represents a key time marker for continental breakup that preceded the formation of the Iapetus ocean.


2014 ◽  
Vol 1 (2) ◽  
pp. 1465-1507
Author(s):  
V. C. Oliveira ◽  
D. P. Sales ◽  
V. C. F. Barbosa ◽  
L. Uieda

Abstract. We have developed a fast total-field anomaly inversion to estimate the magnetization direction of multiple sources with approximately spherical shape and known centres. Our method can be applied to interpret multiple sources with different magnetization directions. It neither requires the prior computation of any transformation like reduction to the pole nor the use of regularly spaced data on a horizontal grid. The method contains flexibility to be implemented as a linear or non-linear inverse problem, which results, respectively, in a least-squares or robust estimate of the components of the magnetization vector of the sources. Applications to synthetic data show the robustness of our method against interfering anomalies and errors in the location of the sources' centre. Besides, we show the feasibility of applying the upward continuation to interpret non-spherical sources. Applications to field data over the Goiás Alkaline Province (GAP), Brazil, show the good performance of our method in estimating geological meaningful magnetization directions. The results obtained for a region of the GAP, near from the alkaline complex of Diorama, suggest the presence of non-outcropping sources marked by strong remanent magnetization with inclination and declination close to -70.35° and -19.81°, respectively. This estimated magnetization direction leads to predominantly positive reduced-to-the-pole anomalies, even for other region of the GAP, in the alkaline complex of Montes Claros de Goiás. These results show that the non-outcropping sources near from the alkaline complex of Diorama have almost the same magnetization direction of that ones in the alkaline complex of Montes Claros de Goiás, strongly suggesting that these sources have emplaced the crust almost within the same geological time interval.


2014 ◽  
Vol 62 ◽  
pp. 1-15
Author(s):  
Jørn G. Rønsbo ◽  
Henning Sørensen ◽  
Encarnacion Roda-Robles ◽  
François Fontan ◽  
Pierre Monchoux

In the Ilímaussaq alkaline complex, minerals from the rinkite–nacareniobsite-(Ce) solid solution series have been found in pulaskite pegmatite, sodalite foyaite, naujaite and naujaite pegmatite from the roof sequence, and in marginal pegmatite, kakortokite and lujavrite from the floor sequence. The electron microprobe analyses embrace almost the full extension of the solid solution series and confirm its continuity. The solid solution series shows similar compositional variations in the roof and floor sequences: Rinkite members of the series are found in the less evolved rocks in the two sequences, whereas nacareniobsite-Ce members occur in the most evolved rocks and pegmatites in the two sequences. The REE (+Y) content varies from 0.83 atoms per formula unit (apfu) in rinkite from pulaskite pegmatite to 1.31 apfu in nacareniobsite-(Ce) from naujaite pegmatite. The main substitution mechanisms in the solid solution series investigated in this work are 2Ca2+ = Na+ + REE3+ and Ti4+ + Ca2+ = Nb5+ + Na+. The increased contents of Nb5+ and REE3+ are only to a minor degree compensated through the F1– = O2– substitution. The chondrite normalised REE patterns of the minerals develop in a similar way in the two sequences, showing relative La-enrichment and Y-depletion from the less to the most evolved rocks. Hainite has not previously been found in the Ilímaussaq complex. It was here identified in a pulaskite pegmatite sample by a combination of X-ray diffraction giving the unit cell dimensions a = 9.5923(7) Å, b = 7.3505(5) Å, c = 5.7023(4) Å, α = 89.958(2)°, β = 100.260(1)°, γ = 101.100(2)°, and X-ray powder pattern and electron microprobe data giving the empirical formula (Ca1.62 Zr0.16Y 0.22) (Na0.87Ca1.11) (Ca 1.65 REE0.35)Na(Ti0.81Nb0.09Fe0.08 Zr0.02)(Si2O7)2O0.99F2.96. Based on published and the present data it is documented that minerals from the hainite-götzenite solid solution series show a compositional variation between the ideal end members (Y,REE,Zr)Na2Ca4Ti(Si2O7)2OF3 and NaCa6Ti(Si2O7)2OF3.


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