scholarly journals Karakteristik Asam Resin Kopal Agathis loranthifolia Sukabumi (Characteristic Resin Acid of Kopal Agathis loranthifolia Sukabumi)

1970 ◽  
Vol 4 (2) ◽  
pp. 13-17
Author(s):  
Ika Resmeiliana ◽  
Kurnia Sofyan ◽  
Suminar S. Achmadi
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Acid Content ◽  
Raw Materials ◽  
Resin Acid ◽  
Resin Acids ◽  
Gas Chromatography Mass Spectrometry ◽  
Alpha Pinene ◽  
Limonene Oxide

Copal is originated from the exudate of Agathis loranthifolia tree, which flows out from tapping. copal is one of Indonesia's export comodities. Unfortunately, since the export was still in the form of raw materials, it was necessary to study the identification of resin acid content of the copal of Sukabumi. It was also necessary to test the quality of the copal. Extraction was done by using acetone: MeOH (9:1) solvent. Then the extraction of resin acid content was identified by using Gas Chromatography Mass Spectrometry (CGMS). The quality of copal was evaluated based on SNI 7634-2011. Resin acids of the copal which were identified by CGMS are limonene (44%), ethylene oxide hexamer, cis-limonene oxide, toluene, trans-carveol, 2-siclohexane-1-one, trans-limonene oxide, and alpha pinene. Copal of Sukabumi belong to the first class, because the obtained parameters are not all included in the premier class ranges. However it is still possible to be upgraded to their premier class by removing the dirt.Keywords : Agathis loranthifolia, copal, limonene, resin acids.

Development, validation, and certification by isotope dilution gas chromatography-mass spectrometry of lyophilized human serum reference materials for cortisol (CRM 192 and 193) and progesterone (CRM 347 and 348)

1991 ◽  
Vol 37 (4) ◽  
pp. 540-546 ◽  
Author(s):  
Linda Thienpont ◽  
Lothar Siekmann ◽  
Alexander Lawson ◽  
Elisabeth Colinet ◽  
Andrȳ De Leenheer
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Reference Materials ◽  
Isotope Dilution ◽  
Certified Reference Materials ◽  
Collaborative Study ◽  
Gas Chromatography Mass Spectrometry ◽  
Chromatography Mass Spectrometry ◽  
Coefficients Of Variation

Abstract The Community Bureau of Reference of the European Communities has produced four batches of lyophilized serum Certified Reference Materials, two for cortisol (CRM 192 and 193) and two for progesterone (CRM 347 and 348). For cortisol, one of the pools consisted of serum from healthy blood donors, whereas the second batch was supplemented with pure cortisol. The progesterone Reference Materials contained only endogenous hormone concentrations. Assessment of vial-to-vial variability in the cortisol and progesterone concentrations showed no between-sample inhomogeneity, and the materials were stable. The quality of the materials was therefore considered sufficient for certification of the values for the cortisol and progesterone concentrations by a collaborative study involving several laboratories from the European Communities, using isotope dilution gas chromatography-mass spectrometry. Inaccuracy in reconstitution of the lyophilized materials was less than 0.3%; imprecision of sampling was less than 0.2%. For determinations of cortisol and progesterone concentrations, the mean within-laboratory coefficients of variation (CVs) were 1.76% (CRM 192), 1.19% (CRM 193), 1.64% (CRM 347), and 1.75% (CRM 348). The between-laboratory CVs were greater: CRM 192, 1.79%; CRM 193, 1.48%; CRM 347, 2.08%; and CRM 348, 2.16%. The concentrations in the reconstituted Reference Materials were certified to be 273 nmol/L in CRM 192 and 763 nmol/L in CRM 193 for cortisol and 10.13 nmol/L in CRM 347 and 40.3 nmol/L in CRM 348 for progesterone. Uncertainties at the 0.95 confidence level--6 (CRM 192), 14 (CRM 193), 0.21 (CRM 347), and 1.0 nmol/L (CRM 348)--were considered compatible with the intended use of the materials.

Comparative Analysis of the Aroma Compounds of Muscat Hamburg Dry White Wines from Different Wine Regions in China

2012 ◽  
Vol 554-556 ◽  
pp. 1581-1584 ◽  
Author(s):  
Yan Cui ◽  
Wei Wang ◽  
Fu Qing Zhang ◽  
Wen Lv
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Comparative Analysis ◽  
Volatile Compounds ◽  
Solid Phase Microextraction ◽  
Solid Phase ◽  
Raw Materials ◽  
Gas Chromatography Mass Spectrometry ◽  
Higher Alcohols ◽  
White Wines

The aroma compoumds of Muscat Hamburg dry white wines from three different wine regions, made with the same brewing technology, were determined by head space solid phase microextraction coupled with gas chromatography mass spectrometry (HS-SPME-GC/MS), with grapes harvested in 2010 from Tianjin Hangu, Heibei Changli and Shandong Pingdu regions as raw materials. Total 58 volatile compounds were identified and 23 componds were quantified. The results show that the wines from Hangu regions contained relatively high levels of terpenes and esters, and lower contents of higher alcohols,which contributed to the wines rich floral and fruity aromas and sweet, musky flavors.

scholarly journals Gas Chromatography-Mass Spectrometry (GC-MS) Analysis of Essential Oil Salvia Officinalis in Sudan

2019 ◽  
Author(s):  
Amna yousif Mohamed ◽  
Ahmed Ali Mustafa
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Essential Oil ◽  
Essential Oils ◽  
Mass Spectrometer ◽  
Essential Oil Composition ◽  
Salvia Officinalis ◽  
Gas Chromatography Mass Spectrometry ◽  
Oil Composition ◽  
Alpha Pinene

Abstract: In this study the essential oils of Salvia officinalis growing in Sudan, were obtained by hydrodistillation and analyzed by Gas chromatography mass spectrometer, forty tow compounds were identified. The essential oil composition of S.officinalis found that it had many important compounds. The detected main compounds were oxygenated monoterpenes followed monohydrocarbone, squiterpenes and other compounds. The main essential oil constituents were α-terpineol (33.07%), camphor (11.57%), α-pinene (8.96%) camphene (5.09%) β-cymen (5.40 %) caryphyllene (3.76%) β-myrcene (3.65%) β-menth1-en-b-ol (3.45%) bomeol (3.38%) β-pinene (2.74%) Epiglobulol (2.59%) 1,8 Cineol (2.24%) and trans-β- terpinyl butanone(2.00% ).

scholarly journals Chemical Profiles of Incense Smoke Ingredients from Agarwood by Headspace Gas Chromatography-Tandem Mass Spectrometry

Molecules ◽  
2018 ◽  
Vol 23 (11) ◽  
pp. 2969 ◽  
Author(s):  
Wen-Yi Kao ◽  
Chien-Yun Hsiang ◽  
Shih-Ching Ho ◽  
Tin-Yun Ho ◽  
Kung-Ta Lee
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Chemical Constituents ◽  
Gas Chromatography Mass Spectrometry ◽  
Chromone Derivatives ◽  
Chromatography Tandem Mass Spectrometry ◽  
Headspace Gas ◽  
Chemical Profiles ◽  
Assess Quality

Agarwood, the resinous wood in the heartwood of Aquilaria trees, has been used as incense in traditional Chinese medicine for its sedative, aphrodisiac, carminative, and anti-emetic effects. Grading of agarwood is usually based on its physical properties. Therefore, it is important to develop analytic methods for judgment and grading of agarwood. Here, we created a headspace (HS) preheating system that is combined with gas chromatography-mass spectrometry (HS GC-MS) to analyze the chemical constituents in the incense smoke produced by agarwood. Incense smoke generated in the HS preheating system was injected directly to GC-MS for analysis. A total of 40 compounds were identified in the incense smoke produced by Kynam agarwood, the best agarwood in the world. About half of the compounds are aromatics and sesquiterpenes. By analyzing chemical constituents in the incense smoke produced by Vietnamese, Lao, and Cambodian varieties of agarwood, we found that butyl hexadecanoate, butyl octadecanoate, bis(2-ethylhexyl) 1,2-benzenedicarboxylate, and squalene were common in the aforementioned four varieties of agarwoods. 2-(2-Phenylethyl) chromone derivatives were identified only in the incense smoke produced by Kynam agarwood, and were the major ingredient (27.23%) in the same. In conclusion, this is the first study that analyzes chemical profiles of incense smoke produced by agarwood using HS GC-MS. Our data showed that 2-(2-phenylethyl) chromone derivatives could be used to assess quality of agarwoods. Moreover, HS GC/MS may be a useful tool for grading quality of agarwood.

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