scholarly journals Water-absorbing materials based on polymer hydrogel and bentonite

Author(s):  
E. V. Vorobieva

The article deals with the production, sorption and rheological properties of composite materials based on polymer hydrogel and bentonite. It is shown that bentonite prevents the collapse of the hydrogel in aqueous solutions of electrolytes and leads to an increase in the moisture content after the collapse. After several repeated cycles of swelling in water, followed by drying at 60 and 110 °C, the degree of swelling of the composite is higher than that of the hydrogel. In the temperature range from 20 to 40 °C, the polymer hydrogel and the composite are able to withstand at least ten cycles of swelling and drying without changing the degree of swelling.

1983 ◽  
Vol 61 (2) ◽  
pp. 267-268 ◽  
Author(s):  
Victor Hugo Acevedo ◽  
Juana Albarracín De Morán ◽  
Leopoldo Armando Sales

The specific conductivities and pH values of copper sulphate solutions in water were measured in the temperature range from 10 °C to 50 °C. The data, previously corrected by hydrolysis, were analyzed by means of the Lee Wheaton theory.This fit, for the evaluation of Λ0, R, and KA parameters, is quite satisfactory up to a maximum concentration of 25 × 10−4 moldm−3 and the agreement between experimental data and the literature value for 25 °C is acceptable.


Author(s):  
A. B. Baranov ◽  
I. N. Tsapenko ◽  
A. V. Petrogradsky ◽  
I. D. Simonov-Emelyanov ◽  
N. L. Shembel

The rheological properties of polysulfide (PPS) melts and composite materials based on them were investigated in a wide range of temperatures and concentrations of fillers of different nature. It was established that the introduction of rheological additives into dispersed and hybrid-filled composite materials allows significantly reducing the viscosity and improving the processability of the compositions. Introduction of heat-stabilizing additives into PPS allows expanding the temperature interval of processing the composite materials based on PFC from 320 to 340°С. Complete thermal stability curves for the PPS compositions in a wide temperature range were obtained.


1977 ◽  
Vol 42 (9) ◽  
pp. 2642-2650
Author(s):  
F. Kaštánek ◽  
J. Kratochvíl ◽  
J. Pata ◽  
M. Rylek

1984 ◽  
Vol 49 (5) ◽  
pp. 1061-1078 ◽  
Author(s):  
Jiří Čeleda ◽  
Stanislav Škramovský

Based on the earlier paper introducing a concept of the apparent parachor of a solute in the solution, we have eliminated in the present work algebraically the effect which is introduced into this quantity by the additivity of the apparent molal volumes. The difference remaining from the apparent parachor after substracting the contribution corresponding to the apparent volume ( for which the present authors suggest the name metachor) was evaluated from the experimental values of the surface tension of aqueous solutions for a set of 1,1-, 1,2- and 2,1-valent electrolytes. This difference showed to be independent of concentration up to the very high values of the order of units mol dm-3 but it was directly proportional to the number of the free charges (with a proportionality factor 5 ± 1 cm3 mol-1 identical for all studied electrolytes). The metachor can be, for this reason, a suitable characteristic for detection of the association of ions and formation of complexes in the solutions of electrolytes, up to high concentrations where other methods are failing.


2006 ◽  
Vol 38 (11) ◽  
pp. 1474-1478 ◽  
Author(s):  
Monimul Huque ◽  
Iqbal Ahmed Siddiquey ◽  
Md. Nizam Uddin

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