scholarly journals Treatment of pulp and paper mill effluent using low cost adsorbents: An overview

2018 ◽  
Vol 10 (2) ◽  
pp. 695-704 ◽  
Author(s):  
Shaveta Kakkar ◽  
Anju Malik ◽  
Sanjeev Gupta
Keyword(s):  
Low Cost ◽  
Oxygen Demand ◽  
Cost Effective ◽  
Paper Mill ◽  
Pulp And Paper ◽  
Industrial Wastes ◽  
Pulp And Paper Mill ◽  
Paper Mills ◽  
Paper Mill Effluent ◽  
Adsorption Processes

In the present review, the suitability of adsorption process using low cost adsorbent for the treatment of pulp and paper mill effluent has been discussed. It is clear that adsorption processes are appropriate for the removal of recalcitrant compounds such as surfactants and pesticides, among others biodegradable or non-biodegradable compound present in pulp and paper mills effluents. The importance of the  adsorption is to improvement of the  removal of various physico- chemical (biological oxygen demand (BOD), chemical oxygen demand (COD), colour, suspended solids, lignin), heavy metals (Cu, Cr, Fe, Zn, Ni and Mn etc) organochlorine compounds, all recalcitrant pollutant, reduce toxicity, enhance colour removal by using different cost effective adsorbents. The effective use of the different adsorbents developed from different adsorbent media such as activated carbon, agriculture by product and industrial wastes and sludge as adsorbents  for the removal of different pollutants from the various processes and operations of pulp and paper mill as potential alternatives to different treatment process and received widespread attention. Adsorption necessity is a novel treatment option to improve the efficiency of removal within the discharge limits of wastewaters into the receiving bodies without causing any damage of the environment. However, still there is a need to find out the practical usefulness of such low cost adsorbent at industrial scale with the special reference to metals.

scholarly journals A review on bioremediation of pulp and paper mill effluent – An alternative to conventional remedial technologies

2018 ◽  
Vol 10 (1) ◽  
pp. 367-374 ◽  
Author(s):  
Sangeeta Madan ◽  
Preeti Sachan ◽  
Utkarsh Singh
Keyword(s):  
Biological Treatment ◽  
Oxygen Demand ◽  
Paper Mill ◽  
Pulp And Paper ◽  
Residual Effects ◽  
Organic Load ◽  
Pulp And Paper Mill ◽  
Paper Mills ◽  
Paper Mill Effluent ◽  
Paper Mill Effluents

At present, a large amount of water required for paper production and various chemicals has been identified in effluents, which is produced at different steps of paper making in paper mills. The pulp and paper industry is typically related to pollution difficulties related to high biological oxygen demand (BOD), chemical oxygen demand (COD), colour, suspended solids, lignin and chlorinated compounds. Several studies have been made on eliminate these difficulties of pulp and paper effluents, the problem still continues. Although the physical and chemical methods are on the track of treatment, they are not on par with biological treatment because of cost ineffectiveness and residual effects. The biological treatment is known to be effective in reducing the organic load and toxic effects of paper mill effluents. Some microorganisms including bacteria and fungi have been involved in degrading the chemicals present in pulp and paper mill effluent. This article is an overview of the attempts made by several researchers worldwide to use biotechnological methods for degradation of the toxic compounds present in pulp and paper mill effluents by using fungi, bacteria, algae and enzymes. The current study clearly shows that application of native dominant bacterial and fungal isolates may be used forthe treatment of large pulp and paper mills effluents.

scholarly journals Thermal characterization of hydrated eco-friendly clinkers produced from pulp and paper mill waste

Cerâmica ◽  
2018 ◽  
Vol 64 (371) ◽  
pp. 311-317 ◽  
Author(s):  
L. Simão ◽  
N. J. Lóh ◽  
D. Hotza ◽  
F. Raupp-Pereira ◽  
J. A. Labrincha ◽  
...  
Keyword(s):  
Thermal Characterization ◽  
Paper Mill ◽  
Pulp And Paper ◽  
Industrial Wastes ◽  
Pulp And Paper Mill ◽  
Paper Mills ◽  
Bet Analysis ◽  
Alternative Materials ◽  
Clinker Production

Abstract Industrial wastes from pulp and paper mills are potentially useful materials to use as alternative materials in clinker production. In this study, eco-friendly clinkers were obtained using only waste as feedstock. Eco-friendly clinker with different C3S and C2S contents were produced and hydrated for 7 days at 40 °C, or for 28 and 90 days at room temperature. The potentialities of these waste and the products obtained were revealed through chemical (XRF), thermal (DTA/TG) and surface area (BET) analysis. For comparison, a common ordinary Portland cement (OPC) was tested. As expected, the hydration rate of formulations presenting higher C3S content was higher, generating higher amounts of Ca(OH)2. Furthermore, the amount of Portlandite formed was lower when compared to OPC.

Water Quality of the River Sava at the Inflow of a Pulp and Paper Mill Effluent

1990 ◽  
Vol 22 (5) ◽  
pp. 189-194 ◽  
Author(s):  
V. V. Cibulić
Keyword(s):  
Treatment Plant ◽  
Oxygen Demand ◽  
Paper Mill ◽  
Negative Influence ◽  
Pulp And Paper ◽  
Water Levels ◽  
Toxic Substances ◽  
Pulp And Paper Mill ◽  
Paper Mill Effluent ◽  
High Concentrations

The results of investigations into the effects of wastewaters from pulp and paper production on the River Sava are presented in this paper. Two situations were studied, i.e., when the treatment plant was in operation and when it was not working. The results of the investigations indicated that the wastewaters had significant effects on the Sava. Chemical oxygen demand (COD) and biochemical oxygen demand (BOD) were increased and some toxic substances were present at high concentrations, e.g., phenols, oils and grease, dyestuff, etc. The negative influence of the wastewaters was greater during the summer, at low water levels in the Sava. The Sava is a tributary of the River Danube, into which the pollution from this river finally flows. Regardless of the water flow rates, toxic substances are constantly accumulating, and, as a result, even such large systems as the Danube and the Sava are becoming more and more polluted.

Summary of Case Studies Investigating the Causes of Pulp and Paper Mill Effluent Regulatory Toxicity

2004 ◽  
Vol 39 (2) ◽  
pp. 93-102 ◽  
Author(s):  
Tibor Kovacs ◽  
Sharon Gibbons ◽  
Brian O'Connor ◽  
Pierre Martel ◽  
Michael Paice ◽  
...  
Keyword(s):  
Rainbow Trout ◽  
Oncorhynchus Mykiss ◽  
Daphnia Magna ◽  
Paper Mill ◽  
Pulp And Paper ◽  
Pulp And Paper Mill ◽  
Pulp And Paper Mills ◽  
Paper Mills ◽  
Paper Mill Effluent ◽  
Rainbow Trout Oncorhynchus Mykiss

Abstract In Canada, effluents from pulp and paper mills are regulated for toxicity. The regulation requires ≥50% survival of rainbow trout (Oncorhynchus mykiss) exposed to full-strength (i.e., 100%) effluent for 96 h in tests that must be conducted monthly. The regulation also calls for ≥50% survival of Daphnia magna exposed to 100% effluent for 48 h in weekly monitoring tests. Every year, about 10 to 25% of the mills exceed the regulatory limit at least once in tests with either rainbow trout or Daphnia magna. Between 1996 and 2003, we investigated 84 such cases from 32 mills. Of the 84 investigations, 49 involved only trout, 29 involved only Daphnia, and six involved both species. We identified the actual cause of toxicity in 70% of the cases and partially or tentatively identified the toxicant(s) in 17% more. In the cases involving only trout, the most frequent causes of toxicity were related to biotreatment performance (e.g., ammonia). In the cases involving only Daphnia, the most frequent cause of toxicity seemed to be related to polymeric formulations. For those cases involving both trout and Daphnia, the cause of toxicity was traced to more than one compound or to excess concentrations of a specific compound resulting from a spill or biotreatment-related problems.

scholarly journals Integral indices for quality assessment of pulp and paper mill effluents

2014 ◽  
Vol 33 (1) ◽  
Author(s):  
Konstantin Bogolitsyn ◽  
Maria Gusakova ◽  
Nina Samsonova ◽  
Natalia Selivanova ◽  
Alexsandra Pochtovalova
Keyword(s):  
Oxygen Demand ◽  
Paper Mill ◽  
Pulp And Paper ◽  
Complex Nature ◽  
Pulp And Paper Mill ◽  
Pulp And Paper Mills ◽  
Paper Mills ◽  
Paper Mill Effluents ◽  
Northwest Region ◽  
Qualitative And Quantitative Characteristics

AbstractThe first part of this investigation studied complex nature of chemical oxygen demand (COD ) parameter on local and overall effluents, which were obtained from two pulp and paper mills, located in the Northwest region of Russia. Contribution of individual compounds and fractions of matters having different chemical nature to COD for these effluents was established. The second part of this study shows that, qualitative and quantitative characteristics of priority pollutants and their contribution to COD for different pulp and paper mills are not the same, though these mills use similar technologies and produce similar products.

Dactylogyrus (Monogenea) infections on the gills of roach (Rutilus rutilus L.) experimentally exposed to pulp and paper mill effluent

Parasitology ◽  
1997 ◽  
Vol 114 (5) ◽  
pp. 439-446 ◽  
Author(s):  
R. SIDDALL ◽  
M. KOSKIVAARA ◽  
E. T. VALTONEN
Keyword(s):  
Rutilus Rutilus ◽  
Paper Mill ◽  
Pulp And Paper ◽  
Larval Abundance ◽  
Pulp And Paper Mill ◽  
Roach Rutilus Rutilus ◽  
Similar Reduction ◽  
Paper Mills ◽  
High Exposure ◽  
Paper Mill Effluent

Experimental exposure to bleached kraft pulp and paper mill effluent (BKME) at a concentration of 10% significantly reduced the abundance and mean number of species of Dactylogyrus on the gills of naturally infected roach, Rutilus rutilus, over a 3 week period. Seven Dactylogyrus species were recorded which differed widely in their susceptibility to the effluent. The experiment coincided with a natural spring peak in dactylogyrid infections on roach. BMKE exposure did not prevent parasite reproduction but post-larval abundance was significantly higher on control than effluent-exposed hosts. There was no evidence of a BKME-induced shift in microhabitat distribution of dactylogyrids. Elevated levels of infection with Dactylogyrus spp. have been recorded on roach from a Finnish lake containing relatively low concentrations of BMKE. The high exposure concentration in this experiment produced a similar reduction in dactylogyrid infections to that reported in separate studies in close proximity to Swedish pulp and paper mills. The discrepancy between the results of the Finnish and Swedish field investigations is therefore considered to be due to differences in BKME concentration between the study areas.

scholarly journals Bioremediation of Agro-Based Pulp Mill Effluent by Microbial Consortium Comprising Autochthonous Bacteria

2012 ◽  
Vol 2012 ◽  
pp. 1-7 ◽  
Author(s):  
Virendra Kumar ◽  
Purnima Dhall ◽  
Rita Kumar ◽  
Yogendra Prakash Singh ◽  
Anil Kumar
Keyword(s):  
Black Liquor ◽  
Oxygen Demand ◽  
Pulp Mill ◽  
Paper Mill ◽  
Kraft Pulping ◽  
Pulp And Paper ◽  
Small Scale ◽  
Pulp And Paper Mill ◽  
Nitrogen And Phosphorus ◽  
Paper Mills

Small-scale agro-based pulp and paper mills are characterized as highly polluting industries. These mills use Kraft pulping process for paper manufacturing due to which toxic lignified chemicals are released into the environment. Lack of infrastructure, technical manpower, and research and development facilities restricts these mills to recover these chemicals. Therefore, the chemical oxygen demand (COD) of the emanating stream is quite high. For solving the above problem, four bacteria were isolated from the premises of agro-based pulp and paper mill which were identified as species ofPseudomonas, Bacillus, Pannonibacter, andOchrobacterum. These bacteria were found capable of reducing COD up to 85%–86.5% in case of back water and 65-66% in case of back water : black liquor (60 : 40), respectively, after acclimatization under optimized conditions (pH 6.8, temperature 35°C, and shaking 200 rpm) when the wastewater was supplemented with nitrogen and phosphorus as trace elements.

scholarly journals Coagulation and UF treatment of pulp and paper mill wastewater in comparison

2012 ◽  
Vol 10 (1) ◽  
pp. 127-136 ◽  
Author(s):  
Marjana Simonič ◽  
Doroteja Vnučec
Keyword(s):  
Ceramic Membrane ◽  
Oxygen Demand ◽  
Active Surface ◽  
Paper Mill ◽  
Pilot Scale ◽  
Pulp And Paper ◽  
Pulp And Paper Mill ◽  
Polyaluminum Chloride ◽  
Paper Mills ◽  
Paper Mill Wastewater

AbstractA study using coagulation-flocculation and ultrafiltration (UF)methods for pulp and paper mills’ wastewater (WW)was carried out. The reduction efficiencies of turbidity and chemical oxygen demand (COD), the removal efficiency of total suspended solids (TSS) and absorbance at 254 nm were the main evaluating parameters. Using coagulation-flocculation, the efficiencies of alum and polyaluminum chloride (PACl)were studied, when used alone and when coupled with flocculant aids. During the coagulation-flocculation process, use of a single coagulant, the coagulant dosage, and the pH, play an important role in determining the coagulation efficiency. At the optimum PACl dosage of 840 mg L−1 and optimum pH of 9.0, turbidity reduction was found to be 94.5%. A combination of inorganic coagulant and flocculant, or polymer was applied, in which PACl was used coupled with the polyelectrolytes Organopol WPB20 and WPB40. PACl coupled with Organopol WPB20 by optimal pH 9 gave a 98.3% reduction of turbidity, 91.9% removal of TSS, and a 60.2% reduction in COD. Ultrafiltration trials were carried out on a pilot scale. A tubular module was used with ceramic membrane. This membrane is a multi-channel membrane with an active surface layer made of Al2O3 and ZrO2. Within the acidic range, the turbidity and TSS were removed at above 99%.

scholarly journals Coliform Bacteria and Nitrogen Fixation in Pulp and Paper Mill Effluent Treatment Systems

2000 ◽  
Vol 66 (12) ◽  
pp. 5155-5160 ◽  
Author(s):  
Francis Gauthier ◽  
Josh D. Neufeld ◽  
Brian T. Driscoll ◽  
Frederick S. Archibald
Keyword(s):  
Activated Sludge ◽  
Water System ◽  
Paper Mill ◽  
Pulp And Paper ◽  
Effluent Treatment ◽  
Coliform Bacteria ◽  
Pulp And Paper Mill ◽  
Paper Mills ◽  
Paper Mill Effluent ◽  
Contrast Analysis

ABSTRACT The majority of pulp and paper mills now biotreat their combined effluents using activated sludge. On the assumption that their wood-based effluents have negligible fixed N, and that activated-sludge microorganisms will not fix significant N, these mills routinely spend large amounts adding ammonia or urea to their aeration tanks (bioreactors) to permit normal biomass growth. N2 fixation in seven Eastern Canadian pulp and paper mill effluent treatment systems was analyzed using acetylene reduction assays, quantitative nitrogenase (nifH) gene probing, and bacterial isolations. In situ N2 fixation was undetectable in all seven bioreactors but was present in six associated primary clarifiers. One primary clarifier was studied in greater detail. Approximately 50% of all culturable cells in the clarifier contained nifH, of which >90% were Klebsiella strains. All primary-clarifier coliform bacteria growing on MacConkey agar were identified as klebsiellas, and all those probed contained nifH. In contrast, analysis of 48 random coliform isolates from other mill water system locations showed that only 24 (50%) possessed thenifH gene, and only 13 (27%) showed inducible N2-fixing activity. Thus, all the pulp and paper mill primary clarifiers tested appeared to be sites of active N2fixation (0.87 to 4.90 mg of N liter−1 day−1) and a microbial community strongly biased toward this activity. This may also explain why coliform bacteria, especially klebsiellas, are indigenous in pulp and paper mill water systems.

scholarly journals Evaluation of the Phytotoxic and Genotoxic Potential of Pulp and Paper Mill Effluent Using Vigna radiata and Allium cepa

2016 ◽  
Vol 2016 ◽  
pp. 1-10 ◽  
Author(s):  
Izharul Haq ◽  
Vineeta Kumari ◽  
Sharad Kumar ◽  
Abhay Raj ◽  
Mohtashim Lohani ◽  
...  
Keyword(s):  
Allium Cepa ◽  
Vigna Radiata ◽  
Oxygen Demand ◽  
Paper Mill ◽  
Pulp And Paper ◽  
Root Tip ◽  
Pulp And Paper Mill ◽  
Paper Mill Effluent ◽  
Tip Cells ◽  
Root Tip Cells

Pulp and paper mill effluent induced phytotoxicity and genotoxicity in mung bean (Vigna radiata L.) and root tip cells of onion (Allium cepa L.) were investigated. Physicochemical characteristics such as electrical conductivity (EC), biological oxygen demand (BOD5), chemical oxygen demand (COD), and total phenols of the pulp and paper mill effluent were beyond the permissible limit specified for the discharge of effluent in inland water bodies. Compared to control plants, seedling exposed to 100% effluent concentration showed a reduction in root and shoot length and biomass by 65%, 67%, and 84%, respectively, after 5 days of treatment. A. cepa root tip cells exposed to effluent concentrations ranging from 25 to 100% v/v showed a significant decrease in mitotic index (MI) from 32 to 11% with respect to control root tip cells (69%) indicating effluent induced cytotoxicity. Further, the effluent induced DNA damage as evidenced by the presence of various chromosomal aberrations like stickiness, chromosome loss, anaphase bridge, c-mitosis, tripolar anaphase, vagrant chromosome, and telophase bridge and micronucleated and binucleated cell in A. cepa. Findings of the present study indicate that pulp and paper mill effluents may act as genotoxic and phytotoxic agents in plant model system.

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