scholarly journals PHOTOVOLTAIC MODULE RECYCLING: THERMAL TREATMENT TO DEGRADE POLYMERS AND CONCENTRATE VALUABLE METALS

Detritus ◽  
2021 ◽  
pp. 48-62
Author(s):  
Priscila Silva Silveira Camargo ◽  
Andrey da Silva Domingues ◽  
João Pedro Guê Palomero ◽  
Angela Cristina Kasper ◽  
Pablo Ribeiro Dias ◽  
...  

ABSTRACT: This work investigated the thermal treatment to separate and concentrate economically valuable materials from laminates of crystalline silicon photovoltaic modules (i.e., photovoltaic modules without the aluminum frame and the junction box). Chemical characterization of the metal content was performed by X-Ray Fluorescence (XRF). The polymers of the backsheet were also characterized by Fourier Transform Infrared Spectroscopy (FTIR). The influence of the atmosphere (oxidizing and inert) on the decomposition of the backsheet was investigated by Thermogravimetric Analysis (TGA). Moreover, non-comminuted samples were tested for 4 thermal time lengths (30, 60, 90, and 120 min) in the furnace under ambient air. The degradation of the polymers was measured and 3 material fractions were obtained: silicon with silver and residual polymers (SS), glass and copper ribbons. Furthermore, there was no statistical difference between the mass losses of the samples submitted for 90 (13.62 ± 0.02 wt.%) and 120 min at 500 °C (p-value = 0.062). In the SS fraction, silver was 20 times more concentrated than in the ground photovoltaic laminate and 30 times more concentrated than high silver concentration ores. The SS fraction (about 6 wt.%) also presented low copper concentration and a high concentration of lead (hazardous metal). About 79 wt.% glass was obtained, as well as 1% copper ribbons (55.69 ± 6.39% copper, 23.17 ± 7.51% lead, 16.06 ± 2.12% tin). The limitations of the treatment and its environmental impact are discussed, and suggestions for industrial-scale application are given.

2020 ◽  
Vol 4 (41) ◽  
pp. 51-56
Author(s):  
DMITRIY STREBKOV ◽  
◽  
NATAL’YA FILIPPCHENKOVA ◽  

In the field of energy supply to agro-industrial facilities, there is an increasing interest in the development of structures and engineering systems using renewable energy sources, including solar concentrator thermal and photovoltaic modules that combine photovoltaic modules and solar collectors in one structure. The use of the technology of concentrator heat and photovoltaic modules makes it possible to increase the electrical performance of solar cells by cooling them during operation, and significantly reduces the need for centralized electricity and heat supply to enterprises of the agroindustrial complex. (Research purpose) The research purpose is in numerical modeling of thermal processes occurring in a solar concentrator heat-photovoltaic module. (Materials and methods) Authors used analytical methods for mathematical modeling of a solar concentrator heat and photovoltaic module. Authors implemented a mathematical model of a solar concentrator heat and photovoltaic module in the ANSYS Fluent computer program. The distribution contours of temperature and pressure of the coolant in the module channel were obtained for different values of the coolant flow rate at the inlet. The verification of the developed model of the module on the basis of data obtained in an analytical way has been performed. (Results and discussion) The results of comparing the calculated data with the results of computer modeling show a high convergence of the information obtained with the use of a computer model, the relative error is within acceptable limits. (Conclusions) The developed design of the solar concentrator heat and photovoltaic module provides effective cooling of photovoltaic cells (the temperature of photovoltaic cells is in the operating range) with a module service life of at least twenty-five years. The use of a louvered heliostat in the developed design of a solar concentrator heat and photovoltaic module can double the performance of the concentrator.


Foods ◽  
2021 ◽  
Vol 10 (4) ◽  
pp. 700
Author(s):  
Bianca R. Albuquerque ◽  
Maria Inês Dias ◽  
Carla Pereira ◽  
Jovana Petrović ◽  
Marina Soković ◽  
...  

Fruit bio-residues can be interesting for the recovery of bioactive molecules, such as phenolic compounds, tocopherols, vitamins, among others. These compounds can be targeted at the food industry and used for the development of functional foods or as food additives. In some cases, fruit epicarps are converted into by-products with non-commercial value, and generally, these fruit parts have a higher content in bioactive compounds than the fruit pulp. From this perspective, S. odorifera, a Brazilian fruit, has an inedible epicarp that could be explored to obtain biological compounds. Therefore, the aims of this study were to evaluate the chemical composition and the antioxidant, anti-proliferative, anti-inflammatory, and antimicrobial bioactivities of this by-product. S. odorifera epicarp showed a total of four organic acids, four phenolic compounds, highlighting the high concentration of anthocyanins (24 ± 1 mg/g dry weight (dw)) and high content of tocopherols (366 ± 2 mg/100 g dw). The hydroethanolic extract showed considerable antioxidant activity (EC50 values of 48.2 ± 0.5 and 27 ± 1 µg/mL for TBARS and OxHLIA assays, respectively), as also antibacterial and antifungal activities (minimal inhibitory concentrations (MICs) ≤ 2.2 mg/mL). The results obtained in this study suggest that Sicana odorifera epicarp represents a reliable option for the development of novel natural-based colorants with functional/bioactive proprieties.


2021 ◽  
Vol 15 (12) ◽  
pp. 3195-3197
Author(s):  
Fariha Sadiqa ◽  
Mufakhara Fatimah ◽  
Abdul Mudabbir Rehan ◽  
Sidra Mushtaq ◽  
Asia Firdous ◽  
...  

Background: Pelvic pain around the time of mensturation without any identifiable pathologic lesion present from menarche is called primary dysmenorrhea. The pain is believed to be related to prostaglandin (PG). Women with dysmenorrhoea have a relatively high concentration of PGF 2 alpha in menstrual fluid and suppression of PG synthesis has become the main treatment. Aim: To compare mean reduction in pain in patients presenting with primary dysmenorrhea given vitamin E & Mefenamic acid versus Mefenamic acid alone. Results: It was a randomized controlled trial which was conducted in Department of Obstetrics & Gynecology, THQ Raiwind Hospital, Lahore for 6 months duration w.e.f 01/02/2017 to 31/07/2017. In this study, 18(36%) in Vitamin-E group and 21(42%) in Mefenamic acid group were between 15-20 years while 32(64%) in Vitamin-E group and 29(58%) in Mefenamic acid group were between 21-25 years, mean±sd was calculated as 20.86±2.92 and 20.66±2.86 years respectively, mean dysmenorrheal pain at baseline was recorded as 50.06±10.27 in Vitamin-E group and 50.14±10.28 in Mefenamic acid group, p value < 0.754, showing that both groups are insignificant, mean dysmenorrheal pain after treatment was recorded as 20.50±10.04 in Vitamin-E group and 30.22±10.28 in Mefenamic acid group, p value was < 0.002 showing significant difference between the two group, comparison of mean reduction in dysmenorrheal pain after treatment was recorded as 20.56±0.91 in Vitamin-E group and 10.92±0.75 in Mefenamic acid group, p value was < 0.000, showing significant difference. Conclusion: We concluded that there is a significant mean reduction in dysmenorrhic pain in patients given Mefenamic Acid + Vitamen E as compared to patients given Mefenamic Acid alone. Keywords: Dysmenorrhic pain, Mefenamic Acid + Vitamen E, mean reduction in dysmenorrhic pain


2021 ◽  
pp. 114236
Author(s):  
Mingyao Ma ◽  
Haisong Wang ◽  
Nianwen Xiang ◽  
Ping Yun ◽  
Hanyu Wang

2012 ◽  
Vol 135 (2) ◽  
Author(s):  
R. Laronde ◽  
A. Charki ◽  
D. Bigaud

In this paper, a methodology is presented for estimating the lifetime of a photovoltaic (PV) module. Designers guarantee an acceptable level of power (80% of the initial power) up to 25 yr for solar panels without having sufficient feedback to validate this lifetime. Accelerated life testing (ALT) can be carried out in order to determine the lifetime of the equipment. Severe conditions are used to accelerate the ageing of components and the reliability is then deduced in normal conditions, which are considered to be stochastic rather than constant. Environmental conditions at normal operations are simulated using IEC 61725 standard and meteorological data. The mean lifetime of a crystalline-silicon photovoltaic module that meets the minimum power requirement is estimated. The main results show the influence of lifetime distribution and Peck model parameters on the estimation of the lifetime of a photovoltaic module.


2018 ◽  
pp. 61-102
Author(s):  
Pablo Dias ◽  
Pablo Dias ◽  
Hugo Veit

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