A review of the composition and evolution of hydrocarbon gases during solidification of the Ilímaussaq alkaline complex, South Greenland

2001 ◽  
pp. 159-166 ◽  
Author(s):  
Jens Konnerup-Madsen
Keyword(s):  
Nepheline Syenite ◽  
Subsequent Development ◽  
High Water ◽  
Vapour Phase ◽  
Low Carbon ◽  
Low Oxygen ◽  
Alkaline Complex ◽  
Hydrocarbon Gases ◽  
Wide Range ◽  
Water Contents

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Konnerup-Madsen, J. (2001). A review of the composition and evolution of hydrocarbon gases during solidification of the Ilímaussaq alkaline complex, South Greenland. Geology of Greenland Survey Bulletin, 190, 159-166. https://doi.org/10.34194/ggub.v190.5187 _______________ Fluid inclusions in minerals from agpaitic nepheline syenites and hydrothermal veins in the Ilímaussaq complex and in similar agpaitic complexes on the Kola Peninsula, Russia, are dominated by hydrocarbon gases (predominantly methane) and hydrogen. Such volatile compositions differ considerably from those of most other igneous rocks and their formation and entrapment in minerals reflects low oxygen fugacities and a wide range of crystallisation temperatures extending to a low-temperature solidus. Their composition reflects initial low carbon contents and high water contents of the magma resulting in the exsolution of a waterrich CO2–H2O dominated vapour phase. Fractionation of chlorides into the vapour phase results in high salinities and the subsequent development of a heterogeneous vapour phase with a highly saline aqueous-rich fraction and a methane-dominated fraction, with preferential entrapment of the latter, possibly due to different wetting characteristics. The light stable isotope compositions support an abiogenic origin for the hydrocarbons in agpaitic nepheline syenite complexes.

scholarly journals Lime Treatment of a Soft Sensitive Clay: A Sustainable Reuse Option

Geosciences ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 182
Author(s):  
Marta Di Sante ◽  
Bruno Di Buò ◽  
Evelina Fratalocchi ◽  
Tim Länsivaara
Keyword(s):  
Mechanical Performance ◽  
High Water ◽  
Compacted Clay ◽  
Lime Treatment ◽  
Microstructural Investigation ◽  
Soft Clays ◽  
Drying Procedures ◽  
Wide Range ◽  
Water Contents ◽  
Lime Addition

This paper presents the results of research aimed at studying the hydraulic and mechanical behavior of Finnish soft clays treated by quicklime. This research investigated the effect of water content and curing time on the characteristics of the compacted soil treated with 7% lime, with the aim of verifying the effectiveness of lime treatment and evaluating its possible re-use, thus avoiding landfill disposal. A laboratory-testing program was carried out both on treated and untreated soil, supported by microstructural investigation. Results have shown a general increase of the hydraulic conductivity due to the addition of lime, reduction of compressibility, and increase in the soil shear strength for a wide range of water contents (10%–40%), proving the effectiveness of the lime treatment. Lime addition to the compacted clay at high water contents (90%–130%) turned out to improve the mechanical characteristics to a lesser extent, while fractionated lime supply did not significantly improve the mechanical performance. The results of this research demonstrate that the re-use of sensitive clays, typically of high water contents, by lime addition require a drying process. Different drying procedures can be adopted (proposed in the paper) depending on the specific site conditions. However, the soil treatment is generally economically convenient in comparison to the disposal in waste landfills, which would represent the only alternative solution.

Water Diffusion in Silicate Glasses and Melts

2006 ◽  
Vol 46 ◽  
pp. 79-88 ◽  
Author(s):  
Harald Behrens
Keyword(s):  
Water Content ◽  
Ambient Pressure ◽  
High Water ◽  
Float Glass ◽  
Water Diffusion ◽  
Experimental Investigations ◽  
Melt Structure ◽  
Water Diffusivity ◽  
Wide Range ◽  
Water Contents

Knowledge on diffusion of water in glasses and melts is important for glass sciences as well as for Earth sciences. The ranges of water contents differ widely in both research domains. Industrial glass contain typically less than 0.1 wt% H2O whereas natural glasses may even contain up to 10 wt% H2O. Dissolved water strongly modifies physical and chemical properties of the melts and, hence, water diffusion studies at low water contents often cannot be transferred to high water contents and vice versa. Pressure effect on water diffusion, on the other hand, is small so that high pressure data can be applied also at ambient pressure without significant error. At low water contents the assumption of constant water diffusivity is often justified whereas at high water contents the H2O diffusivity increases strongly (often linearly or exponentially) with water content. Combining experimental data over a wide range of water contents allows getting deeper understanding of the mechanisms of water diffusion and of the effect of dissolved water on melt structure. In this paper an overview is given on experimental investigations on water diffusivity in aluminosilicate and silicate systems. Effects of base compositions and water content on water diffusivities are discussed. New experimental results for water diffusion in soda lime silica glass, float glass and borosilicate glass are presented.

Precipitation at the transformation interface of pearlite in steel

1990 ◽  
Vol 48 (4) ◽  
pp. 912-913
Author(s):  
F. A. Khalid ◽  
D. V. Edmonds
Keyword(s):  
Thin Foil ◽  
Carbon Steels ◽  
Model Alloy ◽  
Low Carbon ◽  
High Carbon ◽  
Growth Interface ◽  
Medium Carbon ◽  
Interphase Precipitation ◽  
Solution Treated ◽  
Wide Range

The austenite/pearlite growth interface in a model alloy steel (Fe-1lMn-0.8C-0.5V nominal wt%) is being studied in an attempt to characterise the morphology and mechanism of VC precipitation at the growth interface. In this alloy pearlite nodules can be grown isothermally in austenite that remains stable at room temperature thus facilitating examination of the transformation interfaces. This study presents preliminary results of thin foil TEM of the precipitation of VC at the austenite/ferrite interface, which reaction, termed interphase precipitation, occurs in a number of low- carbon HSLA and microalloyed medium- and high- carbon steels. Some observations of interphase precipitation in microalloyed low- and medium- carbon commercial steels are also reported for comparison as this reaction can be responsible for a significant increase in strength in a wide range of commercial steels.The experimental alloy was made as 50 g argon arc melts using high purity materials and homogenised. Samples were solution treated at 1300 °C for 1 hr and WQ. Specimens were then solutionised at 1300 °C for 15 min. and isothermally transformed at 620 °C for 10-18hrs. and WQ. Specimens of microalloyed commercial steels were studied in either as-rolled or as- forged conditions. Detailed procedures of thin foil preparation for TEM are given elsewhere.

Substituent Effects on the Thermal Decomposition of Phosphate Esters on Ferrous Surfaces

2019 ◽  
Author(s):  
James Ewen ◽  
Carlos Ayestaran Latorre ◽  
Arash Khajeh ◽  
Joshua Moore ◽  
Joseph Remias ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Film Formation ◽  
Substituent Effects ◽  
Vapour Phase ◽  
Industrial Applications ◽  
Phosphate Esters ◽  
Antiwear Additives ◽  
Formation Mechanisms ◽  
Phosphate Ester ◽  
Wide Range

<p>Phosphate esters have a wide range of industrial applications, for example in tribology where they are used as vapour phase lubricants and antiwear additives. To rationally design phosphate esters with improved tribological performance, an atomic-level understanding of their film formation mechanisms is required. One important aspect is the thermal decomposition of phosphate esters on steel surfaces, since this initiates film formation. In this study, ReaxFF molecular dynamics simulations are used to study the thermal decomposition of phosphate esters with different substituents on several ferrous surfaces. On Fe<sub>3</sub>O<sub>4</sub>(001) and α-Fe(110), chemisorption interactions between the phosphate esters and the surfaces occur even at room temperature, and the number of molecule-surface bonds increases as the temperature is increased from 300 to 1000 K. Conversely, on hydroxylated, amorphous Fe<sub>3</sub>O<sub>4</sub>, most of the molecules are physisorbed, even at high temperature. Thermal decomposition rates were much higher on Fe<sub>3</sub>O<sub>4</sub>(001) and particularly α-Fe(110) compared to hydroxylated, amorphous Fe<sub>3</sub>O<sub>4</sub>. This suggests that water passivates ferrous surfaces and inhibits phosphate ester chemisorption, decomposition, and ultimately film formation. On Fe<sub>3</sub>O<sub>4</sub>(001), thermal decomposition proceeds mainly through C-O cleavage (to form surface alkyl and aryl groups) and C-H cleavage (to form surface hydroxyls). The onset temperature for C-O cleavage on Fe<sub>3</sub>O<sub>4</sub>(001) increases in the order: tertiary alkyl < secondary alkyl < primary linear alkyl ≈ primary branched alkyl < aryl. This order is in agreement with experimental observations for the thermal stability of antiwear additives with similar substituents. The results highlight surface and substituent effects on the thermal decomposition of phosphate esters which should be helpful for the design of new molecules with improved performance.</p>

SAE 1020

Alloy Digest ◽  
1987 ◽  
Vol 36 (2) ◽  
Keyword(s):  
Fracture Toughness ◽  
Corrosion Resistance ◽  
Carbon Steel ◽  
Low Carbon Steel ◽  
Heat Treating ◽  
Low Carbon ◽  
Steel Mills ◽  
Temperature Performance ◽  
Wide Range ◽  
Cold Worked

Abstract SAE 1020 is a low-carbon steel combining good machinability, workability and weldability. It is carburized for use in case-hardened components and it is used for a wide range of applications in the hot-worked, cold-worked, normalized or quenched-and-tempered conditions. Its many uses include bolts, rods, plate applications, machinery components, case-hardened parts, spinning tools and trimming dies. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness. It also includes information on low temperature performance and corrosion resistance as well as heat treating, machining, joining, and surface treatment. Filing Code: CS-113. Producer or source: Carbon steel mills.

Soil Mixer for a Wide Range of Water Contents

1990 ◽  
Vol 54 (2) ◽  
pp. 555-557 ◽  
Author(s):  
Ralph G. Nash ◽  
M. Leroy Beall
Keyword(s):  
Wide Range ◽  
Water Contents

Hydraulic segmentation does not protect stems from acute water loss during fire

2021 ◽  
Author(s):  
William A Hoffmann ◽  
Amanda C Rodrigues ◽  
Nicholas Uncles ◽  
Lorenzo Rossi
Keyword(s):  
Water Uptake ◽  
Water Loss ◽  
High Water ◽  
Fire Plume ◽  
Magnolia Grandiflora ◽  
Hydraulic Failure ◽  
Factors Influencing ◽  
Wide Range ◽  
Transport Path ◽  
Measured Water

Abstract The heat plume associated with fire has been hypothesized to cause sufficient water loss from trees to induce embolism and hydraulic failure. However, it is unclear whether the water transport path remains sufficiently intact during scorching or burning of foliage to sustain high water loss. We measured water uptake by branches of Magnolia grandiflora while exposing them to a range of fire intensities, and examined factors influencing continued water uptake after fire. Burning caused a 22-fold mean increase in water uptake, with greatest rates of water loss observed at burn intensities that caused complete consumption of leaves. Such rapid uptake is possible only with steep gradients in water potential, which would likely result in substantial cavitation of xylem and loss of conductivity in intact stems. Water uptake continued after burning was complete, and was greatest following burn intensities that killed leaves but did not consume them. This post-fire uptake was mostly driven by rehydration of the remaining tissues, rather than evaporation from the tissues. Our results indicate that the fire-plume hypothesis can be expanded to include a wide range of burning conditions experienced by plants. High rates of water loss are sustained during burning, even when leaves are killed or completely consumed.

scholarly journals Ways into Understanding HIF Inhibition

Cancers ◽  
2021 ◽  
Vol 13 (1) ◽  
pp. 159
Author(s):  
Tina Schönberger ◽  
Joachim Fandrey ◽  
Katrin Prost-Fingerle
Keyword(s):  
Protein Interactions ◽  
Target Genes ◽  
Protein Protein Interactions ◽  
Low Oxygen ◽  
Drug Candidates ◽  
Open Questions ◽  
Wide Range ◽  
Hif Pathway

Hypoxia is a key characteristic of tumor tissue. Cancer cells adapt to low oxygen by activating hypoxia-inducible factors (HIFs), ensuring their survival and continued growth despite this hostile environment. Therefore, the inhibition of HIFs and their target genes is a promising and emerging field of cancer research. Several drug candidates target protein–protein interactions or transcription mechanisms of the HIF pathway in order to interfere with activation of this pathway, which is deregulated in a wide range of solid and liquid cancers. Although some inhibitors are already in clinical trials, open questions remain with respect to their modes of action. New imaging technologies using luminescent and fluorescent methods or nanobodies to complement widely used approaches such as chromatin immunoprecipitation may help to answer some of these questions. In this review, we aim to summarize current inhibitor classes targeting the HIF pathway and to provide an overview of in vitro and in vivo techniques that could improve the understanding of inhibitor mechanisms. Unravelling the distinct principles regarding how inhibitors work is an indispensable step for efficient clinical applications and safety of anticancer compounds.

Effects of Air Temperature on Combustion Characteristics of LPG Diffusion Flame

2020 ◽  
Vol 1008 ◽  
pp. 128-138
Author(s):  
Ahmed M. Salman ◽  
Ibrahim A. Ibrahim ◽  
Hamada M. Gad ◽  
Tharwat M. Farag
Keyword(s):  
Air Temperature ◽  
Diffusion Flame ◽  
Nitrogen Addition ◽  
Flame Length ◽  
Combustion Characteristics ◽  
Operating Conditions ◽  
Low Oxygen ◽  
Air Temperatures ◽  
Air Stream ◽  
Wide Range

In the present study, the combustion characteristics of LPG gaseous fuel diffusion flame at elevated air temperatures were experimentally investigated. An experimental test rig was manufactured to examine a wide range of operating conditions. The investigated parameters are the air temperatures of 300, 350, 400, 450, and 500 K with constant percentage of nitrogen addition in combustion air stream of 5 % to give low oxygen concentration of 18.3 % by mass at constant air swirl number, air to fuel mass ratio, and thermal load of 1.5, 30, and 23 kW, respectively. The gaseous combustion characteristics were represented as axial and radial temperatures distributions, temperatures gradient, visible flame length and species concentrations. The results indicated that as the air temperature increased, the chemical reaction rate increased and flame volume decreased, the combustion time reduced leading to a reduction in flame length. The NO concentration reaches its maximum values near the location of the maximum centerline axial temperature. Increasing the combustion air temperature by 200 K, the NO consequently O2 concentrations are increased by about % 355 and 20 % respectively, while CO2 and CO concentrations are decreased by about % 21 and 99 % respectively, at the combustor end.

Constraints on the formation of the giant Daheishan porphyry Mo deposit (NE China) from whole-rock and accessory mineral geochemistry

2021 ◽  
Author(s):  
Kai Xing ◽  
Qihai Shu ◽  
David R Lentz
Keyword(s):  
High Water ◽  
Accessory Mineral ◽  
Ne China ◽  
Accessory Minerals ◽  
Slab Rollback ◽  
Continental Arc ◽  
Arc Setting ◽  
Porphyry Mo Deposit ◽  
T Values ◽  
Water Contents

Abstract There are more than 90 porphyry (or skarn) Mo deposits in northeastern China with Jurassic or Cretaceous ages. These are thought to have formed mainly in a continental arc setting related to the subduction of the Paleo-Pacific oceanic plate in the Jurassic and subsequent slab rollback in the early Cretaceous. The Jurassic Daheishan porphyry Mo deposit is one of the largest Mo deposits in NE China, which contains 1.09 Mt Mo with an average Mo grade of 0.07%. To better understand the factors that could have controlled Mo mineralization at Daheishan, and potentially in other similar porphyry Mo deposits in NE China, the geochemical and isotopic compositions of the ore-related granite porphyry and biotite granodiorite, and the magmatic accessory minerals apatite, titanite and zircon from the Daheishan intrusions, were investigated so as to evaluate the potential roles that magma oxidation states, water contents, sulfur and metal concentrations could have played in the formation of the deposit. Magmatic apatite and titanite from the causative intrusions show similar εNd(t) values from -1.1 to 1.4, corresponding to TDM2 ages ranging from 1040 to 840 Ma, which could be accounted for by a mixing model through the interaction of mantle-derived basaltic melts with the Precambrian lower crust. The Ce and Eu anomalies of the magmatic accessory minerals have been used as proxies for magma redox state, and the results suggest that the ore-forming magmas are highly oxidized, with an estimated ΔFMQ range of + 1.8 to + 4.1 (+2.7 in average). This is also consistent with the high whole-rock Fe2O3/FeO ratios (1.3–26.4). The Daheishan intrusions display negligible Eu anomalies (Eu/Eu* = 0.7–1.1) and have relatively high Sr/Y ratios (40–94) with adakitic signatures; they also have relatively high Sr/Y ratios in apatite and titanite. These suggest that the fractionation of amphibole rather than plagioclase is dominant during the crystallization of the ore-related magmas, which further indicates a high magmatic water content (e.g., &gt;5 wt%). The magmatic sulfur concentrations were calculated using available partitioning models for apatite from granitoids, and the results (9–125 ppm) are indistinguishable from other mineralized, subeconomic and barren intrusions. Furthermore, Monte Carlo modelling has been conducted to simulate the magmatic processes associated with the formation of the Daheishan Mo deposit, and the result reveals that a magma volume of ∼280 km3 with ∼10 ppm Mo was required to form the Mo ores containing 1.09 Mt Mo in Daheishan. The present study suggests that a relatively large volume of parental magmas with high oxygen fugacities and high water contents is essential for the generation of a giant porphyry Mo deposit like Daheishan, whereas a specific magma composition (e.g., with unusually high Mo and/or S concentrations), might be less critical.

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